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Preparation and Properties of Poly(ethylene terephthalate)/Nylon 6 Alloy Fibers Using Epoxy as a Reactive Compatibilizer(II) -Preparation and Properties of Alloy Fibers-

폴리에틸렌테레프탈레이트와 나일론 6 알로이 섬유의 구조와 성질(II) -알로이 섬유의 제조와 물성 분석-

  • Received : 2014.09.01
  • Accepted : 2014.10.07
  • Published : 2014.10.31

Abstract

The preparation of polymer alloys from immiscible blends of poly(ethylene terephthalate) (PET) and nylon 6 was investigated using epoxy as a reactive compatibilizer during melt compounding. The domain size of nylon 6 in the PET matrix could be controlled to the submicron level by addition of 0.5-2.0 wt% epoxy to the blends. Melt spinning of the alloys were successfully performed in a pilot scale. The alloy fibers containing 5-10 wt% nylon 6 exhibited reasonable mechanical properties, with up to 3 g/d tenacity and 35% elongation. Moreover, the alloy fibers showed improved moisture absorption properties compared with that of neat PET fibers.

Keywords

References

  1. M. S. Park, J. H. Yoon, and D. H. Cho, "A Study on Extraction Condition of Co-PET from PET/Co-PET Sea-Island Type Microfiber Fabric", Text Color Finish, 2001, 13, 34-40.
  2. G. H. Bae, M. J. Ham, and Y. H. Kim, "Effects of Compatibilizers on PPS/PET and PPS/PA66 Blends", Text Sci Eng, 2012, 49, 56-65. https://doi.org/10.12772/TSE.2012.49.1.056
  3. L. Z. Pillon and L. A. Utracki, “Compatibilization of Polyester/polyamide Blends via Catalytic Ester-amide Interchange Reaction”, Polym Eng Sci, 1984, 24, 1300-1305. https://doi.org/10.1002/pen.760241706
  4. K. Kubo and J. Masamoto, “Dispersion of Poly(phenylene ether) in a Poly(phenylene sufide)/poly(phenylene ether) Alloy”, Macromol Mater Eng, 2001, 286, 555-559. https://doi.org/10.1002/1439-2054(20010901)286:9<555::AID-MAME555>3.0.CO;2-W
  5. J. Zhou, B. G. Min, M. K. Lim, K. S. Lee, Y-C. Yu, and J. S. Han, "Preparation and Properties of Poly(ethylene terephthalate) (PET)/Polyamide-6(PA6) Alloy Fibers Using Epoxy as a Reactive Compatibilizer: I. Effect of Epoxy on the Phase Separation of PET/PA6 Alloys", Text Color Finish, 2012, 24(2), 145-152. https://doi.org/10.5764/TCF.2012.24.2.145
  6. C. K. Samios and N. K. Kalfoglou, "Compatibilization of poly(ethylene terephthalate)/polyamide-6 Alloys: Mechanical, Thermal and Morphological Characterization", Polymer, 1999, 40, 4811-4819. https://doi.org/10.1016/S0032-3861(98)00709-5
  7. Y. Huang, Y. Liu, and C. Zhao, “Morphology and Properties of PET/PA-6/E-44 Blends”, J Appl Polym Sci, 1998, 69, 1505-1515. https://doi.org/10.1002/(SICI)1097-4628(19980822)69:8<1505::AID-APP4>3.0.CO;2-G
  8. J. Zhou and B. G. Min, "Compatibilizing Effect of Epoxy Resin on the Phase Separation and Properties of Polyamide 6/poly(ethylene terephthalate) Blends", Text Sci Eng, 2014, 51, 21-26. https://doi.org/10.12772/TSE.2014.51.021
  9. J. Zhou and B. G. Min, "Preparation and Properties of Alloy Fibers Obtained from Poly(ethylene terephthalate)/Polyamide 6 Blends by Using a Reactive Compatibilizer(I): Effect of Reactive Compatibilizer on Morphology, and Thermal and Rheological Properties", Text Sci Eng, 2014, 51, 84-88. https://doi.org/10.12772/TSE.2014.51.084
  10. J. Zhou and B. G. Min, "Interfacial Localization of Multiwalled Carbon Nanotubes in Immiscible Blend of Poly(ethylene terephthalate)/Polyamide 6", Fiber Polym, 2013, 14, 518-524. https://doi.org/10.1007/s12221-013-0518-4