Current Photovoltaic Research

  • 제3권3호
  • /
  • Pages.71-74
  • /
  • 2015
  • /
  • 2288-3274(pISSN)
  • /
  • 2508-125X(eISSN)
한국태양광발전학회 (Korea Photovoltaic Society)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and Characterization of Soluble Polyaniline and TiO2 Composite

  • Kim, Byoung-Ju (Department of New and Renewable Energy, Kyungil University) ;
  • Kang, Kwang-Sun (Department of New and Renewable Energy, Kyungil University)
  • 투고 : 2015.07.21
  • 심사 : 2015.07.29
  • 발행 : 2015.09.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Soluble polyaniline was synthesized by attaching titanium isoproxide ($Ti(OPr)_4$) to the amine group of the aniline. Approximately 1 to 1 molar ratio of aniline and $Ti(OPr)_4$ was mixed and polymerized with ammonium persulfate. The FTIR result showed clear difference between $TiO_2$-aniline composite ($TiO_2An$) and $TiO_2$-polyaniline composite ($TiO_2PAn$). Although the $TiO_2An$ had negligible UV-visible absorption, the $TiO_2PAn$ showed strong absorption in the UV-visible region. Photoluminescence (PL) peaks of $TiO_2An$ were shifted toward red with the reduction of the excitation energy, which could be due to the multiple emission centers. The luminescence peak shift stopped at 501 nm. The PL spectra of $TiO_2PAn$ exhibited three emission peaks at 2.88 eV (430 nm), 2.48 eV (501 nm) and 2.22 eV (558 nm). The new emission center (2.22 eV) was observed after polymerization. Field emission scanning electron microscope image showed crack-free composite film.

