DOI QR코드

DOI QR Code

Competitive Adsorption in Binary Solution with Different Mole Ratio of Sr and Cs by Zeolite A : Adsorption Isotherm and Kinetics

스트론튬과 세슘 이온의 혼합 몰비를 달리한 이성분 용액에서 제올라이트 A에 의한 경쟁 흡착: 흡착등온 및 속도해석

  • Lee, Chang-Han (Department of Environmental Adminstration, Catholic University of Pusan) ;
  • Park, Jeong-Min (Department of Chemical Engineering, Pukyong National University) ;
  • Lee, Min-Gyu (Department of Chemical Engineering, Pukyong National University)
  • 이창한 (부산가톨릭대학교 환경행정학과) ;
  • 박정민 (부경대학교 화학공학과) ;
  • 이민규 (부경대학교 화학공학과)
  • Received : 2014.09.04
  • Accepted : 2014.11.12
  • Published : 2015.02.27

Abstract

The adsorption characteristics of Sr ions and Cs ions in single and binary solution by zeolite A were investigated in batch experiment. The adsorption rate of Sr ions and Cs ions by zeolite A obeyed pseudo-second-order kinetic model in single and binary solution. The initial adsorption rates (h) and adsorption capacities of both ions obtained from pseudo-second-order kinetic model, and the values were decreased with increasing concentration of the competitive ions (0~1.5 mM). Also, adsorption isotherm data in binary solution were well fitted to the extended Langmuir model, the maximum adsorption capacities of Sr and Cs calculated from the model were 1.78 mmol/g and 1.64 mmol/g, respectively. The adsorption of Sr and Cs ions by zeolite A was carried out in the presence of other cations such as $Na^+$, $K^+$, $Mg^{2+}$ and $Ca^{2+}$. The results showed that the zeolite A can maintain a relatively high adsorption capacity for Sr and Cs ions and exhibits a high selectivity in the presence of competitive cations. The effect of competition had an order of $Ca^{2+}$ > $K^+$ > $Mg^{2+}$ > $Na^+$ for Sr ions and $K^+$ > $Ca^{2+}$ > $Na^+$ > $Mg^{2+}$ for Cs ions at the same cation concentration.

