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Dark Conductivity in Semi-Insulating Crystals of CdTe:Sn

  • Makhniy, V.P. (Chernivtsi National University) ;
  • Sklyarchuk, V.M. (Chernivtsi National University) ;
  • Vorobiev, Yu.V. (CINVESTAV-IPN Unidad Quretaro) ;
  • Horley, P.P. (CIMAV Chihuahua / Monterrey)
  • 투고 : 2014.10.27
  • 심사 : 2015.02.24
  • 발행 : 2015.04.30

초록

We prepared semi-insulating CdTe for radiation detectors by isothermal annealing of single crystals grown by Bridgeman technique in a sealed quartz container filled with Sn vapor. The resistivity of CdTe:Sn samples thus obtained was of order of $10^{10}Ohm{\cdot}cm$ at room temperature with electrons lifetime of $2{\times}10^{-8}$ s, which is appropriate for the applications desired. Analysis of electric transport characteristics depending on temperature, sample thickness and voltage applied revealed the presence of traps with concentration of about $(4-5){\times}10^{12}cm^{-3}$ with the corresponding energy level at 0.8 - 0.9 eV counted from the bottom of conduction band. The conductivity was determined by electron injection from electrodes in space charge limited current mode.

키워드

참고문헌

  1. Mathew X. Band gap of CdTe thin films - The dependence on temperature. J. Mater. Sci. Lett. 21 (2001) 529-0531.
  2. Mathew X., Sebastian P.J. Optical properties of electrodeposited CdTe thin films. Solar Energy Mater. and Solar Cells. 59 (1999) 85-98. https://doi.org/10.1016/S0927-0248(99)00034-3
  3. Lutz G. Semiconductor radiation detectors: device physics. Berlin: Springer-Verlag, 2007.
  4. Spieder H. Semiconductor detector systems. Oxford University Press, 2005.
  5. Bhattacharya P. Semiconductor optoelectronic devices. 2nd ed. Prentice-Hall, Inc., USA, 1997.
  6. Balkanski M., Wallis R.F. Semiconductor physics and applications. Oxford University Press, 2000.
  7. Roberts G.G. Smidlin F.W. Study of localized levels in semi-insulators by combined measurements of thermally activated ohmic and space-chargelimited conduction. Phys. Rev. 180 (1969) 785-794. https://doi.org/10.1103/PhysRev.180.785
  8. Grinberg A.A., Luryi S., Pinto M.R., Schryer N.L. Space Charge Limited Current in a film. IEEE Trans. Electron. Dev. 36 (1989) 1162-1170 https://doi.org/10.1109/16.24363
  9. Makhnii V.P. Semi-insulating layers of cadmium telluride. Technical Physics 50 (2005) 1513-1514 https://doi.org/10.1134/1.2131964
  10. Makhnii V.P., Kosolovskiy V.V., Slyotov M.M., Skrypnik M.V., Slyotov A.M. The nature of edge luminescence of CdTe:Mg diffusion layers. Semiconductors 44 (2010) 1167-1169. https://doi.org/10.1134/S1063782610090101
  11. Lampert M.A., Mark P. Current Injection in solids. Academic Press Inc, 1970.
  12. Tutov E. A., Tuma F. A. and Kukuev V. I. Mechanisms of current transferring in Al/ZnO/Si structure, Condens. Environ. Interphas. Bound., 8 (2006) 334-340.
  13. Brunthaler G., Jantsch W., Kaufman U., Schneider J. Electron-spin-resonance analysis of the deep donors lead, tin, and germanium in CdTe. Phys. Rev. B. 31 (1985) 1219-1243.
  14. Franc J., Fiederle M., Babentsov V., Faluler A., Benz K.W., James R. Defect structure of Sn-doped CdTe. J. Electron. Mater. 32 (2003) 773-777.
  15. Berding M.A. Native defects in CdTe. Phys. Rev. B. 60 (1999) 8943-8950. https://doi.org/10.1103/PhysRevB.60.8943
  16. Milnes A.G. Deep impurities in semiconductors. Wiley, 1973.
  17. Milnes A.G., Miner C.J. Semi-insulating III-V materials. Science, Toronto, 1990.
  18. Ashley K.L., Milnes, A.G. Double injection in deep lying impurity semiconductors. Journal of Applied Physics 35 (1964) 369. https://doi.org/10.1063/1.1713320