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Effects of Li2O Addition and Heat-Treatment on Formability of FeS2 Powder for Cathode of Thermal Battery

열전지 양극용 FeS2 분말의 성형성에 미치는 Li2O 첨가 및 열처리의 효과

  • 류성수 (한국세라믹기술원 엔지니어링세라믹팀) ;
  • 이원진 (한국세라믹기술원 엔지니어링세라믹팀) ;
  • 김성원 (한국세라믹기술원 엔지니어링세라믹팀) ;
  • 정해원 (국방과학연구소 국방신기술본부) ;
  • 조성백 (국방과학연구소 국방신기술본부) ;
  • 강승호 (국방과학연구소 국방신기술본부) ;
  • 이성민 (한국세라믹기술원 엔지니어링세라믹팀)
  • Received : 2014.06.02
  • Accepted : 2014.06.18
  • Published : 2014.06.28

Abstract

$FeS_2$ has been widely used for cathode materials in thermal battery because of its high stability and current capability at high operation temperature. Salts such as a LiCl-KCl were added as a binder for improving electrical performance and formability of $FeS_2$ cathode powder. In this study, the effects of the addition of $Li_2O$ in LiCl-KCl binder on the formability of $FeS_2$ powder compact were investigated. With the increasing amount of $Li_2O$ addition to LiCl-KCl binder salts, the strength of the pressed compacts increased considerably when the powder mixture were pre-heat-treated above $350^{\circ}C$. The heat-treatment resulted in promoting the coating coverage of $FeS_2$ particles by the salts as $Li_2O$ was added. The observed coating as $Li_2O$ addition might be attributed to the enhanced wettability of the salt rather than its reduced melting temperature. The high strength of compacts by the $Li_2O$ addition and pre-heat-treatment could improve the formability of $FeS_2$ raw materials.

Keywords

References

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