Advances in environmental research

  • 제3권3호
  • /
  • Pages.231-251
  • /
  • 2014
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  • 2234-1722(pISSN)
  • /
  • 2234-1730(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Modelling and packed bed column studies on adsorptive removal of phosphate from aqueous solutions by a mixture of ground burnt patties and red soil

  • Rout, Prangya R. (Department of Civil Engineering, School of Infrastructure, Indian Institute of Technology) ;
  • Dash, Rajesh R. (Department of Civil Engineering, School of Infrastructure, Indian Institute of Technology) ;
  • Bhunia, Puspendu (Department of Civil Engineering, School of Infrastructure, Indian Institute of Technology)
  • 투고 : 2014.04.01
  • 심사 : 2014.07.21
  • 발행 : 2014.09.25
⟨ 이전 논문 다음 논문 ⟩

초록

The present study examines the phosphate adsorption potential and behavior of mixture of Ground Burnt Patties (GBP), a solid waste generated from cooking fuel used in earthen stoves and Red Soil (RS), a natural substance in fixed bed column mode operation. The characterization of adsorbent was done by Proton Induced X-ray Emission (PIXE), and Proton Induced ${\gamma}$-ray Emission (PIGE) methods. The FTIR spectroscopy of spent adsorbent reveals the presence of absorbance peak at $1127cm^{-1}$ which appears due to P = O stretching, thus confirming phosphate adsorption. The effects of bed height (10, 15 and 20 cm), flow rate (2.5, 5 and 7.5 mL/min) and initial phosphate concentration (5 and 15 mg/L) on breakthrough curves were explored. Both the breakthrough and exhaustion time increased with increase in bed depth, decrease in flow rate and influent concentration. Thomas model, Yoon-Nelson model and Modified Dose Response model were used to fit the column adsorption data using nonlinear regression analysis while Bed Depth Service Time model followed linear regression analysis under different experimental condition to evaluate model parameters that are useful in scale up of the process. The values of correlation coefficient ($R^2$) and the Sum of Square Error (SSE) revealed the Modified Dose Response model as the best fitted model to the experimental data. The adsorbent mixture responded effectively to the desorption and reusability experiment. The results of this finding advocated that mixture of GBP and RS can be used as a low cost, highly efficient adsorbent for phosphate removal from aqueous solution.

