Polymer(Korea) (폴리머)

The Polymer Society of Korea (한국고분자학회)
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Synthesis, Characterization and Swelling Properties of Chitosan/Poly(acrylic acid-co-crotonic acid) Semi-Interpenetrating Polymer Networks

Chitosan/Poly(acrylic acid-co-crotonic acid) Semi-IPN의 합성, 분석 및 팽윤거동

  • Received : 2014.02.03
  • Accepted : 2014.04.05
  • Published : 2014.09.25
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Abstract

A semi-interpenetrating polymer network (semi-IPN) hydrogel composed of crosslinked chitosan and poly (acrylic acid-co-crotonic acid) was prepared in the presence of glutaraldehyde (GA) as a crosslinker. Fourier-transform infrared, thermogravimetric analysis and scanning electron microscopy were employed to confirm the structure of the semi-IPN hydrogel. The swelling capacity of hydrogel was shown to be affected by the monomers weight ratio, chitosan content, initiator and GA concentrations. The results also indicated that the semi-IPN hydrogel had different swelling capacity at various pHs. Additionally, the swelling behavior of the hydrogel was investigated in aqueous solutions of NaCl, $CaCl_2$, and $AlCl_3$.

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