Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Simple Pyrene Derivatives as Fluorescence Sensors for TNT and RDX in Micelles

  • Received : 2014.06.13
  • Accepted : 2014.07.02
  • Published : 2014.11.20
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Abstract

Various pyrene derivatives were synthesized and systematically examined in micelles. Synthesized mono and bispyrene derivatives were tested in micelles so that they displayed a strong excimer band and the excimer band was quenched in the presence of TNT and RDX. In the optimized condition, the binding constant for TNT of a simple dipyrene derivative 4 was increased up to $1.0{\times}10^6M^{-1}$ in cetyl trimethylammonium bromide (CTAB) micelles, which allowed for the detection of 2 ppb of TNT and 334 ppb of RDX by fluorescence titrations.

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