Resources Recycling (자원리싸이클링)

The Korean Institute of Resources Recycling (한국자원리싸이클링학회)
권호 표지
DOI QR코드

DOI QR Code

Trend on the Development of Commercial Technology for Feedstock Recycling and High End Products from PET Wastes by the Patent and Paper Analysis

특허와 논문으로 본 PET 폐자원의 화학원료화 및 고부가 활용기술 동향

  • Received : 2013.12.27
  • Accepted : 2014.10.10
  • Published : 2014.10.30
Download PDF
⟨ Previous Next ⟩

Abstract

Since 1990s, efforts to recycle the waste plastics by chemical methods have increased. And in accordance with this trend, attempts have become active to use the waste PET as raw materials of chemical industries. In this article, the patents and papers for development of commercial technology for feedstock recycling and high end products from PET wastes were collected and analyzed. The open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) and SCI journals from 1974 to 2013 were investigated. The patents and papers were collected using key-words and filtered by the definition of the technology. The patents and papers were analyzed by the years, countries, companies, and technologies and the technical trends were discussed in this paper.

1990년대에 들어서면서 폐플라스틱을 화학적으로 재활용하여 환경문제나 경제적 문제를 해결해보려는 노력이 증대되었고, 이 추세에 따라 폐 PET를 화학적으로 재활용하여 원료화하려는 시도가 활발해졌다. 본 연구에서는 PET 폐자원의 화학원료화 및 고부가 활용기술에 대한 특허와 논문을 분석하였다. 분석범위는 1974년에서 2013년까지의 미국, 유럽연합, 일본, 한국의 등록/공개된 특허와 SCI 논문으로 제한하였다. 특허와 논문은 키워드를 사용하여 수집하였으며, 기술의 정의에 의해 필터링 하였다. 특허와 논문의 동향은 연도, 국가, 기업, 기술 등에 따라 분석하여 고찰하였다.

Keywords

References

  1. Yamamoto, S., Aoki M., Yamagata, M., 1997: Chemical recycling of poly(ethylene terephthalate) by hydrolytic depolymerization under pressure, KOBELCO Technology Review, pp52-55.
  2. Cao, W., Zhang, J., Li, Y., 1999: Application of supercritical fluid technique in the degradation of PET waste, Beijing Huagong Daxue Xuebao (Ziran Kexueban)/Journal of Beijing University of Chemical Technology, 26, pp74.
  3. Yang, Y., et al., 2002: Study on methanolytic depolymerization of PET with supercritical methanol for chemical recycling, Polymer Degradation and Stability, 75, pp185-191. https://doi.org/10.1016/S0141-3910(01)00217-8
  4. Pimpan, V., Sirisook, R., Chuayjuljit, S., 2003: Synthesis of unsaturated polyester resin from postconsumer PET bottles: Effect of type of glycol on characteristics of unsaturated polyester resin, Journal of Applied Polymer Science, 88, pp788-792. https://doi.org/10.1002/app.11567
  5. Chen, C.-H., 2003: Study of glycolysis of poly(ethylene terephthalate) recycled from postconsumer soft-drink bottles. III. Further investigation, Journal of Applied Polymer Science, 87, pp2004-2010. https://doi.org/10.1002/app.11694
  6. Xi, G., Lu, M., Sun, C., 2005: Study on depolymerization of waste polyethylene terephthalate into monomer of bis(2- hydroxyethyl terephthalate), Polymer Degradation and Stability, 87, pp117-120. https://doi.org/10.1016/j.polymdegradstab.2004.07.017
  7. Atta, A.M., 2007: Surface and thermodynamic parameters of polymeric surfactants from recycled poly(ethylene terephthalate), Polymer International, 56, pp984-995. https://doi.org/10.1002/pi.2232
  8. Kim, B.-K., et al., 2008: Chemical recycling of poly(ethylene terephthalate) using a new hybrid process, Journal of Chemical Engineering of Japan, 41 pp923-928. https://doi.org/10.1252/jcej.07WE304
  9. Abdelaal, M.Y., Sobahi, T.R., Makki, M.S.I., 2008: Chemical degradation of poly(ethylene terephthalate), International Journal of Polymeric Materials and Polymeric Biomaterials, 57, pp73-80. https://doi.org/10.1080/00914030701329080
  10. Lopez-Fonseca R., et al., 2011: Kinetics of catalytic glycolysis of PET wastes with sodium carbonate, Chemical Engineering Journal, 168, pp312-320. https://doi.org/10.1016/j.cej.2011.01.031
  11. Viana, M.E., et al., 2011: Chemical recycling of PET by catalyzed glycolysis: Kinetics of the heterogeneous reaction, Chemical Engineering Journal, 173, pp210-219. https://doi.org/10.1016/j.cej.2011.07.031
  12. Goh, H.W., et al., 2012: Process simulation of two-stage evaporation and crystallization systems for bis(2-hydroxyethyl) terephthalate recovery, Journal of Applied Sciences, 12, pp1547-1555. https://doi.org/10.3923/jas.2012.1547.1555
  13. Liu, S., et al., 2013: Butanol alcoholysis reaction of polyethylene terephthalate using acidic ionic liquid as catalyst, Journal of Applied Polymer Science.
  14. Vaidya, U.R., Nadkarni, V.M., 1987: Unsaturated polyester resins from poly(ethylene terephthalate) waste. I. Synthesis and characterization.
  15. 2001: Green PET progress, 358, pp1-5
  16. Tawfik, M.E., 2003: Preparation and characterization of water-extended polyester based on recycled poly(ethylene terephthalate), Journal of Applied Polymer Science, 89, pp3693-3699 https://doi.org/10.1002/app.12419

Cited by

  1. Cu, Mn/γ-Al2O3 촉매상에서 polyethylene telephthalate 단량체의 회수 연구 vol.28, pp.4, 2014, https://doi.org/10.14478/ace.2017.1054