Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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The Novel SCN- Ion-selective Electrode Based on the 1-Benzyl-3-(4-nitrophenyl) thio-urea Ionophore

  • Lee, Kyungmi (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Kang, Dong Hyeon (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Choe, Ju Eun (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Yun, Mira (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • You, Jung-Min (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Go, Min Jeong (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Lee, Junseong (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Jeon, Seungwon (Department of Chemistry and Institute of Basic Science, Chonnam National University)
  • Received : 2014.03.03
  • Accepted : 2014.07.01
  • Published : 2014.11.20
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Abstract

A potentiometric sensor based on the 1-benzyl-3-(4-nitrophenyl) thio-urea was synthesized and tested as an ionophore in PVC based membrane sensor towards $SCN^-$ ions. This membrane exhibits a linear stable response over a wide concentration range ($1.0{\times}10^{-5}$ to $1.0{\times}10^{-2}M$) with a slope of -59.2 mV/dec., a detection limit of ${\log}[SCN^-]=-5.05$, and a selectivity coefficient for thiocyanate against perchlorate anion of ${\log}K^{pot}_{SCN^-j}=-0.133$. The selectivity series of the membrane is as follows: $SCN^-$ > $ClO_4{^-}$ > $I^-$ > $NO_3{^-}$ > $HSO_3{^-}$ > $Cl^-$ > $HSO_4{^-}$ > $F^-$ > $CH_3COO^-$ > $HCO_3{^-}$ > $Br^-$ > $H_2PO_4{^-}$ > $SO{_3}^{2-}$ > $SO{_4}^{2-}$ > $CO{_3}^{2-}$. The proposed electrode showed good selectivity and a good response for the $SCN^-$ ion over a wide variety of other anions in pH 6.0 buffer solutions and has a fast response time of about < 5s. The influences of the membrane by pH, ionophore, and plasticizer were studied.

