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개방식 장치를 이용한 난연성-가연성 이성분계 혼합물(CCl4+o-Xylene and CCl4+p-Xylene)의 인화점 측정

The Measurement of Flash Point for Unflammable-Flammable Binary Mixtures(CCl4+o-Xylene and CCl4+p-Xylene) Using Open Cup Tester

  • 김창섭 (세명대학교 대학원 소방방재공학과) ;
  • 이성진 (세명대학교 임상병리학과) ;
  • 하동명 (세명대학교 보건안전공학과)
  • Kim, Chang-Seob (Department of Fire and Disaster Engineering, Graduate School, Semyung University) ;
  • Lee, Sungjin (Department of Clinical Laboratory Science, Semyung University) ;
  • Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University)
  • 투고 : 2015.09.30
  • 심사 : 2015.11.15
  • 발행 : 2015.12.31

초록

인화점은 인화성에 따라 가연성 액체들을 분류하기 위해 사용된다. 인화점은 인화성 액체를 안전하게 저장, 취급 수송하기 위한 중요한 정보이다. Tag 개방식 장치를 이용하여 두 개의 이성분계 혼합물($CCl_4+o-xylene$ and $CCl_4+p-xylene$)의 인화점을 측정하였다. 또한 라울의 법칙, UNIQUAC 식, 경험식을 이용하여 인화점을 계산하여 그 값을 측정치와 비교하였다. 이 중 경험식에 의한 인화점 계산치가 가장 측정치를 잘 모사하였다.

The flash point is used to categorize inflammable liquids according to their relative flammability. The flash point is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures($CCl_4+o-xylene$ and $CCl_4+p-xylene$) has been measured for the entire concentration range using Tag open cup tester. The flash point temperature was estimated using Raoult's law, UNIQUAC model and empirical equation. The experimentally derived flash point was also compared with the predicted flash point. The empirical equation is able to estimate the flash point fairly well for $CCl_4+o-xylene$ and $CCl_4+p-xylene$ mixture.

키워드

참고문헌

  1. Phoon, L. Y., Mustaffa, A. A., Hashim, Mat, H. R. : "A Review of Flash Point Prediction Models for Flammable Liquid Mixtures", Ind. Eng. Chem. Res., Vol. 53, 12523-12565, (2014)
  2. Crowl, D. A. and Louver, J. F.: "Chemical Process Safety Fundamentals with Applications", Prentice-Hall, (1990)
  3. Lance, R. C., Barnard, A. J., Hooymanm, J. E. : "Measurement of Flash Points : Apparatus, Methodology, Applications", J. of Hazardous Materials, Vol. 3, 107-119, (1979) https://doi.org/10.1016/0304-3894(79)85008-6
  4. Affens, W. A. and Mclaren, G. W. : "Flammability Properties of Hydrocarbon Solutions in Air", J. of Chem. Ind. Eng. Chem., Vol. 17, No. 4, 482-488, (1972)
  5. Chatelier, H. L. : "Estimation of Firedamp by Flammability Limits", Ann. Minmes, Vol. 19, No. 8, 388-395, (891)
  6. Hanley, B. : "A Model for the Calculation and the Verification of Closed Cup Flash Points for Multicomponent Mixtures", Process Saf. Prog., Vol. 17, No. 2, 86-97, (1998) https://doi.org/10.1002/prs.680170204
  7. Poling, B. E., Prausnitz, J. M., O'Connell, J. P. : "The Properties of Gases and Liquids", 5th Ed., McGraw-Hill, New York, (2001)
  8. Liaw, H. J., Lee, Y. H., Tang, C. L., Hsu H. H., Liu, J. H. : "A Mathematical Model for Predicting the Flash Point of Binary Solutions", J. of Loss Prevention in the Process Industries, Vol. 15, 429-438, (2002) https://doi.org/10.1016/S0950-4230(02)00068-2
  9. Ha, D. M., Lee S. J., Back, M. H. : "The Measurement and Estimation of the Lower Flash Points for the Flammable Binary Systems Using Tag Open-Cup Tester", Korean J. Chem. Eng., Vol. 24, No. 4, 551-555, (2007) https://doi.org/10.1007/s11814-007-0001-2
  10. Wilson, G. M. : "Vapor Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing", Journal of the American Chemical Society, Vol. 86, 127-130, (1964) https://doi.org/10.1021/ja01056a002
  11. Ha, D. M. and Lee, S. J. : "The Measurement of the Lower Flash Points for Binary Mixtures", J. of the Korean Society of Safety , Vol. 28, No. 1, 35-39, (2013) https://doi.org/10.14346/JKOSOS.2013.28.1.035
  12. In 2011 Annual Book of ASTM Standards ; ASTM International, : "Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus(ASTM D3278)", West Conshohocken, PA, (2011)
  13. Gmehing, J., Onken U., Arlt, W. : "Vapor-Liquid Equilibrium Data Collection", Vol. 1, Part1-Part7, DECHEMA, (1980)
  14. Lim, J., Jang, S., Kim, H., Cho, H. K., Shin, M. S. : "Solubility of Triclocarban in Pure Alkanols at Different Temperatures", Korean J. Chem. Eng., Vol. 30, No. 1, 181-186, (2013) https://doi.org/10.1007/s11814-012-0099-8