Korean Chemical Engineering Research

  • 제52권3호
  • /
  • Pages.289-293
  • /
  • 2014
  • /
  • 0304-128X(pISSN)
  • /
  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
권호 표지
DOI QR코드

DOI QR Code

Tween계 비이온 계면활성제를 이용하여 중합한 에멀션점착제의 접착물성

Adhesive Properties of Emulsion PSA Polymerized Using Tween Series Nonionic Surfactants

  • 임태균 (동국대학교 화공생물공학과) ;
  • 이명천 (동국대학교 화공생물공학과)
  • Lim, Tae Kyun (Department of Chemical and Biochemical Engineering, Dongguk University) ;
  • Lee, Myung Cheon (Department of Chemical and Biochemical Engineering, Dongguk University)
  • 투고 : 2013.11.13
  • 심사 : 2013.12.12
  • 발행 : 2014.06.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

에멀션형 점착제 분야에서 노닐페닐계 비이온 계면활성제를 대체할 수 있는 친환경 비이온 계면활성제를 찾기 위해 Tween계 비이온 계면활성제를 선정하여 에멀션형 점착제를 제조한 후 이를 노닐페닐계 비이온 계면활성제인 NP-40을 사용한 점착제와 점착물성을 비교해 봄으로써 그 대체 가능성을 확인하였다. 이 결과 Tween 60과 Tween 80의 경우 NP-40의 경우보다 박리강도와 유지력 면에서 매우 우수한 점착물성을 보임을 알 수 있었다.

In making emulsion type pressure sensitive adhesive (PSA), environmentally friendly Tween series nonionic surfactants were used to find out the possibility of substituting the traditional nonyl-phenyl nonionic surfactant (NP-40) by comparing their adhesive properties. Results exhibited that the PSA used Tween series nonionic surfactants showed much better adhesive properties in peel strength and holding power than that used NP-40.

키워드

참고문헌

  1. Mallegol, J., Gorce, J.-P., Dupont, O., Jeynes, C., McDonald, P. J. and Keddie, J. L., "Origins and Effects of a Surfactant Excess near the Surface of Waterborne Acrylic Pressure-Sensitive Adhesives," J. Am. Chem. Soc., 18(11), 4478-4487(2002).
  2. Lee, H. J., Jang, S. H., Chang, S. M. and Kim, J. M.,"Study on Polymerization Condition of Water-based Acrylic Adhesion," Korean Chem. Eng. Res.(HWAHAK KONGHAK), 48(5), 609-614(2010).
  3. Zosel, A. and Schuler, B., "The Influence of Surfactants on the peel strength of Water-based Pressure Sensitive Adhesives," J. Adhes., 70(1-2), 179-195(1999). https://doi.org/10.1080/00218469908010494
  4. Kim, N. S. and Kim, S. H., "Effect of Protective Colloid on the Synthesis of Poly(Vinyl acetate-co-Ethyl acrylate," J. Korean Oil Chemists' Soc., 27(2), 216-221(2010).
  5. Youn, H. J. and Lee, H. L., "Development of Multi-function Mulch papers and Evaluation of Their Performance," Journal of Korea Technical Association of the Pulp and Paper Industry, 30(3), 38-45(1998).
  6. Lindgren, A., Sjostrom, M. and Wold, S., "Quantitative Structure-Effect Relationships for Some Technical Nonionic Surfactants," J. Am. Oil Chem. Soc., 73(7), 863-875(1996). https://doi.org/10.1007/BF02517988
  7. Uppgard, L., Lindgren, A., Sjostrom, M. and Wold, S., "Multivariate Quantitative Structure-Activity Relationships for the Aquatic Toxicity of Alkyl Polyglucosides," J. Surfactants Deterg., 37(2), 131-138(2000).
  8. Han, I. S., "Environmentally friendly Nonionic Surfactant," Surfactant/ Adhesive, 22(3), 2-7(2005).
  9. Gautam, K. K. and Tyagi, V. K., "Microbial Surfactants: A Review," J. Oleo Sci., 55(2), 155-166(2006). https://doi.org/10.5650/jos.55.155
  10. Maneerat, S. J., "Biosurfactants from Marine Microorganism," Sci. Tech., 27(6), 1263-1272(2005).
  11. Schramm, L. L., Stasiuk, E. N. and Marangoni, D.G., "Surfactants and Their applications," Annu. Rep. Prog. Chem., Sect. C, 99(2), 3-48(2003).
  12. Park, M. C. and Lee, M. C., "Effects of Polymeric Emulsifiers on the Properties of Acrylic Emulsion Pressure-Sensitive Adhesives," J. Appl. Polym. Sci., 94(2), 1456-1460(2004). https://doi.org/10.1002/app.21052
  13. Park, M. C. and Lee, M. C., "Adhesive Properties of Acrylic Emulsion Pressure Sensitive Adhesives with Polymeric Emulsifier," Polymer, 27(6), 596-602(2003).
  14. Seo, I. S. and Lee, M. C., "Effects of Intra-particle Composition on the Adhesive Properties and Water Dispersity of Water Dispersible Acrylic Emulsion Pressure Sensitive Adhesive," J. Korean Ind. Eng. Chem., 18(5), 444-448(2007).
  15. Li, B. and Brooks, B. W., "Semi-batch Processes for Emulsion Polymerisation," Polym. Int., 29(1), 41-46(1992). https://doi.org/10.1002/pi.4990290109