키워드

참고문헌

  1. Nasirian, S., Moghaddam, H. M., "Polyaniline assisted by Ti$O_2$:Sn$O_2$ nanoparticles as a hydrogen gas sensor at environmental conditions," Vol. 328, pp 395-404, 2015. https://doi.org/10.1016/j.apsusc.2014.12.051
  2. Rajabi, S., Shogh, A., Iraji, zad., "Defect study of Ti$O_2$ nanorods grown by a hydrothermal method through photoluminescence spectroscopy," J. Luminescence Vol. 157, pp 235-242, 2015. https://doi.org/10.1016/j.jlumin.2014.08.035
  3. Zheng, J., Bao, S., Jin, P., "Ti$O_2$(R)/V$O_2$(M)/Ti$O_2$(A) multilayer film as smart window: Combination of energy-saving, antifogging and self-cleaning functions," Nano Energy, Vol. 11, pp 136-145, 2015. https://doi.org/10.1016/j.nanoen.2014.09.023
  4. Wang, J., He, B., Kong, X. Z., "A study on the preparation of floating photocatalyst supported by hollow Ti$O_2$ and its performance," Applied Surface Sci. Vol. 327, pp 406-412, 2015. https://doi.org/10.1016/j.apsusc.2014.11.112
  5. Sarantopoulos, C., Puzenat, E., Guillard, C., Hermann, J. M., Gleizes, A. N., Maury, F., "Microfibrous Ti$O_2$ supported photocatalysts prepared by metal-organic chemical vapor infiltration for indoor air and waste water purification," Applied Catalysis B: Environmental Vol. 91, pp 225-233, 2009. https://doi.org/10.1016/j.apcatb.2009.05.029
  6. Salvador, A., Pascual-Marti, M. C., Adell, J. R., Requeni, A., March, J. G., "Analytical methodologies for atomic spectrometric determination of metallic oxides in UV sunscreen creams," J. Pharmaceutical Biomedical Analysis, Vol. 22, pp 301-306, 2000. https://doi.org/10.1016/S0731-7085(99)00286-1
  7. Parthiban, S., Anuratha, K. S., Arunparabaharan, S., Abinesh, S., Lakshminarasimhan, N., "Influence of FO incorporation in Ti$O_2$ nanofibers on the electrode efficiency in dye-sensitized solar cells," Ceramics Inter. Vol. 41, pp 1205-1212, 2015. https://doi.org/10.1016/j.ceramint.2014.09.049
  8. Dziewonski, P. M., Grzeszczuk, M., "Towards $TiO_2$-conducting polymer hybrid materials for lithium ion batteries," Electrochimica Acta Vol. 55, pp 3336-3347, 2010. https://doi.org/10.1016/j.electacta.2010.01.043
  9. Barman, S., Deng, F., McCreey, R. L., "Conducting polymer memory devices based on dynamic doping," J. Am. Chem. Soc. Vol. 130, pp 11073-11081, 2008. https://doi.org/10.1021/ja802673w
  10. Gurunathan, K., Amalnerkar, D. P., Trivedi, D. C., "Synthesis and characterization of conducting polymer composite ($PAn/TiO_2$) for cathode material in rechargeable battery," Mater. Lett. Vol. 57, pp 1642-1648, 2003. https://doi.org/10.1016/S0167-577X(02)01045-5
  11. Mahulikar, P. P., Jadhav, R. S., Hundiwale, D. G., "Performance of polyaniline/$TiO_2$ nanocomposites in epoxy for corrosion resistant coatings," Iranian Poly. J. Vol. 20, pp 367-376, 2011.
  12. Radhakrishnan, S., Siju, C. R., Mahanta, D., Patil, S., Madras, G., "Conducting polyaniline-nano-$TiO_2$ composites for smart corrosion resistant coatings," Electrochimica Acta Vol. 54, pp 1249-1254, 2009. https://doi.org/10.1016/j.electacta.2008.08.069
  13. Xu, H., Cao, Q., Wang, X., Li, W., Li, X., Deng, H., "Properties and chemical oxidation polymerization of polyaniline/ neutral red/$TiO_2$ composite electrodes," Mater. Sci. Eng. B Vol. 171, pp 104-108, 2010. https://doi.org/10.1016/j.mseb.2010.03.081
  14. Nasirian, S., Moghaddam, H. M., "Polyaniline assisted by $TiO_2$:$SnO_2$ nanoparticles as a hydrogen gas sensor at environmental conditions," Applied Surface Sci. Vol. 328, pp 395-404, 2015. https://doi.org/10.1016/j.apsusc.2014.12.051
  15. Li, J., Zhao, X., Zhang, Z., Lai, Y., "Facile synthesis of hollow carbonized polyaniline spheres to encapsulate selenium for advanced rechargeable lithium-selenium batteries," J. Alloys and Compounds Vol. 619, pp 794-799, 2015. https://doi.org/10.1016/j.jallcom.2014.09.099
  16. Bian, C., Yu, A., Wu, H., "Fibriform polyaniline/nano-$TiO_2$ composite as an electrode material for aqueous redox supercapacitors," Electrochem. Commun. Vol. 11, pp 266-269, 2009. https://doi.org/10.1016/j.elecom.2008.11.026
  17. Gurunathan, K., Amalnerkar, D. P., Trivedi, D. C., "Synthesis and characterization of conducting polymer composite (PAn/$TiO_2$) for cathode material in rechargeable battery," Mater. Lett. Vol. 57, pp 1642-1648, 2003. https://doi.org/10.1016/S0167-577X(02)01045-5
  18. Fu, X., Jia, C., Wan, Z., Weng, X., Xie, J., Deng, L., "Hybrid electrochromic film based on polyaniline and $TiO_2$ nanorods array," Organic Electronics Vol. 15, pp 2702-2709, 2014. https://doi.org/10.1016/j.orgel.2014.07.040
  19. Kwong, C. Y., Choy, W. C. H., Djuristic, A. B., Chui, P. C., Cheng, K. W., Chan, W. K., "Poly(3-hexylthiophene):$TiO_2$ nanocomposites for solar cell applications," Nanotechnol. Vol. 15, pp 1156, 2004. https://doi.org/10.1088/0957-4484/15/9/008