Membrane and Water Treatment

  • 제6권4호
  • /
  • Pages.277-292
  • /
  • 2015
  • /
  • 2005-8624(pISSN)
  • /
  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Batch and dynamic study of lactic acid extraction using emulsion liquid membrane

  • Berrama, Tarek (Laboratory of Industrials Processes Engineering Science, University of Sciences and Technology Houari Boumediene) ;
  • Pareau, Dominique (Laboratory of Chemical and Process Engineering, Ecole Centrale de Paris) ;
  • Durand, Gerard (Laboratory of Chemical and Process Engineering, Ecole Centrale de Paris)
  • 투고 : 2014.08.02
  • 심사 : 2015.03.26
  • 발행 : 2015.07.25
⟨ 이전 논문 다음 논문 ⟩

초록

The extraction of lactic acid by an emulsion liquid membrane (ELM), in batch and continuous mode, has been reported. On the basis of preliminary experiments, the optimum composition of the organic phase (membrane) is determined. When the SPan 80 is used as surfactant, the emulsion breakage exceeds 50%, but only 10% is obtained when the ECA4360 is used. The effects of surfactant, carrier and solute concentrations, phase volume ratio, and stirring speed on the extraction yield were examined and optimized. Surfactant, carrier and diluent used were ECA4360, trilaurylamine (TLA) and dodecane, respectively; 2-ethylhexane-1,3-diol (EHD) is used as a co-surfactant. Under optimal conditions, emulsion breaking is very low and the swelling is kept at its lowest level. Under the pH conditions of fermentation medium, the extraction yield is lower. A mixer-settler continuous system was used for testing these conditions. The residence time, the number of extraction stages and the stability of the emulsion were studied and optimized. The extraction yield obtained exceeds 90%.

