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Microstructural behavior and mechanics of nano-modified cementitious materials

  • Archontas, Nikolaos D. (Electrical & Computer Engineering Department, Democritus University of Thrace) ;
  • Pantazopoulou, S.J. (Department of Civil & Environmental Engineering, University of Cyprus)
  • Received : 2014.08.27
  • Accepted : 2014.11.30
  • Published : 2015.03.25

Abstract

Ongoing efforts for improved fracture toughness of engineered cementitious materials address the inherent brittleness of the binding matrix at several different levels of the material's geometric scale through the addition of various types of reinforcing fibers. Crack control is required for crack widths that cover the entire range of the grain size spectrum of the material, and this dictates the requirement of hybrid mixes combining fibers of different size (nano, micro, macro). Use of Carbon Nano-Tubes (CNT) and Carbon Nano-Fibers (CNFs) as additives is meant to extend the crack-control function down to the nanoscale where cracking is believed to initiate. In this paper the implications of enhanced toughness thus attained at the material nanostructure are explored, with reference to the global smeared constitutive properties of the material, through consistent interpretation of the reported experimental evidence regarding the behavior of engineered cementitious products to direct and indirect tension.

Keywords

References

  1. Abu Al-Rub R., Ashour A. and Tyson B. (2012a), "On the aspect ratio effect of multi-walled carbon nanotube reinforcements on the mechanical properties of cementitious nanocomposites", Constr. Build. Mater., 35, 647-655. https://doi.org/10.1016/j.conbuildmat.2012.04.086
  2. Abu Al-Rub, R., Tyson, B., Yazdanbakhsh, A. and Grasley, Z. (2012b), "Mechanical Properties of nanocomposite cement incorporating surface-treated and untreated carbon nanotubes and carbon nanofibers", ASCE J. Nanomech. Micromech., 2, 1-6. https://doi.org/10.1061/(ASCE)NM.2153-5477.0000041
  3. Balaguru, P.N. and Shah, S.P. (1992), Fiber reinforced Cement Composites, McGraw-Hill Inc., N.Y.
  4. Bharj, Jyoti, Sarabjit Singh, Subhash Chander and Rabinder Singh, (2014), "Experimental study on compressive strength of cement-CNT composite paste", Indian J. Pure Appl. Phy., 52, 35-38
  5. Chaipanich, A., Nochaiya, T., Wongkeo, W. and Torkittikul, P. (2010), "Compresive strength of microstructure of carbon nanotubes-fly ash cement composites", Mater. Sci. Eng., A 527, 1063-1067. https://doi.org/10.1016/j.msea.2009.09.039
  6. Cwirzen, A., Habermehl-Cwirzen, K. and Penttala, V. (2008), "Surface decoration of carbon nanotubes and mechanical properties of cement/carbon nanotube composites", Adv. Cement Res., 20(2), 65-73 https://doi.org/10.1680/adcr.2008.20.2.65
  7. Dwivedi, N., Kumar, S., Malik, H.K., Govind, Rauthan, C.M.S. and Ranwar, O.S. (2011), "Correlation of sp3 and sp2 fraction of carbon with electrical, optical and nano-mechanical properties of argon-diluted diamond-like carbon films", Appl. Surf. Sci., 257, 6804-6810. https://doi.org/10.1016/j.apsusc.2011.02.134
  8. Ferro G., Tulliani J.M. and Musso, S. (2011) "Carbon nanotubes cement composites", Proceedings, Frattura ed Integrita Strutturale, 18, 34-44, DOI 10.3221/IGF-ESIS.18.04
  9. Fib Model Code (2010), Federation International du Beton, Lausanne, http://www.fibinternational.org/model-code-2010-first-complete-draft-vol-1.
  10. Hlavacek, P., Smilauer, V., Padevet, P., Nasibulina, L. and Nasibulin, A. (2011), "Cement grains with surface synthetized carbon nanofibres: Mechanical properties and nanostructure", CD-ROM Proceedings, Nanocon, 9/2011, Brno, Check Republic.
  11. Konsta-Gdoutos, M.S., Metaxa, Z.S. and Shah S.P. (2010), "Carbon nanofiber-reinforced cement-based materials", J. Transport. Res. Board, No. 2142, Washington, D.C., 114-118.
  12. Konsta-Gdoutos, M.S., Metaxa, Z.S. and Shah, S.P. (2010), "Highly dispersed CNTs reinforced cementbased materials", Cement Concrete Res., 40(7), 1052-1059. https://doi.org/10.1016/j.cemconres.2010.02.015
