Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Synthesis and Property of Pyrene-Naphthalene Diimide-Pyrene Triad

Pyrene-Naphthalene Diimide-Pyrene Triad의 합성 및 물성에 대한 연구

  • Kim, Hyunji (Department of Organic Material and Polymer Engineering, Dong-A University) ;
  • Kim, A-Rong (Department of Organic Material and Polymer Engineering, Dong-A University) ;
  • Park, Jong S. (Department of Organic Material and Polymer Engineering, Dong-A University)
  • 김현지 (동아대학교 유기재료고분자공학과) ;
  • 김아롱 (동아대학교 유기재료고분자공학과) ;
  • 박종승 (동아대학교 유기재료고분자공학과)
  • Received : 2014.09.15
  • Accepted : 2014.10.31
  • Published : 2014.12.27
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Abstract

In this study, we presented a newly synthesized pyrene-naphthalene diimide(NDI)-pyrene triad. The optical and structural properties were examined using various characterization techniques. A donor-acceptor-donor triad molecule exhibited a strong charge transfer, though there existed neither intramolecular nor intermolecular hydrogen bonding sites, due to the formation of preferential complementary complex between pyrene and NDI. Powder XRD measurement revealed a sharp and distinctive X-ray patterns, indicating the presence of microcrystalline-like structure. POM images showed anisotropic fingerprint texture similar to that of cholesteric phase, and SEM images showed numerous columnar structures with length of 1 to $10{\mu}m$. Above observation clearly demonstrated that ${\pi}$-complementary NDI-pyrene interactions in the traid was strong enough to form columnar aggregates in the long range.

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References

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