DOI QR코드

DOI QR Code

Modeling of damage in cement paste subject to external sulfate attack

  • Xiong, Chuansheng (College of Mechanics and Materials, Hohai University) ;
  • Jiang, Linhua (College of Mechanics and Materials, Hohai University) ;
  • Zhang, Yan (College of Mechanics and Materials, Hohai University) ;
  • Chu, Hongqiang (College of Mechanics and Materials, Hohai University)
  • 투고 : 2015.08.13
  • 심사 : 2015.12.16
  • 발행 : 2015.12.25

초록

This study aimed to develop models of sulfate diffusion and ettringite content profile in cement paste for the predication of the damage behavior in cement paste subject to external sulfate. In the models, multiphase reaction equilibrium between ions in pore solution and solid calcium aluminates phases and the microstructure changes in different positions of cement paste were taken into account. The distributions of expansive volume strain and expansion stress in cement paste were calculated based on the ettringite content profile model. In addition, more sulfate diffusion tests and SEM analyses were determined to verify the reliability and veracity of the models. As the results shown, there was a good correlation between the numerical simulation results and experimental evidences. The results indicated that the water to cement ratio (w/c) had a significant influence on the diffusion of sulfate ions, ettringite concentration profile and expansion properties in cement paste specimens. The cracking points caused by ettringite growth in cement paste specimens were predicted through numerical methods. According to the simulation results, the fracture of cement paste would be accelerated when the specimens were prepared with higher w/c or when they were exposed to sulfate solution with higher concentration.

키워드

과제정보

연구 과제 주관 기관 : Ministry of Science and Technology of China, National Natural Science Foundation of China

