한국수소및신에너지학회논문집 (Journal of Hydrogen and New Energy)

  • 제26권1호
  • /
  • Pages.8-14
  • /
  • 2015
  • /
  • 1738-7264(pISSN)
  • /
  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
권호 표지
DOI QR코드

DOI QR Code

다양한 촉매들을 통한 모델 바이오매스-초임계수 촉매 가스화에서 수소 생산 성능에 대한 연구

The Study on of Hydrogen Production Performance by Model Biomass-supercritical Water Gasification with Various Catalysts

  • 허동현 (전북대학교 자원에너지공학과) ;
  • 황종하 (전북대학교 자원에너지공학과) ;
  • 이루세 (전북대학교 자원에너지공학과) ;
  • 손정민 (전북대학교 자원에너지공학과)
  • Heo, Dong Hyun (Department of Mineral Resources and Energy Engineering, Chonbuk National University) ;
  • Hwang, Jong Ha (Department of Mineral Resources and Energy Engineering, Chonbuk National University) ;
  • Lee, Roosse (Department of Mineral Resources and Energy Engineering, Chonbuk National University) ;
  • Sohn, Jung Min (Department of Mineral Resources and Energy Engineering, Chonbuk National University)
  • 투고 : 2015.02.09
  • 심사 : 2015.02.28
  • 발행 : 2015.02.28
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

In this study, the model biomass was used for hydrogen production by supercritical water gasification (SCWG). Model biomasses were glycerol, glycine, lignin and cellulose. The feed concentration was set to 1 wt%. Experiments were conducted in a reactor at $440^{\circ}C$ and above 26.3 MPa for 30 min. The effects of catalysts such as alkali metal salt ($K_2CO_3$ and $Na_2CO_3$) and transition metal salts ($Ni(NO_3)_2$, $Fe(NO_3)_3$ and $Mn(NO_3)_2$) on the gasification were systematically investigated. No tar or coke was observed in all experiments. The results showed that the gasification efficiency increased with various catalysts. For the cellulose and glycerol, all catalysts were effective for the promoted $H_2$ production compared with no catalyst. The significant decrease of $H_2$ production compared with no catalyst was observed with $Na_2CO_3$ and $Fe(NO_3)_3$ for glycine and lignin. respectively. The highest H2 production, 1.24 mmol was obtained for glycerol-SCWG with $Mn(NO_3)_2$. Conclusively, the addition of $Mn(NO_3)_2$ enhanced all model biomass gasification efficiency and increased the hydrogen production promoting the supercritical water reaction.

