DOI QR코드

DOI QR Code

A Study on the Desulfurization Efficiency of Limestone Sludge with Various Admixtures

  • Seo, Sung Kwan (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Chu, Yong Sik (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Shim, Kwang Bo (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Jong Kyu (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Song, Hun (Division of Materials Science and Engineering, Hanyang University)
  • Received : 2015.07.01
  • Accepted : 2015.10.15
  • Published : 2015.11.30

Abstract

The flue gas desulfurization (FGD) process is one of the most effective methods to reduce the amount of $SO_2$ gas (up to 90%) generated by the use of fossil fuel. Limestone is usually used as a desulfurizing agent in the wet-type FGD process; however, the limestone reserves of domestic mines have become exhausted. In this study, limestone sludge produced from the steel works process is used as a desulfurizing agent. Seven different types of additives are also used to improve the efficiency of the desulfurization process. As a result, alkaline additive is identified as the least effective additive, while certain types of organic acids show higher efficiency. It is also observed that the amount of FGD gypsum, which is a by-product of the FGD process, increases with the used of some of those additives.

Keywords

References

  1. J. B. Frandsen, S. Kiil, and J. E. Johnsson, "Optimization of a Wet FGD Pilot Plant Using Fine Limestone and Organic Acids," Chem. Eng. Sci., 56 [10] 3275-87 (2001). https://doi.org/10.1016/S0009-2509(01)00010-0
  2. S. K. Seo, Y. S. Chu, K. B. Shim, J. K. Lee, H. Song, and Y. M. Yun, "A Study on the Application with Limestone Sludge at Flue Gas Desulfurizing Process," J. Korean Ceram. Soc., 51 [6] 1-9 (2014). https://doi.org/10.4191/kcers.2014.51.1.001
  3. N. Ukawa, T. Takashina, N. Shinoda, and T. Shimizu, "Effexts of Particle Size Distribution on Limestone Dissolution in Wet FGD Process Applications," Environment Prog., 12 [3] 238-42 (1993). https://doi.org/10.1002/ep.670120314
  4. P. K. Chan and G. T. Rochelle, "Limestone Dissolution: Effects of pH, $CO_2$, and Buffers Models by Mass Transfer," ACS Symposium Ser., 188 75-9 (1982).
  5. E. H. Kim, J. C. Lee, H. K. Lee, and I. W. Kim, "Effect of Mixed Organic Acid admixtures on $SO_2$ Absorption in Wet Flue Gas Desulfurizing Process," Hwahak Konghak, 36 [5] 827-31 (1998).
  6. J. C. S. Chang and J. D. Mobley, "Testing and Commercialization of Byproduct Dibasic Acid as Buffer Admixtures for Limestone Flue Gas Desulfurizing Systems," J. Air Pollut. Control Assoc., 33 [10] 955-62 (1983). https://doi.org/10.1080/00022470.1983.10465677
  7. P. Tesarek, J. Krchalova, J. Kolisko, P. Rovnanikova, and R. Cerny, "Flue Gas Desulfurizing Gypsum: Study of Basic Mechanical, Hydric and Thermal Properties," Construction and Building Materials, 21 1500-9 (2007). https://doi.org/10.1016/j.conbuildmat.2006.05.009

Cited by

  1. 유기산 첨가제를 이용한 저품질 석회석 슬러리의 탈황 성능 개선 vol.32, pp.2, 2021, https://doi.org/10.14478/ace.2021.1017