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참고문헌

  1. Adak, A., Bandyopadhyay, M. and Pal, A. (2006), "Fixed bed column study for the removal of crystal violet (C. I. Basic Violet 3) dye from aquatic environment by surfactant-modified alumina", Dyes. Pigments., 69(3), 245-251. https://doi.org/10.1016/j.dyepig.2005.03.009
  2. Aksu, Z. and Gonen, F. (2004), "Biosorption of phenol by immobilized activated sludge in a continuous packed bed: prediction of breakthrough curves", Process Biochem., 39(5), 599-613. https://doi.org/10.1016/S0032-9592(03)00132-8
  3. APHA, AWWA, WPCF (2005), Standard Methods for the Examination of Water and Wastewater, (21st Ed.), American Public Health Association, Washington DC, USA.
  4. Cavas, L., Karabay, Z., Alyuruk, H., Dogan, H. and Demir, G.K. (2011), "Thomas and artificial neural network models for the fixed-bed adsorption of methylene blue by a beach waste Posidonia oceanica (L.) dead leaves", Chem. Eng. J., 171(2), 557-562. https://doi.org/10.1016/j.cej.2011.04.030
  5. Chen, J.G., Kong, H.N., Wu, D.Y., Chen, X.C., Zhang, D.L. and Sun, Z.H. (2007), "Phosphate immobilization from aqueous solution by fly ashes in relation to their composition", J. Hazard. Mater., 39(2), 293-300.
  6. Chen, S., Yue, Q., Gao, B., Li, Q., Xu, X. and Fu, K. (2012), "Adsorption of hexavalent chromium from aqueous solution by modified corn stalk: A fixed-bed column study", Bioresour. Technol., 113, 114-120. https://doi.org/10.1016/j.biortech.2011.11.110
  7. Chen, H., Zhang, H. and Yan, Y. (2013), "Adsorption dynamics of toluene in structured fixed bed with ZSM-5 membrane/PSSF composites", Chem. Eng. J., 228, 336-344. https://doi.org/10.1016/j.cej.2013.04.102
  8. Jia, C.R., Dai, Y.R., Chang, J.J., Wu, C.Y., Wu, Z.B. and Liang, W. (2013), "Adsorption characteristics of used brick for phosphorous removal from phosphate solution", Desalin. Water Treat., 51(28-30), 5886-5891. https://doi.org/10.1080/19443994.2013.770207
  9. Chimenos, J.M., Fernandez, A.I., Villalba, G., Segarra, M., Urruticoechea, A., Artaza, B. and Espiella, F. (2003), "Removal of ammonium and phosphates from wastewater resulting from the process of cochineal extraction using MgO-containing by-product", Water Res., 37(7), 1601-1607. https://doi.org/10.1016/S0043-1354(02)00526-2
  10. Elzinga, E.J. and Sparks, D.L. (2007), "Phosphate adsorption onto hematite: An in situ ATR-FTIR investigation of the effects of pH and loading level on the mode of phosphate surface complexation", J. Colloid. Interf. Sci., 308(1), 53-70. https://doi.org/10.1016/j.jcis.2006.12.061
  11. Huang, W., Li, D., Zhu, Y., Xu, K., Li, J., Han, B. and Zhang, Y. (2013a), "Phosphate adsorption on aluminum-coordinated functionalized macroporous-mesoporous silica:Surface structure and adsorption behavior", Mater. Res. Bull., 48(12), 4974-4978. DOI: http://dx.doi.org/10.1016/j.materresbull.2013.04.093
  12. Huang, W.Y., Zhu, R.H., He, F., Li, D., Zhu, Y. and Zhang, Y.M. (2013b), "Enhanced phosphate removal from aqueous solution by ferric-modified laterites: Equilibrium, kinetics and thermodynamic studies", Chem. Eng. J., 228, 679-687. https://doi.org/10.1016/j.cej.2013.05.036
  13. Hutchins, R.A. (1973), "New method simplifies design of activated carbon systems", Chem. Eng., 20, 133-138.
  14. Ioannou, Z., Dimirkou, A. and Ioannou, A. (2013), "Phosphate adsorption from aqueous solutions onto Goethite, Bentonite, and Bentonite-Goethite system", Water Air Soil Pollut., 224, 1374-1382. https://doi.org/10.1007/s11270-012-1374-3
  15. Jia, Z., Wang, Q., Liu, J., Xu, L. and Zhu, R. (2013), "Effective removal of phosphate from aqueous solution using mesoporous rodlike NiFe2O4 as magnetically separable adsorbent", Colloids. Surf. A Physicochem. Eng. Asp., 436, 495-503. DOI: http://dx.doi.org/10.1016/j.colsurfa.2013.07.025
  16. Johansson, L. and Gustafsson, J.P. (2000), "Phosphate removal using blast furnace slags and opokamechanisms", Water Res., 34(1), 259-265. https://doi.org/10.1016/S0043-1354(99)00135-9
  17. Kadam, A.M., Nemade, P.D., Oza, G.H. and Shankar, H.S. (2009), "Treatment of municipal wastewater using laterite-based constructed soil filter", Ecol. Eng., 35(7), 1051-1061. https://doi.org/10.1016/j.ecoleng.2009.03.008
  18. Karageorgiou, K., Paschalis, M. and Anastassakis, G.N. (2007), "Removal of phosphate species from solution by adsorption onto calcite used as natural adsorbent", J. Hazard. Mater., 139(3), 447-452. https://doi.org/10.1016/j.jhazmat.2006.02.038
  19. Kennedy, V.J., Augusthy, A., Varier, K.M., Magudapathy, P., Panchapakesan, S., Nair, K.G.M. and Vijayan, V. (1999), "Elemental analysis of river sediments by PIXE and PIGE", Int. J. PIXE., 09, 407-416. https://doi.org/10.1142/S0129083599000516
  20. Krishnan, K.A. and Haridas, A. (2008), "Removal of phosphate from aqueous solutions and sewage using natural and surface modified coir pith", J. Hazard. Mater., 152(2), 527-535. https://doi.org/10.1016/j.jhazmat.2007.07.015
