Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
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Adsorption of Low-level CO2using Activated Carbon Pellet with Glycine Metal Salt Impregnation

글리신 금속염 함침 입자상 활성탄의 저농도 이산화탄소 흡착능 평가연구

  • Lim, Yun Hui (Department of Applied Environmental Science, Center for Environmental Studies, Kyung Hee University) ;
  • Adelodun, A.A. (Department of Applied Environmental Science, Center for Environmental Studies, Kyung Hee University) ;
  • Jo, Young Min (Department of Applied Environmental Science, Center for Environmental Studies, Kyung Hee University)
  • 임윤희 (경희대학교 환경응용과학과, 환경연구센터) ;
  • ;
  • 조영민 (경희대학교 환경응용과학과, 환경연구센터)
  • Received : 2013.07.17
  • Accepted : 2013.10.28
  • Published : 2014.02.28
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Abstract

The present study has evaluated the $CO_2$ adsorption amount of activated carbon pellets (AC). Coconut shell based test AC were modified with surface impregnation of glycine, glycine metal salts and monoethanolamine for low level $CO_2$ (3000 ppm) adsorption. Physical and chemical properties of prepared adsorbents were analyzed and the adsorbed amount of $CO_2$ was investigated by using pure and 3,000 ppm $CO_2$ levels. The impregnation of nitrogen functionalities was verified by XPS analysis. The adsorption capacity for pure $CO_2$ gas was found to reach upto 3.08 mmol/g by AC-LiG (Activated carbon-Lithium glycinate), which has the largest specific surface area ($1026.9m^2/g$). As for low level $CO_2$ flow the primary amine impregnated adsorbent showed 0.26 mmol/g of adsorption amount, indicating the highest selectivity. An adsorbent with potassium-glycine salts (AC-KG, Activated carbon-Potassium glycinate) instead of amine presented with 0.12 mmol/g of adsorption capacity, which was higher than that of raw activated carbon granules (0.016 mmol/g).