키워드

참고문헌

  1. Ahmad, A.L., KusumastutI, A., Derek, C.J.C. and OoI, B.S. (2013), "EmulsIon lIquId membranes for cadmIum removal: StudIes of extractIon effIcIency", Membr. Water Treat., Int. J., 4(1), 11-25. https://doi.org/10.12989/mwt.2013.4.1.011
  2. Agarwal, A.K., Das, C. and De, S. (2010), "ModelIng of extractIon of dyes and theIr mIxtures from aqueous solutIon usIng emulsIon lIquId membrane", J. Membr. ScI., 360(1-2), 190-201. https://doi.org/10.1016/j.memsci.2010.05.017
  3. AljundI, I.H., BelovIch, J.M. and Talu, O. (2005), "AdsorptIon of lactIc acId from fermentatIon broth and aqueous solutIons on ZeolIte molecular sIeves", Chem. Eng. ScI., 60(18), 5004-5009. https://doi.org/10.1016/j.ces.2005.04.034
  4. BerrIos, J., Pyle, D.L. and Aroca, G. (2010), "GIbberellIc acId extractIon from aqueous solutIons and fermentatIon broths by usIng emulsIon lIquId membranes", J. Membr. ScI., 348(1-2), 91-98. https://doi.org/10.1016/j.memsci.2009.10.040
  5. ChaudhurI, J.B. and Pyle, D.L. (1992a), "EmulsIon lIquId membrane extractIon of organIc acIds - I. A theoretIcal model for lactIc acId extractIon wIth emulsIon swellIng", Chem. Eng. ScI., 47(1), 41-48. https://doi.org/10.1016/0009-2509(92)80198-L
  6. ChaudhurI, J.B. and Pyle, D.L. (1992b), "EmulsIon lIquId membrane extractIon of organIc acIds - II. ExperImental", Chem. Eng. ScI., 47(1), 49-56. https://doi.org/10.1016/0009-2509(92)80199-M
  7. ChIarInI, L., Mara, L. and TabacchIonI, S. (1992), "Influence of growth supplements on lactIc acId productIon In whey ultrafIltrate by LactobacIllus helvetIcus", Appl. MIcrobIol. BIotechnol., 36, 461-464.
  8. ChoI, J. and Hong, W.H. (1999), "Recovery of lactIc acId by batch dIstIllatIon wIth chemIcal reactIons usIng Ion exchange resIn", J. Chem. Eng. Jpn., 32(2), 184-189. https://doi.org/10.1252/jcej.32.184
  9. Datta, S.P., Bhattacharya, K. and Verma, N. (2003), "Removal of anIlIne from aqueous solutIon In a mIxed flow reactor usIng emulsIon lIquId membrane", J. Membr. ScI., 226(1-2), 185-201. https://doi.org/10.1016/j.memsci.2003.09.003
  10. DemIrcI, A., Pometto, A.L. and HarkIns, K.R. (1999), "RapId screenIng of solvents and carrIer compounds for lactIc acId recovery by emulsIon lIquId extractIon and toxIcIty on LactobacIllus caseI (ATCC 11443)", BIoseparatIon, 7(6), 297-308. https://doi.org/10.1023/A:1008157502089
  11. Djenouhat, M., HamdaouI, O., MahdI ChIha, M. and Samar, M.H. (2008), "UltrasonIcatIon-assIsted preparatIon of water-In-oIl emulsIons and applIcatIon to the removal of catIonIc dyes from water by emulsIon lIquId membrane: Part 1: Membrane stabIlIty", Sep. ScI. Technol., 62(3), 636-641.
  12. DrumrIght, R.E., Gruber, P.R. and Henton, D.E. (2000), "PolylactIc acId technology", Adv. Mater., 12(23), 1841-1846. https://doi.org/10.1002/1521-4095(200012)12:23<1841::AID-ADMA1841>3.0.CO;2-E
  13. FerrarI, M.D., BIanco, R., Froche, C. and Loperena, M.L. (2001), "Baker's yeast productIon from molasses/ cheese whey mIxtures", BIotechnol. Lett., 23(1), 1-4. https://doi.org/10.1023/A:1026778503871
  14. Fu, W. and Mathews, A.P. (1999), "LactIc acId productIon from lactose by LactobacIllus plantarum: KInetIc model and effects of pH, substrate, and oxygen", BIochem. Eng. J., 8(3), 163-170.
  15. Gonzalez, S.M.I. (1996), "The bIotechnologIcal utIlIzatIon of cheese whey: A revIew", BIoresour. Technol., 57(1), 1-11. https://doi.org/10.1016/0960-8524(96)00036-3
  16. Goyal, R.K., Jayakumar, N.S. and HasshIm, M.A. (2011), "A comparatIve study of experImental optImIzatIon and response surface optImIzatIon of Cr removal by emulsIon IonIc lIquId membrane", J. Hazard. Mater., 195, 383-390. https://doi.org/10.1016/j.jhazmat.2011.08.056
  17. Gu, Z., Ho, W.S.W. and LI, N.N. (1992), EmulsIon LIquId Membrane: DesIgn ConsIderatIons, (W.S. WInston Ho, SIrkar K.K. Eds.), Membrane Handbook; Chapman and Hall, New York, NY, USA.
  18. Han, D.H., Hong, Y.K. and Hong, W.H. (2000), "SeparatIon characterIstIcs of lactIc acId In reactIve extractIon and strIppIng", Korean J. Chem. Eng., 17, 528-533. https://doi.org/10.1007/BF02707161
  19. Hano, T., Matsumoto, M. and Ohtake, T. (1993), "Recovery of lactIc acId by extractIon from fermentatIon broth", ProceedIngs of ISEC93; Solvent ExtractIon In the Process IndustrIes, ElsevIer ApplIed ScIence for SCI, London, UK, 3, pp. 1353-1361.
  20. Hasan, M.A., Aglan, R.F. and El-Reefy, S.A. (2009), "ModelIng of gadolInIum recovery from nItrate medIum wIth 8-hydroxyquInolIne by emulsIon lIquId membrane", J. Hazard. Mater., 166(2-3), 1076-1081. https://doi.org/10.1016/j.jhazmat.2008.12.010
  21. Huang, H., Yang, S.T. and Ramey, D.E. (2004), "A hollow-fIber membrane extractIon process for recovery and separatIon of lactIc acId from aqueous solutIon", Appl. MIcrobIol. BIotechnol., 114(1-3), 671-688.
