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Development and Evaluation of Regression Model for TOC Contentation Estimation in Gam Stream Watershed

감천 유역의 TOC 농도 추정을 위한 회귀 모형 개발 및 평가

  • Jung, Kang-Young (Nakdong River Environment Research Center, National Institute of Environmental Research, NIER) ;
  • Ahn, Jung-Min (Nakdong River Environment Research Center, National Institute of Environmental Research, NIER) ;
  • Lee, Kyung-Lak (Nakdong River Environment Research Center, National Institute of Environmental Research, NIER) ;
  • Kim, Shin (Nakdong River Environment Research Center, National Institute of Environmental Research, NIER) ;
  • Yu, Jae-Jeong (Nakdong River Environment Research Center, National Institute of Environmental Research, NIER) ;
  • Cheon, Se-Uk (Nakdong River Environment Research Center, National Institute of Environmental Research, NIER) ;
  • Lee, In Jung (Nakdong River Environment Research Center, National Institute of Environmental Research, NIER)
  • 정강영 (국립환경과학원 낙동강물환경연구소) ;
  • 안정민 (국립환경과학원 낙동강물환경연구소) ;
  • 이경락 (국립환경과학원 낙동강물환경연구소) ;
  • 김신 (국립환경과학원 낙동강물환경연구소) ;
  • 유재정 (국립환경과학원 낙동강물환경연구소) ;
  • 천세억 (국립환경과학원 낙동강물환경연구소) ;
  • 이인정 (국립환경과학원 낙동강물환경연구소)
  • Received : 2015.01.27
  • Accepted : 2015.05.28
  • Published : 2015.06.30

Abstract

In this study, it is an object to develop a regression model for the estimation of TOC (total organic carbon) concentration using investigated data for three years from 2010 to 2012 in the Gam Stream unit watershed, and applied in 2009 to verify the applicability of the regression model. TOC and $COD_{Mn}$ (chemical oxygen demand) were appeared to be derived the highest correlation. TOC was significantly correlated with 5 variables including BOD (biological oxygen demand), discharge, SS (suspended solids), Chl-a (chlorophyll a) and TP (total phosphorus) of p<0.01. As a result of PCA (principal component analysis) and FA (factor analysis), COD, TOC, SS, discharge, BOD and TP have been classified as a first factor. TOCe concentration was estimated using the model developed as an independent variable $BOD_5$ and $COD_{Mn}$. R squared value between TOC and measurement TOC is 0.745 and 0.822, respectively. The independent variable were added step by step while removing lower importance variable. Based on the developed optimal model, R squared value between measurement value and estimation value for TOC was 0.852. It was found that multiple independent variables might be a better the estimation of TOC concentration using the regression model equation(in a given sites).