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References

  1. Ahn, S.Y., H.J. Song, J.W. Park, J.H. Lee, I.Y. Lee, and K.R. Jang (2010) Characterization of metal corrosion by aqueous amino acid salts for the capture of $CO_2$, Korean J. Chem. Eng., 27(5), 1576-1580. https://doi.org/10.1007/s11814-010-0246-z
  2. Arenillas, A., K.M. Smith, T.C. Drage, and C.E. Snape (2005) $CO_2$ capture using some fly ash-derived carbon materials, Fuel, 84, 2204-2210. https://doi.org/10.1016/j.fuel.2005.04.003
  3. Baek, S.O. and Y.S. Kim (1998) Characterization of Air Quality in Various Types of Indoor Environments in Urban Areas-Focusing on Homes, Offices, and Restaurants-, J. KAPRA, 14(4), 343-360.
  4. Beruto, D., R. Botter, and A.W. Searcy (1984) Thermodynamics and kinetics of carbon dioxide chemisorption on calcium oxide, J. Phys. Chem., 88(18), 4052-4055. https://doi.org/10.1021/j150662a039
  5. Biniak, S., G. Szyma'nski, J. Siedlewski, and A. 'Swiakowski (1997) The characterization of activated carbons with oxygen and nitrogen surface groups, Carbon, 35(12), 1799-1810. https://doi.org/10.1016/S0008-6223(97)00096-1
  6. Diaz, E., E. Munoz, A. Vega, and S. Ordonez (2008) Enhancement of the $CO_2$ retention capacity of Y zeolites by Na and Cs treatments: effect of adsorption temperature and water treatment, Ind. Eng. Chem. Res., 47 (2), 412-418. https://doi.org/10.1021/ie070685c
  7. Gray, M.L., Y. Soong, K.J. Champagne, H. Pennline, J.P. Baltrus, R.W. Stevens Jr., R. Khatri, S.S.C. Chuang, and T. Filburn (2005) Improved Immobilized Carbon Dioxide Capture Sorbents, Fuel Processing Technology, 86(14-15), 1449-1455. https://doi.org/10.1016/j.fuproc.2005.01.005
  8. Han, J.U., D.J. Kim, M. Kang, J.W. Kim, J.M. Kim, and J.E. Yie (2005) Study of $CO_2$ Adsorption Characteristics on Acid Treated and LiOH Impregnated Activated Carbons, J. Korean Ind. Eng. Chem., 16(3), 312-316.
  9. Jeon, J.K., Y.K. Park, and K. Chue (2004) Study of PSA process for carbon dioxide recovery over zeolite adsorbent: Effect of rinse rate on process performance J. Korean Soc. Atmos. Environ., 20(1), 99-110.
  10. Jo, D.H., K.S. Cho, C.G. Park, and S.H. Kim (2012) Effects of Inorganic-organic Additives on $CO_2$ Adsorption of Activated Carbon, Korean Chem. Eng. Res., 50(5), 885-889. https://doi.org/10.9713/kcer.2012.50.5.885
  11. Kang, K.H., S.K. Kam, S.W. Lee, and M.G. Lee (2007) Adsorption characteristics of activated carbon prepared from waste citrus peels by NaOH activation, J. Environ. Sci., 16(11), 1279-1285. https://doi.org/10.5322/JES.2007.16.11.1279
  12. Kim, K.H., Y.H. Lim, and Y.M. Jo (2010) Adsorption Isotherm of Low Level Carbon Dioxide in Indoor Air, J. Korean Soc. Indoor Environ., 7(2), 113-126.
  13. Kim, J.M. (2009) Status and prospect of carbon dioxide storage technologies, KIC News, 12(2), 31-41.
  14. Kim, M.J., S.H. Chung, M.S. Lee, D.W. Lee, and K.Y. Lee (2013) Catalytic Nitrate Reduction in Water over Mesoporous Silica Supported Pd-Cu Catalysts, Clean Technology, 19(1), 65-72. https://doi.org/10.7464/ksct.2013.19.1.065
  15. Knowles, G.P., S.W. Delaney, and A.L. Chaffee (2006) Diethylenetriamnie [propyl (silyl)]-Functionalized (DT) Mesoporous Silicaes as $CO_2$ Adsorbents, Ind. Eng. Chem. Res., 45, 2626-2633. https://doi.org/10.1021/ie050589g
  16. Kumar, P.S., J.A. Hogendoorn, G.F. Versteeg, and P.H.M. Feron (2003) Kinetics of the reaction of $CO_2$ with aqueous potassium salt of taurine and glycine, AlChE Journal, 49(1), 203-213. https://doi.org/10.1002/aic.690490118
  17. Lee, K.M. and Y.M. Jo (2009) Ambient adsorption of low level carbon dioxide by metal treated activated carbon, J. Korean Soc. Atmos. Environ., 25(4), 316-324. https://doi.org/10.5572/KOSAE.2009.25.4.316
  18. Lim, Y.H., Y.K. Park, and Y.M. Jo (2012) Characterization of Glycine Metal Salts for $CO_2$ Absorption, Appl. Chem. Eng., 23(3), 284-288.
  19. Lim, Y.H., Y.M. Jo, and J.S. Park (2011) $CO_2$ Absorption by Alkali-modified Amino Acid Salts, Appl. Chem. Eng., 22(5), 526-531.
  20. Lim, Y.H., Y.M. Jo, and S.H. Kim (2013) Adsorption of Carbon Dioxide using Pelletized AC with Amine impregnation, Journal of the Korean Oil Chemists' Society, 30(1), 88-95. https://doi.org/10.12925/jkocs.2013.30.1.088
  21. Lu, C., H. Bai, F. Su, W. Chen, J.F. Hwang, and H.H. Lee (2010) Adsorption of Carbon Dioxide from Gas Streams via Mesoporous Spherical-Silica Particles, J. Air & Waste Manage. Assoc., 60(4), 489-496. https://doi.org/10.3155/1047-3289.60.4.489
  22. Mathonat, C., V. Majer, A.E. Mather, and J.P.E. Grolier (1997) Enthalpies of absorption and solubility of $CO_2$ in aqueous solutions of methyldiethanolamine, Fluid Phase Equilibria, 140(1-2), 171-182. https://doi.org/10.1016/S0378-3812(97)00182-9
  23. McKee, T. and J.R. McKee (2004) Biochemistry, 3/E, 80pp, Life Science Publishing Co.
  24. Park, J.M., Y.H. Park, S.H. Yi, and J.I. Park (2005) Temperature Compensation of NDIR $CO_2$ Gas Sensor, Proceeding of the KIEEME Annual Summer Conference, 6, 81-82.
  25. Song, H.J., S.M. Lee, J.H. Lee, J.W. Park, K.R. Jang, J.G. Shim, and J.H. Kim (2009) Absorption of Carbon Dioxide into Aqueous Potassium Salt of Serine, J. Kor. Soc. Environ. Eng., 31(7), 505-514.
  26. Thompson, R.W. and A. Dyer (1985) Nucleation of zeolite Na-A crystals in hydrothermal systems, Zeolites, 5, 302-308. https://doi.org/10.1016/0144-2449(85)90162-9
  27. Xu, X., C. Song, B.G. Miller, and A.W. Scaroni (2005) Adsorption separation of carbon dioxide from flue gas of natural gas-fired boiler by a novel nanoporous "molecular basket" adsorbent, Fuel Processing Technology, 86(14-15), 1457-1472. https://doi.org/10.1016/j.fuproc.2005.01.002
  28. Zou, Y., M. Vera, and A.E. Rodrigues (2002) Adsorption of Carbon Dioxide at High Temperature-a Review, Separation and Purification Technology, Separation and Purification Technology, 26(2/3), 195-205. https://doi.org/10.1016/S1383-5866(01)00165-4