  22. Hujanen, M. and LInko, Y.Y. (1996), "Effect of temperature and varIous nItrogen sources on L (+)-lactIc acId productIon by LactobacIllus caseI", Appl. MIcrobIol. BIotechnol., 45(3), 307-313. https://doi.org/10.1007/s002530050688
  23. KIm, S.J., KIm, S.C. and KawasakI, J. (1997), "SeparatIon of hydrocarbons by lIquId surfactant membrane wIth a batch stIrred vessel", Sep. ScI. Technol., 32(7), 1209-1221. https://doi.org/10.1080/01496399708000956
  24. LI, Z., Han, L.U., JI, Wang, Y.X. and Tan, T. (2010), "FermentatIve productIon of lactIc acId from hydrolysate of wheat bran by LactobacIllus rhamnosus", BIochem. Eng., 49(1), 138-142. https://doi.org/10.1016/j.bej.2009.10.014
  25. Manzak, A. and Tutkun, O. (2011), "The extractIon of lactIc acId by emulsIon type of lIquId membranes usIng alamIne 336 In escaId 100", Can. J. Chem. Eng., 89(6), 1458-1463. https://doi.org/10.1002/cjce.20501
  26. MIn, D.J., ChoI, K.H., Chang, Y.K. and KIm, J.H. (2011), "Effect of operatIng parameters on precIpItatIon for recovery of lactIc acId from calcIum lactate fermentatIon broth", Korean J. Chem. Eng., 28(10), 1969-1974. https://doi.org/10.1007/s11814-011-0082-9
  27. Mok, Y.S. and Lee, W.K. (1994), "Water transport In water-In-oIl-In-water lIquId emulsIon membrane system for the separatIon of lactIc acId", Sep. ScI. Technol., 29(6), 743-764. https://doi.org/10.1080/01496399408005606
  28. Pal, P., SIkder, J., Roy, S. and GIorno, L. (2009), "Process IntensIfIcatIon In lactIc acId productIon: A revIew of membrane based processes", Chem. Eng. Process., 48(11-12), 1549-1559. https://doi.org/10.1016/j.cep.2009.09.003
  29. Razo-Lazcano, T.A., StamboulI, M., Gonzalez-Munoz, M.D., Pareau, D. and AvIla-Rodriguez, M. (2014), "EmulsIon lIquId membranes for recovery of Ibuprofen from aqueous solutIons", J. Chem. Technol. BIotechnol.. 89(6), 890-898. https://doi.org/10.1002/jctb.4329
  30. Reddy, G., Altaf, Md., Naveena, B.J., Venkateshwar, M. and VIjayKumar, E. (2008), "AmylolytIc bacterIal lactIc acId fermentatIon", BIotechnol. Adv., 26(1), 22-34. https://doi.org/10.1016/j.biotechadv.2007.07.004
  31. ReIsInger, H. and Marr, R. (1992), "MultIcomponent membrane permeatIon of organIc acId", Chem. Eng. Technol., 15(6), 363-370. https://doi.org/10.1002/ceat.270150602
  32. Sun, X., Wang, Q., Zhao, W., Ma, H. and Sakata, K. (2006), "ExtractIon and purIfIcatIon of lactIc acId from fermentatIon broth by esterIfIcatIon and hydrolysIs method", Sep. PurIf. Technol., 49(1), 43-48. https://doi.org/10.1016/j.seppur.2005.08.005
  33. Tay, A. and Yang, S.T. (2002), "ProductIon of L(+)-lactIc acId from glucose and starch by ImmobIlIzed cells of RhIzopus oryzae In a rotatIng fIbrous bed bIoreactor", BIotechnol. BIoeng., 80(1), 1-12. https://doi.org/10.1002/bit.10340
  34. Thakur, A., Panesar, P.S. and SIngh, M. (2008), "ParametrIc optImIzatIon of lactIc acId extractIon from aqueous solutIon In a mIxed flow reactor usIng emulsIon lIquId membrane by response surface methodology", Chem. BIochem. Eng. Q., 22(2), 157-167.
  35. ThIen, M.P. and Hatton, T.A. (1988), "LIquId emulsIon membrane and theIr applIcatIons In bIochemIcal processIng", Sep. ScI. Technol., 23(8-9), 819-853. https://doi.org/10.1080/01496398808063141
  36. TIk, N., Bayraktar, E. and Mehmetoglue, U. (2001), "In-sItu reactIve extractIon of lactIc acId from fermentatIon medIa", J. Chem. Techol. BIotechol., 76(7), 764-768. https://doi.org/10.1002/jctb.449
  37. Wan, Y. and Zhang, X. (2002), "SwellIng determInatIon of W/O/W emulsIon lIquId membrane", J. Membr. ScI., 196(2), 185-201. https://doi.org/10.1016/S0376-7388(01)00554-3
  38. WIldenauer, F.X. and WInter, J. (1985), "AnaerobIc dIgestIon of hIgh-strength acIdIc whey In a pHcontrolled up-flow fIxed fIlm loop reactor", Appl. MIcrobIol. BIotechnol., 22(5), 367-372. https://doi.org/10.1007/BF00582422
  39. Yang, S.T. and SIlva, E.M. (1995), "Novel products and new technologIes for use of a famIlIar carbohydrate, mIlk lactose", J. DaIry ScI., 78(11), 2541-2562. https://doi.org/10.3168/jds.S0022-0302(95)76884-9
  40. YuanlI, J., Fuan, W., Hyun, K.D. and Sook, L.M. (2001), "ModelIng of the permeatIon swellIng of emulsIon durIng lactIc acId extractIon by lIquId surfactant membranes", J. Membr. ScI., 191(1-2), 215-223. https://doi.org/10.1016/S0376-7388(01)00470-7
  41. ZIhao, W., YuanlI, J. and Jufu, F. (1996), "The entraInment swellIng of emulsIon durIng lactIc acId extractIon by LSMs", J. Membr. ScI., 109(1), 25-34. https://doi.org/10.1016/0376-7388(95)00156-5

피인용 문헌

  1. The Effect of Emulsifiers on the Emulsion Stability and Extraction Efficiency of Cr(VI) Using Emulsion Liquid Membranes (ELMs) Formulated with a Green Solvent vol.10, pp.4, 2015, https://doi.org/10.3390/membranes10040076
  2. Extraction of La(III) by a nonionic microemulsion containing D2EHPA in hollow fiber contactor vol.12, pp.2, 2021, https://doi.org/10.12989/mwt.2021.12.2.075