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Dielectric Relaxation Properties of KNN-BT Ceramics with (Ba,Ca)SiO3 Glass Frit

(Ba,Ca)SiO3 Glass Frit 첨가에 따른 NKN-BT 세라믹스의 유전 완화 특성

  • Bae, Seon Gi (Department of Electrical Engineering, Incheon National University) ;
  • Shin, Hyeo-Kyung (Department of Electrical Engineering, Incheon National University) ;
  • Lee, Seung-Hwan (R&D Center, Samwha Capacitor Co., Ltd.) ;
  • Im, In-Ho (Electrical Engineering, Shinansan University)
  • 배선기 (인천대학교 전기공학과) ;
  • 신혜경 (인천대학교 전기공학과) ;
  • 이승환 (삼화콘덴서공업(주) R&D Center) ;
  • 임인호 (신안산대학교 전기과)
  • Received : 2014.05.02
  • Accepted : 2014.05.15
  • Published : 2014.06.01

Abstract

We investigated dielectric relaxation properties of $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3$ ceramics by addition (0~0.3 wt%) of $(Ba,Ca)SiO_3$ glass frit. All composition of $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3$ added $(Ba,Ca)SiO_3$ glass frit showed the same crystallographic properties, coexistence of orthorhombic and tetragonal phase. By increasing addition of $(Ba,Ca)SiO_3$ glass frit, the Curie temperatures of $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3$ ceramics were decreased, whereas maximum dielectric constants of $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3$ ceramics were dramatically increased. Especially the deviations of Curie temperature $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3$ ceramics were increased by increasing amount of $(Ba,Ca)SiO_3$ glass frit, and it indicated that $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3$ ceramics added $(Ba,Ca)SiO_3$ glass frit have relaxor characteristics.

Keywords

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