참고문헌

  1. Bary, B., Leterrier, N., Deville, E. and Bescop, P.L. (2014), "Coupled chemo-transport-mechanical modelling and numerical simulation of external sulfate attack in mortar", Cement Concrete Comp., 49(5), 70-83. https://doi.org/10.1016/j.cemconcomp.2013.12.010
  2. Basista, M. and Weglewski, W. (2008), "Micromechanical modeling of sulphate corrosion in concrete: influence of ettringite forming reaction", Theor. Appl.Mech., 35(2), 29-52. https://doi.org/10.2298/TAM0803029B
  3. Bassuoni, M.T. and Nehdi, M.L. (2008), "Neuro-fuzzy based prediction of the durability of selfconsolidating concrete to various sodium sulfate exposure regimes", Comput. Concrete, 5(6), 573-597. https://doi.org/10.12989/cac.2008.5.6.573
  4. Bonakdar, A., Mobasher, B. and Chawla, N. (2012), "Diffusivity and micro-hardness of blended cement materials exposed to external sulfate attack", Cement Concrete Comp., 34(1), 76-85. https://doi.org/10.1016/j.cemconcomp.2011.08.016
  5. Diamidot, D. and Glasser F.P. (1993), "Thermodynamic investigation of the CaO-$Al_2O_3$-$CaSO_4{\cdot}2H_2O$ system at $25^{\circ}C$ and the influence of Na2O", Cement Concrete Res., 23(1), 221. https://doi.org/10.1016/0008-8846(93)90153-Z
  6. Feng, P., Miao, C.W. and Bullard, J.W. (2014), "A model of phase stability, microstructure and properties during leaching of Portland cement binders", Cement Concrete Comp., 49, 9-19 https://doi.org/10.1016/j.cemconcomp.2014.01.006
  7. Garboczi, E.J. (1990) "Permeability, diffusivity, and microstructural parameters: a critical review", Cement Concrete Res., 20(90), 591-601. https://doi.org/10.1016/0008-8846(90)90101-3
  8. Garboczi, E.J. and Bentz, D.P. (1992), "Computer simulation of the diffusivity of cement-based materials", J. Mater. Sci., 27(8), 2083-2092. https://doi.org/10.1007/BF01117921
  9. Gospodinov, P., Kazandjiev, R. and Mironova, M. (1996), "The effect of sulfate ion diffusion on the structure of cement stone", Cement Concrete Comp., 18(6), 401-407. https://doi.org/10.1016/S0958-9465(96)00032-7
  10. Gospodinov, P.N., Kazandjiev, R.F., Partalin, T.A. and Mironova, M.K. (1999), "Diffusion of sulfate ions into cement stone regarding simultaneous chemical reactions and resulting effects", Cement Concrete Res., 29, 1591-1596. https://doi.org/10.1016/S0008-8846(99)00138-6
  11. Gospodinov, P., Kazandjiev, R. and Mironova, M. (2007a), "Mechanisms of sulfate ionic diffusion in porous cement based composites", Comput. Concrete, 4(4), 273-284. https://doi.org/10.12989/cac.2007.4.4.273
  12. Gospodinov, P., Kazandjiev, R. and Mironova, M. (2007b), "Mechanisms of sulfate ionic diffusion in porous cement based composites: effect of capillary size change", Comput. Concrete, 4(2), 273-284. https://doi.org/10.12989/cac.2007.4.4.273
  13. Guo, Z.H. and Shi, X.D. (2003), Theory and analysis of reinforced concrete, Tsinghua University Press, Beijing, China.
  14. Idiart, A.E., Lopez, C.M. and Carol, I. (2011), "Chemo-mechanical analysis of concrete cracking and degradation due to external sulfate attack: a meso-scale model", Cement Concrete Comp., 33(3), 411-423. https://doi.org/10.1016/j.cemconcomp.2010.12.001
  15. Koukkari, P. and Pajarre, R. (2007), "Combining reaction kinetics to the multi-phase gibbs energy calculation", Comput. Aided Chem. Eng., 24(7), 153-158. https://doi.org/10.1016/S1570-7946(07)80049-6
  16. Neville, A. (2004), "The confused world of sulfate attack on concrete", Cement Concrete Res., 34(8), 1275-1296. https://doi.org/10.1016/j.cemconres.2004.04.004
  17. Page, C.L., Short, N.R. and Tarras, A.E. (1981), "Diffusion of chloride ions in hardened cement pastes", Cement Concrete Res., 11(3), 395-406. https://doi.org/10.1016/0008-8846(81)90111-3
  18. Peng, J.H., Zhang, J.X. and Qu, J. (2006), "The mechanism of formation and transformation of ettringite", Journal of Wuhan University of Technology - Mater. Sci. Ed., 21(3), 158-161. https://doi.org/10.1007/BF02840908
  19. Prince, W., Espagne, M. and AiTcin, P.C. (2003) "Ettringite formation: a crucial step in cement superplasticizer compatibility", Cement Concrete Res., 33(5), 635-641. https://doi.org/10.1016/S0008-8846(02)01042-6
  20. Samson, E. and Marchand, J. (2007), "Modeling the transport of ions in unsaturated cement-based materials", Comput. Struct., 85(23), 1740-1756. https://doi.org/10.1016/j.compstruc.2007.04.008
  21. Song, Z., Jiang, L., Chu, H., Xiong, C., Liu, R. and You, L. (2014), "Modeling of chloride diffusion in concrete immersed in CaCl2 and NaCl solutions with account of multi-phase reactions and ionic interactions", Constr. Build. Mater., 66(1), 1-9. https://doi.org/10.1016/j.conbuildmat.2014.05.026
  22. Sun, C., Chen, J., Zhu, J., Zhang, M. and Ye, J. (2013), "A new diffusion model of sulfate ions in concrete", Constr. Build. Mater., 39(1), 39-45. https://doi.org/10.1016/j.conbuildmat.2012.05.022
  23. Tixier, R. and Mobasher, B. (2003a), "Modeling of damage in cement-based materials subjected to external sulfate attack. i: formulation", J. Mater. Civ. Eng., 15(4), 305-313. https://doi.org/10.1061/(ASCE)0899-1561(2003)15:4(305)
  24. Tixier, R. and Mobasher, B. (2003b), "Modeling of damage in cement-based materials subjected to external sulfate attack. ii: comparison with experiments", J. Mater. Civ. Eng., 15(4), 314-322. https://doi.org/10.1061/(ASCE)0899-1561(2003)15:4(314)
  25. Tumidajski, P.J., Chan, G.W. and Philipose, K.E. (1995), "An effective diffusivity for sulfate transport into concrete", Cement Concrete Res., 25(6), 1159-1163. https://doi.org/10.1016/0008-8846(95)00108-O
  26. Zuo, X.B., Sun, W. and Yu, C. (2012a), "Numerical investigation on expansive volume strain in concrete subjected to sulfate attack", Constr. Build. Mater., 36(4), 404-410. https://doi.org/10.1016/j.conbuildmat.2012.05.020
  27. Zuo, X.B., Sun, W., Li, H. and Zhao, Y.K. (2012b), "Modeling of diffusion-reaction behavior of sulfate ion in concrete under sulfate environments", Comput. Concrete, 10(1), 79-93. https://doi.org/10.12989/cac.2012.10.1.079

피인용 문헌

  1. Numerical investigation on gypsum and ettringite formation in cement pastes subjected to sulfate attack vol.19, pp.1, 2015, https://doi.org/10.12989/cac.2017.19.1.019
  2. Modeling of time-varying stress in concrete under axial loading and sulfate attack vol.19, pp.2, 2015, https://doi.org/10.12989/cac.2017.19.2.143
  3. X-ray CT monitoring of macro void development in mortars exposed to sulfate attack vol.21, pp.4, 2015, https://doi.org/10.12989/cac.2018.21.4.367
  4. Effect of interfacial transition zone on the transport of sulfate ions in concrete vol.192, pp.None, 2015, https://doi.org/10.1016/j.conbuildmat.2018.10.140