키워드

참고문헌

  1. Y. Guo, S. Z. Wang, D. H. Xu, Y. M. Gong, H. H. Ma, X. Y. Tang, "Review of catalytic supercritical water gasification for hydrogen production from biomass", Renewable and Sustainable Energy Reviews, Vol. 14, 2010, p. 334-343. https://doi.org/10.1016/j.rser.2009.08.012
  2. S. J. Yoon, Y. C. Choi, J. G. Lee, "Hydrogen production from biomass tar by catalytic steam reforming", Energy Conversion and Management, Vol. 51, 2010, p. 42-47. https://doi.org/10.1016/j.enconman.2009.08.017
  3. S. J. Yoon, J. G. Lee, H. W. Ra, M. W. Seo, "Supercritical Water Gasification of Low Rank Coal with High Moisture Content", Trans. of the Korean Hydrogen and New Energy Society, Vol. 24, No. 4, 2013, p. 340-346. https://doi.org/10.7316/KHNES.2013.24.4.340
  4. D. I. Kim, J. G. Lee, Y. K. Kim, S. J. Yoon, "The Characteristics of Coal Gasification using Microwave Plasma", Trans. of the Korean Hydrogen and New Energy Society, Vol. 23, No. 1, 2012, p. 93-99. https://doi.org/10.7316/khnes.2012.23.1.093
  5. J. Tao, L. Zhao, C. Dong, Qiang Lu, X. Du, E. Dahlquist, "Catalytic Steam Reforming of Toluene as a Model Biomass Gasification Tar Compound using Ni-$CeO_2$/SBA-15 Catalysts", Energies, Vol. 6, 2013, p. 3284-3296. https://doi.org/10.3390/en6073284
  6. R. Yin, R. Liu, J. Wu, X. Wu, C. Sun, C. Wu, "Influence of particle size on performance of a pilot-scale fixed-bed gasification system", Bioresource Technol, Vol. 119, 2012, p. 15-21 https://doi.org/10.1016/j.biortech.2012.05.085
  7. G. Guan, G. Chen, Y. Kasai, E. W. C. Lim, X. Hao, M. Kaewpanh, A. Abuliti, C. Fushimie, A. Tsutsumi, "Catalytic steam reforming of biomass tar over iron- or nickel-based catalyst supported on calcined scallop shell", Applied Catalysis B: Environmental, Vol. 115-116, 2012, p. 159-168. https://doi.org/10.1016/j.apcatb.2011.12.009
  8. A. Kruse, T. Henningsen, A. Sinag, and J. Pfeiffer, "Biomass gasification in supercritical water: influence of the dry matter content and the formation of phenols", Ind Eng Chem Res, Vol 42, No. 16, 2003, p. 3711-3717. https://doi.org/10.1021/ie0209430
  9. X. Xu, Y. Matsumura, J. Stenberg, M. J. Antal, Jr., "Carbon-catalyzed gasification of organic feedstocks in supercritical water", Ind Eng Chem Res, Vol. 35, No. 8, 1996, p. 2522-2530. https://doi.org/10.1021/ie950672b
  10. P. E. Savage, "A perspective on catalysis in suband supercritical water", Journal of Supercritical Fluids, Vol. 47, 2009, p. 407-414. https://doi.org/10.1016/j.supflu.2008.09.007
  11. A. A. Peterson, F. Vogel, R. P. Lachance, M. Froling, M. J. Antal, J. W. Tester, "Thermochemical biofuel production in hydrothermal media: a review of suband supercritical water technologies", Energy and Environmental Science, Vol. 1, 2008, p. 32-65. https://doi.org/10.1039/b810100k
  12. L. J. Guo, Y. J. Lu, X. M. Zhang, C. M. Ji, Y. Guan, A. X. Pei, "Hydrogen production by biomass gasification in supercritical water: a systematic experimental and analytical study", Catalysis Today, Vol. 129, 2007, p. 275-286. https://doi.org/10.1016/j.cattod.2007.05.027
  13. Y. Matsumura, T. Minowa, B. Potic, S. R. A. Kersten, W. Prins, PS. Willibrordus, et al, "Biomass gasification in near- and supercritical water: status and prospects", Biomass Bioenergy, Vol. 29, 2005, p. 269-292. https://doi.org/10.1016/j.biombioe.2005.04.006
  14. Y. Calzavara, C. Joussot-Dubien, G. Boissonnet, S. Sarrade, "Evaluation of biomass gasification in supercritical water process for hydrogen production", Energy Convers Manage, Vol. 46, 2005, p. 615-631. https://doi.org/10.1016/j.enconman.2004.04.003
  15. M. Watanabe, H. Inomata, K. Arai, "Catalytic hydrogen generation from biomass (glucose and cellulose) with $ZrO_2$ in supercritical water", Biomass Bioenergy, Vol. 22, 2002, p. 405-410. https://doi.org/10.1016/S0961-9534(02)00017-X
  16. A. Kruse, D. Meier, P. Rimbrecht, M. Schacht, "Gasification of pyrocatechol in supercritical water in the presence of potassium hydroxide", Ind Eng Chem Res, Vol. 39, 2000, p. 4842-4848. https://doi.org/10.1021/ie0001570
  17. M. Osada, T. Sato, M. Watanabe, T. Adschiri, K. Arai, "Low temperature catalytic gasification of lignin and cellulose with a ruthenium catalyst in supercritical water". Energy Fuels, Vol. 18, 2004, p. 327-333. https://doi.org/10.1021/ef034026y
  18. J. Wang, T. Takarada, "Role of calcium hydroxide in supercritical water gasification of low-rank coal". Energy Fuels, Vol. 15, 2001, p. 356-362. https://doi.org/10.1021/ef000144z
  19. A. J. Byrd, K. K. Pant, R. B. Gupta, "Hydrogen production from glycerol by reforming in supercritical water over Ru/$Al_2O_3$ catalyst", Fuel, Vol. 87, 2008, p. 2956-2960. https://doi.org/10.1016/j.fuel.2008.04.024
  20. N. Ding, R. Azargohar, A. K. Dalai, J. A. Kozinski, "Catalytic gasification of glucose to H2 in supercritical water", Fuel Processing Technology, Vol. 127, 2014, p. 33-40. https://doi.org/10.1016/j.fuproc.2014.05.014
  21. S. Guo, L. Guo, C. Cao, J. Yin, Y. Lu, X. Zhang, "Hydrogen production from glycerol by supercritical water gasification in a continuous flow tubular reactor", International Journal of Hydrogen Energy, Vol. 37, No. 7, 2012, p. 5559-5568. https://doi.org/10.1016/j.ijhydene.2011.12.135
  22. D. Xu, S. Wang, X. Hu, C. Chen, Q. Zhang, Y. Gong, "Catalytic gasification of glycine and glycerol in supercritical water", International Journal of Hydrogen Energy, Vol. 34, No. 13, 2009, p.5357-5364. https://doi.org/10.1016/j.ijhydene.2008.08.055
  23. L. Zhang, P. Champagne, C. C. Xu, "Screening of supported transition metal catalysts for hydrogen production from glucose via catalytic supercritical water gasification", International Journal of Hydrogen Energy, Vol. 36, No. 16, 2011, p. 9591-9601. https://doi.org/10.1016/j.ijhydene.2011.05.077
  24. G. Schuster, G. Loffler, K. Weigl, H. Hofbauer, "Biomass steamgasification - an extensive parametric modeling study", Bioresource Technology, Vol. 77, 2001, p. 71-79. https://doi.org/10.1016/S0960-8524(00)00115-2