Keywords

References

  1. Bernard, P., Antoine, L., Bernard, L., 2004, Principal component analysis an appropriate tool for water quality evaluation and management application to a tropical lake system, Ecological Modeling, 178, 295-311. https://doi.org/10.1016/j.ecolmodel.2004.03.007
  2. Cho, H. K., 2011, A study on the related characteristics of discharge-water quality in Nakdong river, J. Environ. Sci., 20(3), 373-384.
  3. Choi, J. Y., Han, D. H., 2011, Development of water quality standard for TOC as organic matter index, The Seoul Institute, 12(3), 173-184.
  4. Choi, D. H., Jung, J. W., Yoon, K. S., Lee, K. S., Choi, W. J., Lim, S. S., Park, H. N., Yim, B. J., Hwang, T. H., 2012, Estimation of TOC concentration using BOD, COD in runoff from paddy fields, J. Korean Soc. Water Environ., 28(6), 813-818.
  5. Dignac, M. F., Ginestet, P., Rybacki, D., Bruchet, A., Urbain, V., and Scribe, P., 2000, Fate of wastewater organic pollution during activated sludge treatment: natire of residual organic matter, Water Res., 34(17), 4185-4194 https://doi.org/10.1016/S0043-1354(00)00195-0
  6. Jung, J. W., Cho, S. H., Choi, J. H., Kim, K. S., Jung, S. J., Lim, B. J., 2013, Development and evaluation of simple regression model and multiple regression model for TOC contentation estimation in stream flow, J. Korean Soc. Water Environ., 29(5), 625-629.
  7. Kim, J. K., Shin, M. S., Jang, C. W., Jung, S. M., Kim, B. C., 2007, Comparison of TOC and DOC distribution and the oxidation efficency of BOD and COD in several reservoirs and rivers in the Han river system, J. Korean Soc. Water Environ., 23(1), 72-80.
  8. Kim, B. C., Jung, S. M., Jang, C. W., Kim, J. K., 2007, Comparison of BOD, COD and TOC as the indicator of organic matter pollution in streams and reservoirs of Korea, J. Korean. Soc. Environ. Eng., 29(6), 640-643.
  9. Kim, M. A., Lee, J. K., Zoh, K. D., 2007, Evaluation of the Geum river by multivariate analysis: principal component analysis and factor analysis, J. Korean Soc. Water Environ.,, 23(1), 161-168.
  10. Kim, H. S., Hong, J. J., Seong, J. U., Choi, K. S., Park, J. C., 2013, Comparison of organic matter distribution in major tributaries of the Nakdong river, J. Korean Soc. Water Environ., 29(5), 618-624.
  11. Kim, G. H., Jung, K. Y., Lee, I. J., Lee, K. L., Cheon, S. U., Im, T. H., Yoon, J. S., 2014, A study on instream flow for water quality improvement in lower watershed of Nam River dam, J. Korean Soc. Water Environ., 30(1), 44-59. https://doi.org/10.15681/KSWE.2014.30.1.044
  12. Kim, G. H., Jung, K. Y., Yoon, J. S., Cheon, S. U., 2013, Temporal and spatial analysis of water quality data observed in lower watershed of Nam river dam, J-KOSHAM., 13(6), 429-437.
  13. Lyu, J. H., Lee, D. G., 2007, Inquiry of water environment in mihocheon (stream) -water quality monitoring focused on TOC-, J. Korean Soc. Water Environ., 23(5), 731-739.
  14. Lee, T. H., Lee, B. M., Hur, Jin., Jung, M. S., Kang, T. G., 2010, Conversion of CODMn into TOC and refractory organic matter concentrations for treated sewage using regression equations, J. Korean Soc. Water Environ., 26(6), 969-975.
  15. Park, H. S., Park, C. K., Song., M. K., Baek, K. H., Shin, S. K., 2001, Evaluation of water quality characteristics using factor analysis in the Nakdong river, J. Korean Soc. Water Environ., 17(6), 693-701.
  16. Park, H. Y., Lee, J. K., Ha, H., Lee, H. B., Kim, Y. K., Park, C. O., Park, S. I., 2006, A correlation study of organic matters by TOC, J. Korean. Soc. Environ. Eng., 2006 Proceeding of Spring Conference, 834-842.
  17. Park, J. H., Park, B. K., Lee, I. J., Lee, J. K., Rhew, D. H., 2013, Necessity of refractory organic matters management in total maximum daily loads (TMDLs), J. Korean Soc. Water Environ., 29(3), 393-399.
  18. Park, J. W., Moon, M. J., Han, S. W., Lee, H. J., Jung, S. J., Hwang, K. S., Kim, K. S., 2014, Application of regression analysis model to TOC concentration estimation -Osu stream watershed-, J. Environ. Impact Assess., 23(3), 187-196. https://doi.org/10.14249/eia.2014.23.3.187
  19. Sakamoto, H., Hamaguchi R., Iwase M., 1988, Evaluation of river water pollution in the chanai district of eastern hokkaido by the multivariate analysis method, Water and Waste, 30(3), 239-245.
  20. Yoon, Y. S., Yu, J. J., Kim, M. S., Lee, H. J., 2006, Computation and assessment of delivery pollutant loads for the streams in the Nakdong river basin, J. Korean Soc. Water Environ., 22(2), 277-287.