한국환경과학회지 (Journal of Environmental Science International)

  • 제23권6호
  • /
  • Pages.1157-1163
  • /
  • 2014
  • /
  • 1225-4517(pISSN)
  • /
  • 2287-3503(eISSN)
한국환경과학회 (The Korean Environmental Sciences Society)
권호 표지
DOI QR코드

DOI QR Code

고체상 추출제로서 Polyvinyl Chloride에 D2EHPA를 고정화한 PVC-D2EHPA의 제조와 Cu(II) 제거 특성

Preparation of PVC-D2EHPA beads by Immobilization of D2EHPA on Polyvinyl Chloride as Solid Phase Extractant and Removal Characteristics of Cu(II)

  • Kam, Sang-Kyu (Department of Environmental Engineering, Jeju National University) ;
  • You, Hae-Na (Department of Chemical Engineering, Pukyong National University) ;
  • Lee, Dong-Hwan (Department of Chemistry, Dong Eui University) ;
  • Lee, Min-Gyu (Department of Chemical Engineering, Pukyong National University)
  • 투고 : 2014.04.16
  • 심사 : 2014.05.28
  • 발행 : 2014.06.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The solid phase extractant (PVC-D2EHPA bead) was prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polyvinyl chloride (PVC). The prepared PVC-D2EHPA beads were characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal experiments of Cu(II) by PVC-D2EHPA beads conducted batchwise. The removal kinetics of Cu(II) was found to follow the pseudo-second-order model. The equilibrium data fitted well with Langmuir isotherm model and the maximum removal capacity was 2.6 mg/g at $20^{\circ}C$. The optimum pH region was in the range of 3.5 to 6. and the standard free energy (${\Delta}G^{\circ}$) was between -4.67~-4.98 kJ/mol, indicating the spontaneous nature of Cu(II) removal by PVC-D2EHPA beads.

키워드

참고문헌

  1. Alguacil, F. J., Alonso, M., Lopez, F., Lopez-Delgado, A., 2008, Uphill permeation of Cr(VI) using Hostarex A327 as ionophore by membrane-solvent extraction processing, Chemosphere, 72, 684-689. https://doi.org/10.1016/j.chemosphere.2008.02.030
  2. Feklistov, D., Laguntsov, N., Penkina, Y., Kim, V., 2004, Encapsulated di-2- ethylhexylphosphoric acid : synthesis, dispersity, and extraction properties, Ars Sep. Acta, 3, 40-50.
  3. Gherasim, C. V., Bourceanu, G., Olariu, R. I., Arsene, C., 2011, Removal of lead(II) from aqueous solutions by a polyvinyl-chloride inclusion membrane without added plasticizer, J. Membr. Sci., 377, 167-174. https://doi.org/10.1016/j.memsci.2011.04.042
  4. Gong, X. C., Luo, G. S., Yang, W. W., Wu, F. Y., 2006, Separation of organic acids by newly developed polysulfone microcapsules containing triotylamine, Sep. Purif. Technol., 48, 235-243. https://doi.org/10.1016/j.seppur.2005.07.030
  5. Jung H. S., Lee, G. H., 2011, Effect of operating parameters on the removal performance of copper ion by electrodialysis (in korean), J, Korean Soc, Water Qual,, 27, 54-60.
  6. Kabay, N., Cortina, J. L., Trochimczuk, T., Streat, M., 2010, Solvent-impregnated resins(SIRs) - Methods of preparation and their applications, React. Funct. Polym., 70, 484-496. https://doi.org/10.1016/j.reactfunctpolym.2010.01.005
  7. Kentish, S. E., Stevens, G. W., 2001, Innovations in separations technology for the recycling and re-use of liquid waste streams, Chem. Eng. J., 84, 149-159. https://doi.org/10.1016/S1385-8947(01)00199-1
  8. Kobayashi, T., Yoshimoto, M., Nakao, K., 2010, Preparation and characterization of immobilized chelate extractant in PVA gel bead for an efficient recovery of copper(II) in aqueous solution, Ind. Eng. Chem. Res., 49, 1652-1660. https://doi.org/10.1021/ie901543w
  9. Kolev, S. D., Baba, Y., Cattrall, R. W., Tasaki, T., Pereira, N., Perera, J. M., Stevens, G. W., 2009, Solid phase extraction of zinc (II) using a PVC-based polymer inclusion membrane with di (2-ethylhexyl) phosphoric acid (D2EHPA) as the carrier, Talanta, 78, 795-799. https://doi.org/10.1016/j.talanta.2008.12.047
  10. Liu. Y., 2006, Some consideration on the Langmuir isotherm equation, Colloids Surf. A: Physicochem. Eng., 274, 34-36. https://doi.org/10.1016/j.colsurfa.2005.08.029
  11. Trochimczuk, A. W., Kabay, N., Arda, M., Streat, M., 2004, Stabilization of solvent impregnated resins (SIRs) by coating with water soluble polymers and chemical crosslinking, React. Funct. Polym., 59, 1-7. https://doi.org/10.1016/j.reactfunctpolym.2003.12.011
  12. Vellaichamy, S. and Palanivelu, K., 2011, "Preconcentration and separation of copper, nickel and zinc in aqueous samples by flame atomic absorption spectrometry after column solid-phase extraction onto MWCNTs impregnated with D2EHPA-TOPO mixture", J. Hazard. Mater., Vol. 185, 1131-1139. https://doi.org/10.1016/j.jhazmat.2010.10.023
  13. Wanngah, W. S., Endud, C. S., Mayanar, R. 2002, Removal of copper (II) ions from aqueous solution onto chitosan and cross-linked chitosan beads, React. Funct. Polym., 50, 181-190. https://doi.org/10.1016/S1381-5148(01)00113-4
  14. Xu, J., Xu, Z. L., 2002, Poly(vinyl chloride) (PVC) hollow fiber ultrafiltration membranes prepared from PVC/additives/solvent, J. Membr. Sci., 208, 203-212. https://doi.org/10.1016/S0376-7388(02)00261-2
  15. Yadav, K. K., Singh, D. K., Anitha, M., Varshney, L., Singh, H., 2013, Studies on separation of rare earths from aqueous media by polyethersulfone beads containing D2EHPA as extractant, Sep. Purif. Technol., 118, 350-358. https://doi.org/10.1016/j.seppur.2013.07.012
  16. Yang, W. W., Luo, G. S., Gong, X. C., 2005, Extraction and separation of metal ions by a column packed with polystyrene microcapsules containing Aliquat 336, Sep. Purif. Technol., 43, 175-182. https://doi.org/10.1016/j.seppur.2004.08.007
  17. Yang, W. W., Luo, G. S., Wu, F. Y., Chen, F., Gong, X. C., 2004, Di-2-ethylhexyl phosphoric acid immobilization with polysulfone microcapsules, React. Funct. Polym., 61, 91-99. https://doi.org/10.1016/j.reactfunctpolym.2004.04.002

피인용 문헌

  1. Preparation of Solid-Phase Extractant by Immobilizing Di-(2-ethylhexyl)phosphoric Acid (D2EHPA) and Tri-butyl-phosphate (TBP) in Polysulfone and Removal Characteristics of Cu(II) vol.24, pp.1, 2015, https://doi.org/10.5322/JESI.2015.24.1.1
  2. Removal Characteristics of Sr(II) by Solid-Phase Extractant Prepared by Immobilizing Di-(2-ethylhexyl)phosphoric acid (D2EHPA) and Tri-butyl-phosphate (TBP) in Polysulfone vol.24, pp.3, 2015, https://doi.org/10.5322/JESI.2015.24.3.267