Journal of Environmental Science International (한국환경과학회지)

The Korean Environmental Sciences Society (한국환경과학회)
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Synthesis and Fluorescent Properties of New Rhodamine B Containing Phenothiazine Moiety

새로운 로다민 B 페노시아진 유도체의 합성과 형광 특성

  • Received : 2015.03.24
  • Accepted : 2015.05.18
  • Published : 2015.07.31
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Abstract

A colorimetric chemosensors $Sn^{2+}$ have been designed and synthesized by three steps. The spirolactam ring-opening process of rhodamine B is one of the most useful mechanisms for controlling fluorescence properties. Herein, new fluorescent chemosensors 1 and 2 based on rhodamine B containing phenothiazine derivertive were synthesized. They exhibit selective fluorescence enhancement behaviour in the presence of $Sn^{2+}$ ion. Complexation between these compounds and the metal cations were confirmed through continuous variation method. It is observed that compounds 1, 2, and $Sn^{2+}$ ion are complexed by 1:1 formation. Especially the proposed compounds 1 and 2 exhibit quick, simple and facile synthetic route.

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References

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