Keywords

References

  1. Alinnor, I. J., 2007, Adsorption of heavy metal ions from aqueous solution by fly ash, Fuel, 86, 853-857. https://doi.org/10.1016/j.fuel.2006.08.019
  2. Caputo, D., Pepe, F., 2007, Experiments and data processing of ion exchange equilibria involving Italian natural zeolites: a review, Micropor. Mesopor. Mater., 105, 222-231. https://doi.org/10.1016/j.micromeso.2007.04.024
  3. Chen, D. Z., Zhang, J. X., Chen, J. M., 2010, Adsorption of methyl tert-butyl ether using granular activated carbon: Equilibrium and kinetic analysis, Intern. J. Environ. Sci. Technol., 7(2), 235-242. https://doi.org/10.1007/BF03326133
  4. Chegrouche, S., Mellah, A., Barkat, M., 2009, Removal of strontium from aqueous solutions by adsorption onto activated carbon: kinetic and thermodynamic studies, Desalination, 235(1), 306-318. https://doi.org/10.1016/j.desal.2008.01.018
  5. Choy, K. K., Ko, D. C., Cheung, C. W., Porter, J. F., McKay, G., 2004, Film and intraparticle mass transfer during the adsorption of metal ions onto bone char, Journal of colloid and interface science, 271(2), 284-295. https://doi.org/10.1016/j.jcis.2003.12.015
  6. Depci, T., Kul, A. R., Onal, Y., 2012, Competitive adsorption of lead and zinc from aqueous solution on activated carbon prepared from Van apple pulp: Study in single- and multi-solute systems, Chem. Eng. J., 200, 224-236.
  7. El-Kamash, A. M., 2008, Evaluation of zeolite A for the sorptive removal of Cs$^+$ and Sr$^{2+}$ ions from aqueous solutions using batch and fixed bed column operations, J. Hazard. Mater., 151(2), 432-445. https://doi.org/10.1016/j.jhazmat.2007.06.009
  8. Hafizi, M., Abolghasemi, H., Moradi, M., Milani, S. A., 2011, Strontium adsorption from sulfuric acid solution by Dowex 50W-X resins, Chinese J. Chem. Eng., 19(2), 267-272. https://doi.org/10.1016/S1004-9541(11)60164-X
  9. Hui K. S., Chao C.Y.H., Kot S.C., 2005, Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash, J. of Hazar. Mat., 127(1-3), 89-101. https://doi.org/10.1016/j.jhazmat.2005.06.027
  10. Kang, S. Y., Lee, J. U., Moon, S. H., Kim, K. W., 2004. Competitive adsorption characteristics of Co$^{2+}$, Ni$^{2+}$, and Cr$^{3+}$ by IRN-77 cation exchange resin in synthesized wastewater. Chemosphere, 56, 141-147 https://doi.org/10.1016/j.chemosphere.2004.02.004
  11. Khan, S. A., Riaz-ur-Rehman A., Khan, M. A., 1995, Adsorption of chromium (III), chromium (VI) and silver (I) on bentonite, Waste Manage., 15(4), 271-282. https://doi.org/10.1016/0956-053X(95)00025-U
  12. Kocherginsky, N. M., Zhang, Y. K., Stucki, J. W., 2002, D2EHPA based strontium removal from strongly alkaline nuclear waste, Desalination, 144(1), 267-272. https://doi.org/10.1016/S0011-9164(02)00326-0
  13. Leppert, D., 1990, Heavy metal sorption with clinoptilolite zeolite: alternatives for treating contaminated soil and water, Mining Eng., 42(6), 604-608.
  14. Li, L., Liu, F., Jing, X., Ling, P., Li, A., 2011, Displacement mechanism of binary competitive adsorption for aqueous divalent metal ions onto a novel IDA-chelating resin: isotherm and kinetic modeling, Water Res., 45(3), 1177-1188. https://doi.org/10.1016/j.watres.2010.11.009
  15. Liu, H., Wang, C., Liu, J., Wang, B., Sun, H., 2013, Competitive adsorption of Cd (II), Zn (II) and Ni (II) from their binary and ternary acidic systems using tourmaline, J. Environ. Manage., 128, 727-734. https://doi.org/10.1016/j.jenvman.2013.06.024
  16. Malamis, S., Katsou, E., 2013, A review on zinc and nickel adsorption on natural and modified zeolite, bentonite and vermiculite: Examination of process parameters, kinetics and isotherms, J. Hazard. Mater., 252-253(15), 428-461. https://doi.org/10.1016/j.jhazmat.2013.03.024
  17. Mathews, A. P., Weber Jr, W. J., 1977, Effects of external mass transfer and intraparticle diffusion on adsorption rates in slurry reactors, Am. Inst. Chem. Eng. Symp. Ser. 73, 91-107.
  18. Park, Y., Lee, Y. C., Shin, W. S., Choi, S. J., 2010, Removal of cobalt, strontium and cesium from radioactive laundry wastewater by ammonium molybdophosphate-polyacrylonitrile (AMP PAN), Chem. Eng. J., 162, 685-695. https://doi.org/10.1016/j.cej.2010.06.026
  19. Petrus, R., Warchol, J. K., 2005. Heavy metal removal by clinoptilolite, An equilibrium study in multi-component systems, Water Res., 39, 819-830. https://doi.org/10.1016/j.watres.2004.12.003
  20. Shawabkeh, R. A., Rockstraw, D. A., Bhada, R. K., 2002, Copper and strontium adsorption by a novel carbon material manufactured from pecan shells, Carbon, 40(5), 781-786. https://doi.org/10.1016/S0008-6223(01)00198-1
  21. Sheha, R. R., El-Khouly, S. H., 2013, Adsorption and diffusion of cesium ions in zirconium (IV) iodomolybdate exchanger, Chem. Eng. Res. Design, 91(5), 942-954. https://doi.org/10.1016/j.cherd.2012.09.007
  22. Sahai, N., Carroll, S. A., Roberts, S., O'Day, P. A., 2000, X-ray absorption spectroscopy of strontium (II) coordination: II. Sorption and precipitation at kaolinite, amorphous silica, and goethite surfaces, J. Colloid. Interf. Sci., 222(2), 198-212. https://doi.org/10.1006/jcis.1999.6562
  23. Sljivic, M., Smiciklas, I., Plecas, I., Pejanovic, S., 2011, The role of external and internal mass transfer in the process of Cu$^{2+}$ removal by natural mineral sorbents. Environ. Technol., 32(9), 933-943. https://doi.org/10.1080/09593330.2010.521952
  24. Smiciklas, I., Dimovic, S., Plecas, I., 2007, Removal of Cs$^{1+}$, Sr$^{2+}$ and Co$^{2+}$ from aqueous solutions by adsorption on natural clinoptilolite, Appl. Clay Sci., 35(1), 139-144. https://doi.org/10.1016/j.clay.2006.08.004
  25. Vadivelan, V., Kumar, K. V., 2005, Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk, J. Colloid Interf. Sci., 286(1), 90-100. https://doi.org/10.1016/j.jcis.2005.01.007
  26. Weber, W. J., Morris, J. C., 1963, Kinetics of adsorption on carbon solution, J. Sanitary Eng. Div. Am. Soc. Civ. Eng., 89, 31-39.
  27. Wan Ngah, W. S., Isa, I. M., 1998, Comparison study of copper ion adsorption on chitosan, Dowex A-1, and Zerolit 225, J. Appl. Polym. Sci., 67, 1067-1070. https://doi.org/10.1002/(SICI)1097-4628(19980207)67:6<1067::AID-APP14>3.0.CO;2-Y
  28. Wu, J., Li, B., Liao, J., Feng, Y., Zhang, D., Zhao, J., Wen, W., Yang, Y., Liu, N., 2009, Behavior and analysis of cesium adsorption on montmorillonite mineral, J. Environ. Radioact., 100, 914-920. https://doi.org/10.1016/j.jenvrad.2009.06.024

Cited by

  1. Removal of Sr and Cs ions by SAN-Zeolite Beads Prepared by Immobilization of Zeolite with SAN vol.24, pp.11, 2015, https://doi.org/10.5322/JESI.2015.24.11.1331
  2. Preparation of Novel PS-zeolite Beads Immobilized Zeolite with Polysulfone for Radioactive Materials vol.37, pp.3, 2015, https://doi.org/10.4491/KSEE.2015.37.3.145
  3. Adsorption Characteristics of Radioactive Cs Ion by Zeolite X vol.39, pp.2, 2017, https://doi.org/10.4491/KSEE.2017.39.2.66
  4. Adsorption Characteristics of As and Se Ions by HTMAB Modified Anthracite vol.27, pp.3, 2018, https://doi.org/10.5322/JESI.2018.27.3.167