Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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Synthesis of Gemini Type Cationic Surfactants and Properties of Spacer Length

제미니형 양이온 계면활성제 합성 및 Spacer 길이에 따른 물성

  • Park, Jong-Kwon (Department of Engineering Chemistry, College of Engineering, Chungbuk National University Chemistry) ;
  • Jeong, Noh-Hee (Department of Engineering Chemistry, College of Engineering, Chungbuk National University Chemistry)
  • 박종권 (충북대학교 공과대학 공업화학과) ;
  • 정노희 (충북대학교 공과대학 공업화학과)
  • Received : 2013.12.06
  • Accepted : 2014.01.10
  • Published : 2014.03.30
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Abstract

Gemini type of cationic surfactant, namely ${\alpha},{\omega}$-alkane-bis(N-lauroyloxyethyl-N,N-dimethyl)-diammonium bromide was synthesized and confirmed by FT-IR and $^1H$-NMR spectroscopy. Their inhibition effect on corrosion of mild steel in 1 M HCl solution was tested by weight loss method. Surface tensions were measured by surface tensiometer Sigma 70. Their c.m.c. values evaluated by surface tension method was $4.01{\times}10^{-5}{\sim}4.99{\times}10^{-5}mol/L$. The Krafft point of the these surfactants were < $0^{\circ}C$. The emulsifying properties of synthesized cationic gemini surfactants and sodium dodecyl sulfate (SDS), tetradecyl trimethyl ammonium bromide (TTAB) was investigated. Of these, ${\alpha},{\omega}$-alkane-bis(N-lauroyloxyethyl-N,N-dimethyl)-diammonium bromide has been confirmed as a good emulsifier. The inhibition efficiency increases by increasing cationic gemini surfactant concentration. As a result, these surfactants are expected to be applied as corrosion inhibitors.

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References

  1. A. Yaroslavov, O. Yu. Udalykh, N. S. Melik-Nuberov, V. A. Kabanov, Y. A. Ermakov, V. A. Azov, and F. M. Menger, "Conventional and Gemini Surfactants Embedded Within Bilayer Membranes: Contrasting Behavior". J. Chem. Eur. 7, 4835 (2001). https://doi.org/10.1002/1521-3765(20011119)7:22<4835::AID-CHEM4835>3.0.CO;2-Y
  2. F. M. Menger, J.S. Keiper and Angew. "Gemini Surfactants". Chem. Int. Ed. 39 1906 (2000) https://doi.org/10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-Q
  3. J. W. McBain, "Advances in Colloid Science", Wiley, New York, 5, 196, (1972)
  4. R. Zana, and J. Xia, Gemini Surfactants; Marcel Dekker: New York, (2004)
  5. D. T. Lee, H. Kim and H. S. Cho, "Gemini surfactants", J. of Korean Oil Chemist'Soc., 11, 1 (1994).
  6. F. M. Menger and J. S. Keiper, "Gemini surfactants", Angewandte Chemie International Edition, (2000).
  7. T. A. Camesano and R. Nagarajan, "Micelle formation and CMC of gemini surfactants: A thermodynamic model", Colloids and Surfaces A: Physicochemical and Eng. Aspects, 167, 165 (2000). https://doi.org/10.1016/S0927-7757(99)00473-2
  8. F. M. Menger and C. A. Littau, "Gemini-surfactants: synthesis and properties", J. Am. Chem. Soc., 113, 1452 (1991).
  9. F. M. Menger and C. A. Littau, "Gemini surfactants: a new class of self-assembling molecules", J. Am. Chem. Soc., 115, 10083 (1993). https://doi.org/10.1021/ja00075a025
  10. S. Karaborni, K. Esselink, P. A. J. Hilbers, B. Smit, J. l. Karthauser, N. M. van Os and R. Zana, "Simulating the Self-Assembly of Gemini (Dimeric) Surfactants", Science., 226, 254 (1994).
  11. R. Zana, and J. Xia, Gemini Surfactants; Marcel Dekker: New York, (2004)
  12. F. M. Menger, J.S. Keiper, Angew. "Gemini Surfactants". Chem. Int. Ed. 39 1906 (2000) https://doi.org/10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-Q
  13. W. D. Bancroft, "The Theory of Emulsification, V", J. Phys. Chem., 17, 501 (1913)
  14. E. Jungermann, Cationic surfactants, organic chemistry of cationic surfactant, Vol l4, (1970).
  15. V. Seredyuk, E. Alami, M. Nyden, K. Holmberg, A. V. Peresypkin, and F. M. Menger, "Adsorption of Zwitterionic Gemini Surfactants at the Air-Water and Solid-Water Surfaces". Colloids & Surfaces, 203, 245, (2002). https://doi.org/10.1016/S0927-7757(01)01106-2
  16. M. Okahara, A. Masuyama, Y. Sumida, and Y. P. Zhu, "Surface active properties of amphiphilic compounds with two hydrophiphilic ionic groups and two lipophilic alkyl chains", J. of Japan Oil Chemist' Soc., 37, 746 (1988). https://doi.org/10.5650/jos1956.37.746
  17. L. Chen, Y. Shang, H. Liu and Y. Hu, "Middle-phase microemulsion induced by brine in region of low cationic gemini surfactant content", Colloids and Surfaces A : Physicochemical and Eng. Aspects, 305, 29 (2007). https://doi.org/10.1016/j.colsurfa.2007.04.037
  18. H. L. Rosano, D. Jon and J. H. Whittam, "Free energy, enthalpy, and entropy changes during the formation of a n-hexadecane/ potassium stearate / water / 1-pentanol microemulsion system", J. of Am. Oil Chemist Soc., 59, 360 (1982). https://doi.org/10.1007/BF02541020
  19. L. Han, H. Chen and P. Luo, "Viscosity behavior of cationic gemini surfactants with long alkyl chains", Surface Science, 564, 141 (2004). https://doi.org/10.1016/j.susc.2004.06.172
  20. A. Dourna, A. Mokhtar and M. M. Niyaz, "Electrochemical effect of cationic gemini surfactant and halide salts on corrosion inhibition of low carbon steel in acid medium.", Corrosion Science, 52, 794, (2010). https://doi.org/10.1016/j.corsci.2009.10.039