Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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Synthesis and Characterization of CoAl2O4 Inorganic Pigment Nanoparticles by a Reverse Micelle Processing

역-마이셀 공정에 의한 CoAl2O4 무기안료 나노 분말의 합성 및 특성

  • Son, Jeong-Hun (School of Nano & Advanced Materials Eng., Changwon National Univ.) ;
  • Bae, Dong-Sik (School of Nano & Advanced Materials Eng., Changwon National Univ.)
  • 손정훈 (국립창원대학교 신소재공학과) ;
  • 배동식 (국립창원대학교 신소재공학과)
  • Received : 2014.05.02
  • Accepted : 2014.06.25
  • Published : 2014.07.27
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Abstract

Inorganic pigments have high thermal stability and chemical resistance at high temperature. For these reasons, they are used in clay, paints, plastic, polymers, colored glass and ceramics. $CoAl_2O_4$ nano-powder was synthesized by reverse-micelle processing the mixed precursor(consisting of $Co(NO_3)_2$ and $Al(NO_3)_3$). The $CoAl_2O_4$ was prepared by mixing an aqueous solution at a Co:Al molar ratio of 1:2. The average particle size, and the particle-size distribution, of the powders synthesized by heat treatment (at 900; 1,000; 1,100; and $1,200^{\circ}C$ for 2h) were in the range of 10-20 nm and narrow, respectively. The average size of the synthesized nano-particles increased with increasing water-to-surfactant molar ratio. The synthesized $CoAl_2O_4$ powders were characterized by X-ray diffraction analysis(XRD), field-emission scanning electron microscopy(FE-SEM) and color spectrophotometry. The intensity of X-ray diffraction of the synthesized $CoAl_2O_4$ powder, increased with increasing heating temperature. As the heating temperature increased, crystal-size of the synthesized powder particles increased. As the R-value(water/surfactant) and heating temperature increased, the color of the inorganic pigments changed from dark blue-green to cerulean blue.

Keywords

References

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