Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Synthesis of High Molecular Weight Poly(m-phenylene terephthalamide) in NMP/CaCl2 Solvents

NMP/CaCl2 용매에서 고분자량 폴리메타페닐렌 테레프탈아미드의 합성

  • Lee, Woo-Seung (Department of Advanced Organic Materials, Yeungnam University) ;
  • Yim, Jong-Ha (Department of Advanced Organic Materials, Yeungnam University) ;
  • Ahn, Ji-Hoon (Department of Advanced Organic Materials, Yeungnam University) ;
  • Son, Tae-Won (Department of Chemical Engineering, Yeungnam University)
  • 이우승 (영남대학교 유기신소재공학부) ;
  • 임종하 (영남대학교 유기신소재공학부) ;
  • 안지훈 (영남대학교 유기신소재공학부) ;
  • 손태원 (영남대학교 화학공학부)
  • Received : 2015.02.25
  • Accepted : 2015.05.25
  • Published : 2015.06.30
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Abstract

A new solvent was developed for the synthesis of a high-molecular-weight aramid polymer, PMTA, which is a low-weight form of poly(m-phenylene terephthalamide). The condensation method was optimized to obtain the best-grade polymer. HCl liberated from the optimized polymer was neutralized with CaO and the polymer was characterized. A series of neutralization experiments were performed to determine the relationships between the viscosity properties and the experimental conditions. The PMTA properties were characterized by instrumental analysis.

Keywords

References

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