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Evaluation of Applicability of Heavy Oil Upgrading By-Product (Pitch) as A Pavement Paving Material

중질유 고도정제 부산물의 도로포장용 역청재료로서의 적용성 평가

  • Received : 2014.08.19
  • Accepted : 2014.08.31
  • Published : 2014.10.16

Abstract

PURPOSES : The objective of this study is to evaluate the applicability of the pitch, which is produced during SDA petroleum upgrading process, as a pavement paving material. In order for the purpose, the physical and chemical properties of the pitch are analyzed, and then the various plasticizers are applied in the pitch. METHODS : Two types of pitch are selected from oil refinery companies, which are owned the SDA petroleum upgrading process. Also, two types of asphalt binders, PG 64-22 and PG 58-22, are employed to compare with the pitch because these two types of asphalt binders are currently used as paving materials. For the chemical property of the pitch, the composition of SARA (Saturate, Aromatic, Resin, Asphaltene), the elementary composition, and the functional group are analyzed. For the physical property of the pitch, the basic material property tests, such as penetration test, softening point test, flash point test, ductility test, and rotational viscometer test, are performed. Also, the DSR (Dynamic Shear Rheometer) test and the BBR (Bending Beam Rheometer) test are conducted using asphalt binder specimens obtained by both short term aging (Rolling Thin Film Oven, RTFO) and long term aging (Pressure Aging Vessel, PAV) processes. The rheological property of each pitch type is evaluated as a function of temperatures and loading cycles. PG 64-22 asphalt binder is used as a control material. RESULTS AND CONCLUSIONS : The Pitch may not be suitable for the pavement paving material without modifications, but the pitch can be used as alternatives of modified addictive or asphalt. If low molecular component, such as saturate and aromatic components, are added in the pitch based on the development of various plasticizers, it has a strong possibility for the pitch to be used as a alternative. However, in order to verify the performance property of the pitch, further research is needed.

Keywords

References

  1. Cho, Dong-Woo, Bahia, Hussain U.", Effect of Aggregates'Surface and Water on Rheology of Asphalt Films" Transportation Research Record: Journal of the Transportation Research Board, No 1998, TRB, National Research Council, Washington, D.C., pp.10-17 (2007).
  2. Hong H, Han Y, Kim Y, Rhee S., "A Study on Road Paving Material to Use Pitch", Korea Society of Road Engineers (2013)
  3. H. S. Yeon, C. S. Woo, and K. H. Kang, Extraction and Vacuum Distillation Characteristics of Oil Sand Bitumen Using Solvent, Appl. Chem., 12, 361 (2008).
  4. K. H. Kim et al., Physical and Chemical Characteristics of Solvent-Insolubles and Solvent-Solubles in Oilsands Bitumen, J. Energy Eng., 17, 38 (2008).
  5. 김재호 외 :" 오일샌드로부터 합성원유(SCO) 생산 원천기술 개발 기획", 한국에너지기술연구원 기획보고서 (2007)
  6. M. S. Rana, V. Samano, J. Ancheyta, and J. A. I. Diaz, A review of recent advances on process technologies for upgrading of heavy oils and residua, Fuel, 86, 1216 (2007). https://doi.org/10.1016/j.fuel.2006.08.004
  7. N. S. Nho et al., Development of next-generation integrated upgrading process for extra-heavy oil fractions., Korea Institute of Energy Research (2009).
  8. N. S. Nho et al., Feasibility Study about Upgrading Package Process for the Production of Synthetic Crude Oil & Petrochemical Feedstocks from Low-Cost Heavy Oils., Korea Institute of Energy Research (2012).
  9. N. Nu :" Refining Alberta's Energy Advantage - An Unprecedented Investment Opportunity", Alberta Employment, Immigration and Industry, October (2007)
  10. Yun T, Ham S, Yoo P", Characteristics of Dynamic Shear Modulus Mastercurve of Aged or Unaged Asphalt Binders" International Journal of Highway Engineering Vol. 15, No. 1, pp87-94 (2013). https://doi.org/10.7855/IJHE.2013.15.1.087