Keywords

References

  1. Guien, Z.; Bin, L.; Jing, F.; Suling, F. Talanta 1997, 44, 1141. https://doi.org/10.1016/S0039-9140(96)02080-2
  2. Tsuge, K.; Kataoka, M.; Seto, Y. J. Health Sci. 2000, 46, 343. https://doi.org/10.1248/jhs.46.343
  3. Thomas, E. L.; Milligan, T. W.; Joyner, R. E.; Jefferson, M. M. Infect. Immun 1994, 62, 529.
  4. Pruitt, K. M.; Rahemtulla, B. M.; Baldone, D. C.; Rahamtulla, F. Biochemistry 1988, 27, 240. https://doi.org/10.1021/bi00401a036
  5. Hovinen, J.; Silvennoinen, R.; Vilpo, J. Chem. Res. Toxicol. 1998, 11, 91. https://doi.org/10.1021/tx970196p
  6. Li, Q.; Wei, W.; Liu, Q. Analyst 2000, 125, 1885. https://doi.org/10.1039/b004497k
  7. van Staden, J. F.; Botha, A. Anal. Chim. Acta 2000, 403, 279.
  8. Michigami, Y.; Fujii, K.; Ueda, K.; Yamamoto, Y. Analyst 1992, 117, 1855. https://doi.org/10.1039/an9921701855
  9. Lu, G.; Xu, H.; Jianyan, L. Huaxue Fence 1989, 25, 120.
  10. James, A. C.; Gray, T.; Kulkarni, K. R. Anal. Chem. 1988, 60, 1710. https://doi.org/10.1021/ac00168a015
  11. Kiryushov, V. N.; Kopylova, N. S.; Kletenik, Y. B.; Zavod. Lab 1995, 61, 8.
  12. (a) Hofmeister, F. Arch. Exp. Patol. Pharmakol. 1888, 24, 247. https://doi.org/10.1007/BF01918191
  13. (b) Marcus, Y. Ion Solvation; Wiley: New York, 1985; pp 107-109.
  14. Seo, H. R.; Lee, H. K.; Jeon, S. Bull. Korean Chem. Soc. 2004, 25, 1484. https://doi.org/10.5012/bkcs.2004.25.10.1484
  15. Khorasani, J. H.; Amini, M. K.; Motaghi, H.; Tangesta-ninejad, S.; Modhadam, M. Sens. Actuat. B 2002, 87, 448. https://doi.org/10.1016/S0925-4005(02)00294-0
  16. Amini, M. K.; Shahrokhian, S.; Tangestaninejad, S. Anal. Chem. 1999, 71, 2502. https://doi.org/10.1021/ac9812633
  17. Badr, I. H. A.; Meyerhoff, M. E.; Hassan, S. S. M. Anal. Chem. 1995, 67, 754.
  18. Kim, D. W.; Lee, S. H.; Kim, J.; Kim, J.; Park, J. K.; Kim, J. S. Bull. Korean Chem. Soc. 2009, 30, 2303. https://doi.org/10.5012/bkcs.2009.30.10.2303
  19. Badri, A.; Poulasdaz, P. Int. J. Electrochem. Sci. 2011, 6, 3178.
  20. Schulthess, P.; Ammann, D.; Krautler, B.; Caderas, C.; Stepanek, R.; Simon, W. Anal. Chem. 1985, 57, 1397. https://doi.org/10.1021/ac00284a048
  21. Stepanek, R.; Kraultler, B.; Schulthess, P.; Lindemann, B.; Ammann, D.; Simon, W. Anal. Chim. Acta 1986, 182, 83. https://doi.org/10.1016/S0003-2670(00)82439-3
  22. Jeong, E.; Lee, H. K.; Ahmed, M. S.; Seo, H.; Jeon, S. Bull. Korean Chem. Soc. 2010, 31, 401. https://doi.org/10.5012/bkcs.2010.31.02.401
  23. Abbaspour, A.; Kamyabi, M. A.; Esmaeilbeig, A. R.; Kia, R. Talanta 2002, 57, 859. https://doi.org/10.1016/S0039-9140(02)00129-7
  24. Florido, A.; Bachas, L. G.; Valiente, M.; Villaescusa, I. Anaylst 1994, 119, 2421. https://doi.org/10.1039/an9941902421
  25. Wang, E.; Ohashi, S.; Kamata, S. Anal. Sci. 1991, 7, 755. https://doi.org/10.2116/analsci.7.Supple_755
  26. Bricker, J.; Daunert, S.; Bachas, L. G. Anal. Chem. 1991, 63, 1585. https://doi.org/10.1021/ac00015a016
  27. Umezawa, Y.; Buhlmann, P.; Umezawa, K.; Tohda, K.; Amemiya, S. Inf. Bull.-IUPAC 2000, 72, 1851.
  28. Richard, P. B.; Vasile, V. C. Inf. Bull.-IUPAC 1993, 65, 1849.
  29. Bruker.; SMART, version 5.0, Data collection software, Bruker AXS, Inc.; Madison, WI, 1998.
  30. Bruker.; SAINT, version 5.0, Data integration software, Bruker AXS Inc., Madison, WI, 1998.
  31. Sheldrick, G. M.; Program for absorption correction with the Bruker SMART system, SADABS, Universitat Gottingen, Germany, 1996.
  32. Sheldrick, G. M.; SHELXL-97: Program for the refinement of crystal structures; Universitat Gottingen: Germany, 1997.
  33. Seo, H.; Jeong, E.; Ahmed, M. S.; Lee, H. K.; Jeon, S. Bull. Korean Chem. Soc. 2010, 31, 1699. https://doi.org/10.5012/bkcs.2010.31.6.1699
  34. Ammann, D.; Pretsch, E.; Simon, W.; Linder, E.; Bezegh, A.; Pun-gor, E. Anal. Chim. Acta 1984, 171, 119.
  35. Schaller, U.; Bakker, E.; Spichiger, U. E.; Pretsch, E. Anal. Chem. 1994, 66, 391. https://doi.org/10.1021/ac00075a013
  36. Rosatzin, T.; Bakker, E.; Suzuki, K.; Simon, W. Anal. Chim. Acta 1993, 220, 197.
  37. Eugster, R.; Gehring, P. M.; Morf, W. E.; Spichiger, U.; Simon, W. Anal. Chem. 1991, 63, 2285. https://doi.org/10.1021/ac00020a017
  38. Shamsipour, M.; Ershad, S.; Samadi, N.; Rezvani, A. R.; Haddadzadeh, H. Talanta 2005, 65, 991. https://doi.org/10.1016/j.talanta.2004.08.032
  39. Erden, S.; Demirel, A.; Memon, S.; Yılmaz, M.; Canel, E.; Kılıc, E. Sensor Actuator B 2006, 113, 290. https://doi.org/10.1016/j.snb.2005.03.002
  40. Hassan, S. S. M.; Ghalia, M. H. A.; E-Amr, A. G.; Mohamed, A. H. K. Anal. Chim. Acta 2003, 482, 9. https://doi.org/10.1016/S0003-2670(03)00172-7
  41. Amemiya, S.; Buhlmann, P.; Umezawa, Y.; Jagessar, R. C.; Burns, D. H. Anal. Chem. 1999, 71, 1049. https://doi.org/10.1021/ac980952b

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