  13. Konsta-Gdoutos, M.S., Metaxa, Z.S. and Shah, S.P. (2010), "Multi-scale mechanical and fracture characteristics and early-age strain capacity of high performance carbon nanotube/cement nanocomposites", Cement Concrete Compos., 32(2), 110-115. https://doi.org/10.1016/j.cemconcomp.2009.10.007
  14. Kumar, S., Kolay P., Mala, S. and Mishra, S. (2012) "Effect of multiwalled carbon nanotubes on mechanical strength of cement pastes", ASCE J. Mater. Civil Eng., 24(1), 84-91. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000350
  15. Li G.Y., Wang P.M. and Zhao X., (2005) "Mechanical behavior and microstructure of cement composites incorporating surface-treated MWCNTs", Carbon, 43, 1239-1245. https://doi.org/10.1016/j.carbon.2004.12.017
  16. Li V.C. (2003), "On Engineered cementitious composites (ECC)", J. Adv. Concrete Technol., 1(3), 215-230. https://doi.org/10.3151/jact.1.215
  17. Makar, J.M. and Beaudin, J.J. (2004), "Carbon nanotubes and their applications in the construction industry," in "Nanotechnology in construction", 1st Intnl. Symp. Nanotechnology in Construction, 331-341.
  18. Metaxa, Z.S., Konsta-Gdoutos, M.S. and Shah, S.P. (2009), "Carbon nanotubes reinforced concrete", ACI SP 276-2, 11-19.
  19. Metaxa, Z.S., Konsta-Gdoutos, M.S. and Shah, S.P. (2011), "Mechanical properties and nanostructure of cement-based materials reinforced with carbon nanofibers and polyvinyl alcohol (PVA) microfibers", ACI SP, 270-10, 115-124.
  20. Morsy, M.S., Alsayed, S.H. and Aqel, M. (2011), "Hybrid effect of CNT and nano-clay on physic mechanical properties of cement mortar", Constr. Build. Mater., 25, 145-149. https://doi.org/10.1016/j.conbuildmat.2010.06.046
  21. Musso, S., Tulliani, J.M., Ferro, G. and Tagliaferro, A. (2009), "Influence of carbon nanotubes structure of the mechanical behavior of cement composites", Compos. Sci. Technol., 69, 1985-1990. https://doi.org/10.1016/j.compscitech.2009.05.002
  22. Peled, A., Cyr, M. and Shah, S.P. (2000), "Hybrid fibers in high performances extruded cement composites", 5th Intern. RILEM Symp., BEFIB, Lyon, France.
  23. Pantazopoulou S.J. and Mills R.H. (1995), "Microstructural aspects of the mechanical response of plain concrete", ACI Mater. J., 92(6), 605-616, November-December.
  24. Pantazopoulou, S.J. and Zanganeh, M. (2001), "Triaxial tests of fiber reinforced concrete", ASCE J. Mater. Civil Eng., 13(5), 340-348. https://doi.org/10.1061/(ASCE)0899-1561(2001)13:5(340)
  25. Sakulich, A.R. and Li, V.C. (2011), " Nanoscale characterization of engineered cementitious composites (ECC)", Cement Concrete Res., 41, 169-175. https://doi.org/10.1016/j.cemconres.2010.11.001
  26. Shah, S.P., Konsta-Gdoutos, M.S., Metaxa, Z.S. and Mondal, P. (2009), "Nanoscale modification of cementitious materials", Nanotech. Constr. 3, (Eds.: Z. Bittnar, P.J.M. Bartos, J. Nemecek, V. Smilauer, J. Zeman, Springer, pp. 125-130.
  27. Shi, C.J. and Mo, Y.L. (2008), "High-performance construction materials: Science and applications, Vol. 1, Engineering materials for technological needs", World Scientific, ISBN 981279736X, 9789812797360, 431pp.
  28. Sobolkina, A., Mechtcherine, V., Khavrus, V., Maier, D., Mende, M., Ritchel, M. and Leonhardt, A. (2012), "Dispersion of Carbon Nanotubes and its influence of the mechanical properties of the cement matrix", Cement Concrete Compos., 34, 1104-1113. https://doi.org/10.1016/j.cemconcomp.2012.07.008
  29. Tastani, S.P. and Pantazopoulou, S.J. (2006), "Bond οf G-FRP bars in cncrete: Exper. study and analytical interpretation", ASCE J. Compos. Constr., 10(5), 381-391. https://doi.org/10.1061/(ASCE)1090-0268(2006)10:5(381)
  30. Tyson, B., Abu Al-Rub, R., Yazdanbakhsh, A. and Grasley, Z. (2011), "Carbon nanotubes and carbon nanofibers for enhancing the mechanical properties of nanocomposite cementitious materials", ASCE Mater. J. Civil Eng., 23(7), 1027-1035.
  31. Wang, C., Li, K.Z., Li, H.J., Jiao, G.S., Lu, J.H. and Hou, D.S. (2008), "Effect of carbon fiber dispersion of the mechanical properties of the carbon FRC composites", Mater. Sci. Eng., A:487, 52-57. https://doi.org/10.1016/j.msea.2007.09.073

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