DOI QR코드

DOI QR Code

산화그래핀 박막 코팅기술 개발 및 특성평가

Development and Analysis of Graphene Oxide Thin Film Coating

  • 투고 : 2015.02.26
  • 심사 : 2015.03.20
  • 발행 : 2015.05.01

초록

산화그래핀 소재를 합성하여 투명한 박막 코팅기술을 개발하고 특성을 평가하였다. 스핀과 스프레이 공정을 동시에 이용하여 산화그래핀을 유리 기판에 균일하게 박막코팅을 하였다. 균일하게 산화그래핀을 스핀-스프레이 공정을 이용하여 박막코팅을 하기 위하여 유리기판을 amine-functional group으로 표면개질을 하였다. 또한, 스핀-스프레이 공정을 이용하여 산화그래핀 박막을 4층까지 적층을 하였고 86% 이상의 투명도를 확보하였다. 이와 같은 합성된 산화그래핀 박막소재의 스핀-스프레이 코팅 기술은 다양한 전자제품들의 display를 대면적으로 코팅할 수 있을 것으로 기대되어진다.

In this study, we synthesized graphene oxide and developed novel spin-spray coating technology. The graphene oxide thin film was uniformly coated on amine-functionalized glass surfaces using spin-spray coating technology. We also stacked up to four layers of graphene oxide on glass substrates in a uniform manner. From the results, we infer that this spin-spray coating of graphene oxide thin film could be a powerful tool for various electronic display coating applications.

키워드

참고문헌

  1. Jeong, J. -I. and Yang, J. -H., 2011, "Trend and Prospect of Thin Film Processing Technology," Journal of the Korean Magnetics Society, Vol. 21, No. 5, pp. 185-192. https://doi.org/10.4283/JKMS.2011.21.5.185
  2. Geim, A. K. and Novoselov, K. S., 2007, "The Rise of Graphene," Nature, Vol. 6, pp. 183-191. https://doi.org/10.1038/nmat1849
  3. Geim, A. K., 2009, "Graphene: Status and Prospects," Science, Vol. 324, No. 5934, pp. 1530-153. https://doi.org/10.1126/science.1158877
  4. Dong, X., Su, C. -Y., Zhang, W., Zhao, J., Ling, Q., Huang, W., Chen, P. and Li, L. -J., 2010, "Ultra-large Single-layer Graphene Obtained From Solution Chemical Reduction and Its Electrical Properties," Physical Chemistry Chemical Physics, Vol. 12, pp. 2164-2169. https://doi.org/10.1039/b914546j
  5. Becerril, H. A., Mao, J., Liu, Z., Stoltenberg, R. M., Bao, Z. and Chen, Y., 2008, "Evaluation of Solution-Processed Reduced Graphene Oxide Films as Transparent Conductors," ACS Nano, Vol. 2, No. 3, pp. 463-470. https://doi.org/10.1021/nn700375n
  6. Pham, V. H., Cuong, T. V., Hur, S. H., Shin, E. W., Kim, J. S., Chung, J. S. and Kim, E. J., 2010, "Fast and Simple Fabrication of A Large Transparent Chemically-converted Graphene Film by Spray-coating," Carbon, Vol. 48, No. 7, pp. 1945-1951. https://doi.org/10.1016/j.carbon.2010.01.062
  7. Liang, H., Bu, Y., Zhang, J., Cao, Z. and Liang, A., 2013, "Graphene Oxide Film as Solid Lubricant," ACS Applied Materials & Interfaces, Vol. 5, No. 13, pp. 6369-6375. https://doi.org/10.1021/am401495y
  8. Hummers Jr., W. S. and Offeman, R. E., 1958, "Preparation of Graphitic Oxide," Journal of the American Chemical Society, Vol. 80, No. 6, pp. 1339-1339. https://doi.org/10.1021/ja01539a017
  9. Wang, W. and Vaughn, M. W., 2008, "Morphology and Amine Accessibility of (3-Aminopropyl) Triethoxysilane Films on Glass Surfaces," Scanning, Vol. 30, No. 2, pp. 65-77. https://doi.org/10.1002/sca.20097
  10. Paredes, J. I., Villar-Rodil, S., Martinez-Alonso, A. and Tasco'n, J. M. D., 2008, "Graphene Oxide Dispersions in Organic Solvents," Langmuir, Vol. 24, No. 19, pp. 10560-10564. https://doi.org/10.1021/la801744a