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Addition of nano particle to increase the cavitation resistance of urethane

나노입자 첨가를 통한 우레탄수지의 캐비테이션 저항 향상

  • Lee, Iksoo (Graduate School of Energy and Environment, Seoul National University of Science and Technology) ;
  • Kim, Nackjoo (Graduate School of Energy and Environment, Seoul National University of Science and Technology) ;
  • Pak, Daewon (Graduate School of Energy and Environment, Seoul National University of Science and Technology)
  • 이익수 (서울과학기술대학교, 에너지환경대학원) ;
  • 김낙주 (서울과학기술대학교, 에너지환경대학원) ;
  • 박대원 (서울과학기술대학교, 에너지환경대학원)
  • Received : 2014.11.19
  • Accepted : 2014.12.26
  • Published : 2014.12.30

Abstract

In this study, a new paint which is able to resist the cavitation erosion is tried to be developed by using urethane added with nano particles such as multi-wall and single-wall carbon nano tube and spherical and fiber type graphite. The new paint synthesized was characterized with physical properties and resistivity to cavitation erosion($t_{50}$). Among nano particles, fiber type graphite($t_{50}$ 292min) showed high hardness and wear resistance compared with spherical type($t_{50}$ 182min). For carbon nano tube, single-wall type($t_{50}$ 286min) was higher than multi-wall type in wear resistance. Fiber-type graphite was the best nano-particle for paint with resistivity to cavitation erosion. In the application test of paint, the manually painted sample showed surface with smooth but the surface of sample prepared with spray was not smooth. During spray, dust was fixed on the surface.

본 연구에서는 캐비테이션에 의한 부식에 강한 도료를 개발하기 위하여 고탄성의 우레탄 수지에 내마모 성능을 향상시키기 위한 첨가제로서 Multi wall과 Single wall type의 Carbon nano tube(CNT)와 Spherical과 Fiber type의 Graphite 나노 입자를 첨가하여 물성과 캐비테이션에 대한 저항성, 작업성 등을 비교 평가하였다. 나노 입자로서 Graphite에서는 캐비테이션 저항성($t_{50}$)이 Spherical type($t_{50}$ 182min)보다는 Fiber type($t_{50}$ 292min)이 높은 캐비테이션 저항성을 갖는 것으로 관찰되었다. 또한 CNT에서는 Single wall type의 캐비테이션 저항성($t_{50}$ 286min)이 Multi wall보다는 더 높은 것으로 관찰되었다. 나노 입자중에서 가격 및 캐비테이션 저항성을 감안하면 가장 최적의 나노 입자는 Fiber type의 Graphite로 관찰되었다. 도료의 작업성 평가에서 수동 작업에 의해 제작된 표면은 매끈한 표면을 가지고 있으나 Spray 작업에 의해 제작된 표면은 표면이 균일하지 않으며 Spray시 발생된 Dust가 표면에 고착된 형태로 관찰되었다.

Keywords

References

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