  21. Liana, A.R., Maria, L. and Caetano, P.S. (2010), "Adsorption kinetic, thermodynamic and desorption studies of phosphate onto hydrous niobium oxide prepared by the reverse microemulsion method", Adsorption, 16(3), 173-181. https://doi.org/10.1007/s10450-010-9220-7
  22. Lindsay, W.L. (1979), Chemical Equilibria in Soils, Wiley, New York, USA.
  23. Mateus, D.M.R. and Pinho, H.J.O. (2010), "Phosphorous removal by expanded clay-six years of pilot-scale constructed wetlands experience", Water. Environ. Res., 82(2), 128-137. https://doi.org/10.2175/106143009X447894
  24. Mateus, D.M.R., Vaz, M.M.N. and Pinho, H.J.O. (2012), "Fragmented limestone wastes as a constructed wetland substrate for phosphorous removal", Ecol. Eng., 41, 65-69. https://doi.org/10.1016/j.ecoleng.2012.01.014
  25. Nur, T., Johir, M.A.H., Loganathan, P., Nguyen,T., Vigneswaran, S. and Kandasamy, J. (2013), "Phosphate removal from water using an iron oxide impregnated strong base anion exchange resin", J. Ind. Eng. Chem., 20(4), 1031-1037. DOI: http://dx.doi.org/10.1016/j.jiec.2013.07.009
  26. Rahaman, M.A., Ahsan, S., Kaneco, S., Katsumata, H., Suzuki, T. and Ohta, K. (2005), "Wastewater treatment with multilayer media of waste and natural indigenous materials", J. Environ. Manage., 74(2), 107-110. https://doi.org/10.1016/j.jenvman.2004.08.012
  27. Rout, P.R., Bhunia, P. and Dash, R.R. (2014a), "A mechanistic approach to evaluate the effectiveness of red soil as a natural adsorbent for phosphate removal from wastewater", Desalin. Water. Treat. DOI: http://dx.doi.org/10.1080/19443994.2014.881752
  28. Rout, P.R, Bhunia, P. and Dash, R.R. (2014b), "Modelling isotherms, kinetics and understanding the mechanism of phosphate adsorption onto a solid waste: Ground Burnt Pattie", J. Environ. Chem. Eng., 2(3), 1331-1342. https://doi.org/10.1016/j.jece.2014.04.017
  29. Sun, X.F., Imai, T., Sekine, M., Higuchi,T., Yamamoto, K. and Kanno, A. (2013), "Adsorption of phosphate using calcined Mg3-Fe layered 3 double hydroxides in a fixed-bed column study", J. Ind. Eng. Chem., 20(5), 3623-3630. DOI: http://dx.doi.org/10.1016/j.jiec.2013.12.057
  30. Thomas, H.C. (1944), "Heterogeneous ion exchange in a flowing system", J. Am. Chem. Soc., 66(), 1466-1664. DOI: http://dx.doi.org/10.1021/ja01238a017
  31. Uddin, Md.T., Rukanuzzaman, Md., Khan, Md.M.R. and Islam, Md.A. (2009), "Adsorption of methylene blue from aqueous solution by jackfruit (Artocarpus heteropyllus) leaf powder: A fixed-bed column study", J. Env. Manag., 90(11), 3443-3450. https://doi.org/10.1016/j.jenvman.2009.05.030
  32. Wang, Y., Gao, B.Y., Yue, W.W., Xu, X.M. and Xu, X. (2008), "Adsorption kinetics of phosphate from aqueous solutions onto modified corn residue", Environ. Sci., 29(3), 703-708.
  33. Yaghmaeian, K., Moussavi, G. and Alahabadi, A. (2014), "Removal of amoxicillin from contaminated water using NH4Cl-activated carbon: Continuous flow fixed-bed adsorption and catalytic ozonation regeneration", Chem. Eng. J., 236, 538-544. https://doi.org/10.1016/j.cej.2013.08.118
  34. Yan, G., Viraraghavan, T. and Chen, M. (2001), "A new model for heavy metal removal in a biosorption column", Adsorpt. Sci. Technol., 19(1), 25-43. https://doi.org/10.1260/0263617011493953
  35. Yang, J., Wang, S., Lu, Z.B. and Lou, S.J. (2009), "Converter slag-coal cinder columns for the removal of phosphorous and other pollutants", J. Hazard. Mater., 168(1), 331-337. https://doi.org/10.1016/j.jhazmat.2009.02.024
  36. Yoon, Y.H. and Nelson, J.H. (1984), "Application of gas adsorption kinetics. Part 1. A theoretical model for respirator cartridge service time", Am. Ind. Hyg. Assoc. J., 45(8), 509-516. https://doi.org/10.1080/15298668491400197
  37. Yuan, M., Carmichael, W.W. and Hilborn, E.D. (2006), "Microcystin analysis in human sera and 469 liver from human fatalities in Caruaru, Brazil", Toxicon, 48(6), 627-640. https://doi.org/10.1016/j.toxicon.2006.07.031
  38. Zhang, L., Hong, S., He, J., Gan, F. and Ho, Y.S. (2011), "Adsorption characteristic studies of phosphorous onto laterite", Desalin. Water Treat., 25(1-3), 98-105. https://doi.org/10.5004/dwt.2011.1871
  39. Zhao, B., Shang, Y., Xiao, W., Dou, C. and Han, R. (2014), "Adsorption of Congo red from solution using cationic surfactant modified wheat straw in column model", J. Env. Chem. Eng., 2(1), 40-45. https://doi.org/10.1016/j.jece.2013.11.025
  40. Zheng, T.T., Sun, Z.X., Yang, X.F. and Holmgren, A. (2012), "Sorption of phosphate onto mesoporous $\gamma$-alumina studied with in-situ ATR-FTIR spectroscopy", Chemistry Cent. J., 6(1), 26-36. https://doi.org/10.1186/1752-153X-6-26
  41. Zong, E., Wei, D., Wan, H., Zheng, S., Xu, Z. and Zhu, D. (2013), "Adsorptive removal of phosphate ions from aqueous solution using zirconia-functionalizedgraphite oxide", Chem. Eng. J., 221, 193-203. https://doi.org/10.1016/j.cej.2013.01.088

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