상하수도학회지 (Journal of Korean Society of Water and Wastewater)

  • 제29권6호
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  • Pages.685-692
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  • 2015
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  • 1225-7672(pISSN)
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  • 2287-822X(eISSN)
대한상하수도학회 (The Korean Society of Water and Wastewater)
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2-브로모페놀 제거를 위한 액상 페레이트 적용 연구

Application of in situ Liquid Ferrate(VI) for 2-Bromophenol Removal

  • ;
  • 김일규 (부경대학교, 환경공학과(BK21플러스 해양융합디자인인재양성 사업단))
  • Laksono, Fajar Budi (Dept. of Marine Convergence Design, Pukyong National University) ;
  • Kim, Il-Kyu (Dept. of Environmental Engineering, Pukyong National University)
  • 투고 : 2015.11.19
  • 심사 : 2015.12.15
  • 발행 : 2015.12.15
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초록

The concern over the risk of environmental exposure to brominated phenols has been increased and has led the researchers to focus their attention on the study of bromophenol treatment. In this study, the effects of pH and ferrate(VI) dose on the degradation of 2-bromophenol were investigated. The results indicated that the oxidation of 2-bromophenol by liquid ferrate(VI) was found to be highly sensitive to the pH condition. Furthermore, the highest removal efficiency was observed at the neutral condition with the removal efficiency of 94.2%. In addition, experimental results showed that 2-bromophenol removal efficiency increased with increasing of ferrate dosage. Ferrate(VI) dose of 0.23 mM was sufficient to remove most of the 2-bromophenol with the efficiency of 99.73% and kapp value of $2982M^{-1}s^{-1}$. Seven compounds were identified as the intermediate products by the GC/MS analysis.

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참고문헌

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