DOI QR코드

DOI QR Code

Attrition Characteristics of WGS Catalysts for SEWGS System

SEWGS 시스템을 위한 WGS 촉매들의 마모특성

  • Received : 2014.02.20
  • Accepted : 2014.04.30
  • Published : 2014.04.30

Abstract

Attrition characteristics of WGS catalysts for pre-combustion $ CO_2$ capture were investigated to check attrition loss of those catalysts, to check change of particle size distribution during attrition tests, and to determine solid circulation direction of WGS catalysts in a SEWGS system. The cumulative attrition losses of two catalysts increased with increasing time. However, attrition loss under humidified condition was lower than that under non-humidified condition case for long-term attrition tests. Between two catalysts, attrition loss of PC-29 catalyst was higher than that of commercial catalyst for long-term attrition tests. However, the commercial catalyst generated much more fines than PC-29 catalyst during attrition. Therefore, we conclude that the PC-29 catalyst is more suitable for fluidized bed operation if we take into account the separation efficiency of cyclone. Based on the results from the tests for the effect of humidity on the attrition loss, we selected solid circulation direction from SEWGS reactor to regeneration reactor because the SEWGS reactor contains more water vapor than regeneration reactor.

Keywords

References

  1. R. James, "Clean Coal technology Status: $CO_2$ Capture and Storage", Technology Briefing for Colorado Rural Electric Association, EPRI, 2007.
  2. H. J. Ryu, "Selection of Process Configuration and Operating Conditions for SEWGS System", Trans. of the Korean Hydrogen and New Energy Society, Vol. 20, No. 2, 2009, pp. 168.
  3. H. J. Ryu, J. S. Hyun, H. Kim, and T. S. Hwang, "Reaction Characteristics of WGS Catalyst with Fraction of Catalyst in a Batch Type Fluidized Bed Reactor", Trans. of the Korean Hydrogen and New Energy Society, Vol. 22, No. 4, 2011, pp. 465.
  4. H. J. Ryu, Y. C. Park, S. H. Jo, and M. H. Park, "Development of Novel Two-Interconnected Fluidized Bed System", Korean Journal of Chemical Engineering, Vol. 25, No. 5, 2008, pp. 1178-1183. https://doi.org/10.1007/s11814-008-0194-z
  5. H. J. Ryu, "Selection of Process Configuration and Operating Conditions for SEWGS System", Trans. of the Korean Hydrogen and New Energy Society, Vol. 20, No, 2, 2009, pp. 168-178.
  6. H. J. Ryu, J. Park, H. K. Kim, and M. H. Park, "Solid Circulation Characteristics in a 3kW Chemical- looping Combustor", Korean Chem. Eng. Res., Vol. 46, No. 6, 2008, pp. 1057-1062.
  7. H. J. Ryu, H. S. Kim, S. Y. Lee, D. H. Lee, and J. C. Kim, "Effects of Operating Variables on Sorption Capacity of $CO_2$ absorbents for SEWGS Process", Korean Chem. Eng. Res., Vol. 50, No. 6, 2012, pp. 994-1001. https://doi.org/10.9713/kcer.2012.50.6.994
  8. H. J. Ryu, J. S. Hyun, H. Kim, and T. S. Hwang, "Reaction Characteristics of WGS Catalyst with Fraction of Catalyst in a Batch Type Fluidized Bed Reactor", Trans. of the Korean Hydrogen and New Energy Society, Vol. 22, No. 4, 2011, pp. 465-473.
  9. H. Kim, D. H. Lee, S. Y. Lee, T. S. Hwang, and H. J. Ryu, "Reaction Characteristics of WGS Catalyst for SEWGS Process in a Pressurized Fluidized Bed Reactor", Trans. of the Korean Hydrogen and New Energy Society, Vol. 23, No. 4, 2012, pp. 337-345. https://doi.org/10.7316/KHNES.2012.23.4.337
  10. H. J. Ryu, D. H. Lee, J. H. Moon, Y. Park, and S. H. Jo, "The Characteristics of Attrition of Absorbents for Pre-combustion $CO_2$ Capture", Trans. of the Korean Hydrogen and New Energy Society, Vol. 24, No. 5, 2013, pp. 428-436. https://doi.org/10.7316/KHNES.2013.24.5.428
  11. Y. S. Moon, C. K. Yi, J. E. Son, C. K. Ryu, and J. H. Choi, "The Effect of Fluidized-Bed Variables on Attrition of Solid Particles", J. Korean Ind. Eng. Chem., Vol. 16, No. 5, 2005, pp. 603-608.
  12. Y. S. Park, and J. E. Son, "Attrition characteristics of Domestic Low Grade Anthracite Coal in a Fluidized Bed Combustor", HWAHAK KONGHAK, Vol. 28, No. 3, 1990, pp. 320-326.
  13. C. K. Ryu, and J. B. Lee, "Standard Test Method for Determination of Attrition of Powdered sorbents by Air Jet", KEPRI report, 1991, TM. 97GJ17, I1999.431.

Cited by

  1. CO Conversion Characteristics of WGS Catalysts for SEWGS System vol.26, pp.2, 2015, https://doi.org/10.7316/KHNES.2015.26.2.096
  2. Selection of Oxygen Carrier Candidates for Chemical Looping Combustion by Measurement of Oxygen Transfer Capacity and Attrition Loss vol.27, pp.4, 2016, https://doi.org/10.7316/KHNES.2016.27.4.404