DOI QR코드

DOI QR Code

Accumulation of Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn in urban soil and their mobility characteristics

  • Bhattacharyya, Krishna G. (Department of Chemistry, Gauhati University) ;
  • Mahanta, Mayur J. (Department of Chemistry, Gauhati University)
  • 투고 : 2014.01.12
  • Accepted : 2014.08.12
  • Published : 2014.12.25

Abstract

Eight trace metals, Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn, were measured in the urban soil of Guwahati City, Assam, India from 31 sites representing five different types of land use, residential, commercial, industrial, public utilities, and roadside. Cd and Co occurred in very low concentrations (Cd << Co) in all types of land use without any significant variation from one type of land use to another. Ni concentrations were more than those of Co, and the concentrations depended on land use pattern. Average Cr and Cu concentrations were ${\geq}100mg/kg$, but Cr had a significantly higher presence in industrial land use. Pb concentrations showed similar trends. The two metals, Mn and Zn, were present in much larger amounts compared to the others with values ${\geq}300mg/kg$. Industrial and roadside soil contained much more Mn while commercial soil was enriched with Zn. Toxicity Characteristic Leaching Procedure (TCLP) was used for elucidating the mobility characteristics of the eight heavy metals. Mn suffered the highest leaching from commercial land (9.9 mg/kg on average) and also from other types of land. Co, Cu and Pb showed higher leachability from commercial soils but the leached concentrations were less than those of Mn. The two metals, Zn and Ni, were leached from residential land in considerable amounts. The TCLP showed Mn to be the most leachable metal and Cr the least.

Keywords

References

  1. Abollino, O., Aceto, M., Malandrino, M., Mentasti, E., Sarzanini, C. and Barberis, R. (2002), "Distribution and mobility of metals in contaminated sites: Chemo metric investigation of pollutant profiles", Environ. Pollut., 119(2), 177-193. https://doi.org/10.1016/S0269-7491(01)00333-5
  2. Adriano, D.C. (2001), "Biogeochemistry, bioavailability and risks of metals", Trace Elements in the Terrestrial Environment: (2nd Edition), Springer-Verlag, New York, NY, USA.
  3. Barceloux, D.G. and Barceloux, D. (1999), "Chromium", Clin. Toxicol., 37(2), 173-194. https://doi.org/10.1081/CLT-100102418
  4. Bhattacharyya, K.G. and Mahanta, M.J. (2011), "Total concentrations, fractionation and mobility of heavy metals in soils of urban area of Guwahati, India", Environ. Monit. Assess., 173(1-4), 221-240. https://doi.org/10.1007/s10661-010-1383-x
  5. Bullock, P. and Gregory, P.J. (Eds.) (1991), Soil in the Urban Environment, Oxford, Blackwell Scientific Publications, Boston.
  6. Charlesworth, S.M. and Lees, J.A. (1999), "The distribution of heavy metals in deposited urban dusts and sediments, Coventry, England", Environ. Geochem. Health, 21(2), 97-115. https://doi.org/10.1023/A:1006694400288
  7. Chlopecka, A., Bacon, J.R., Wilson, M.J. and Kay, J. (1996), "Forms of cadmium, lead and zinc in contaminated soils from southwest Poland", J. Environ. Quality, 25(1), 69-79.
  8. Glennon, M., Harris, P., Ottesen, R.T., Scanlon, R.P. and O'Connor, P. (2014), "The Dublin SURGE Project: Geochemical baseline for heavy metals in topsoils and spatial correlation with historic industry in Dublin, Ireland", J. Environ. Geochem. Health, 36(2), 235-254. https://doi.org/10.1007/s10653-013-9561-8
  9. Gonzalez, A.M. and Barnes, R.M. (2002), "Comparison of microwave-assisted extraction and waste extraction test (WET) preparation for inductively coupled plasma spectroscopic analyses of waste samples", Anal. Bioanal. Chem., 374(2), 255-261. https://doi.org/10.1007/s00216-002-1482-9
  10. Govil, P.K., Sorlie, J.E., Murthy, N.N., Sujatha, D., Reddy, G.L.N., Rudolph-Lund, K., Krishna, A.K. and Rama Mohan, K. (2008), "Soil contamination of heavy metals in the Katedan Industrial Development Area, Hyderabad, India", Environ. Monit. Assess., 140(1-3), 313-323. https://doi.org/10.1007/s10661-007-9869-x
  11. Gustafson, J.P., Pechova, P. and Berggren, D. (2003), "Modeling metal binding to soils: the role of natural organic matter", Environ. Sci. Tech., 37(12), 2767-2774. https://doi.org/10.1021/es026249t
  12. Harrison, R.M., Laxen, D.P.H. and Wilson, S.J. (1981), "Chemical associations of lead, cadmium, copper, and zinc in street dusts and roadside soils", Environ. Sci. Tech., 15(11), 1378-1383. https://doi.org/10.1021/es00093a013
  13. Heasman, L., van der Sloot, H.A. and Quevauviller, Ph. (1997), "Chapter 4: Contaminated Soil", Harmonization of Leaching/Extraction Tests, Elsviere, pp. 57-74.
  14. Herreweghe, S.V., Swennen, R., Vandecasteele, C. and Cappuyns, V. (2003), "Solid phase speciation of arsenic by sequential extraction in standard reference materials and industrially contaminated soil samples", Environ. Pollut., 122(3), 323-342. https://doi.org/10.1016/S0269-7491(02)00332-9
  15. Hooper, K., Iskander, M., Sivia, G., Hussein, F., Hsu, J., Deguzman, M., Odion, Z., Ilejay, Z., Sy, F., Petreas, M. and Simmons, B. (1998), "Toxicity characteristic leaching procedure fails to extract oxoanion-forming elements that are extracted by municipal solid waste leachates", Environ. Sci. Tech., 32(23), 3825-3830. https://doi.org/10.1021/es980151q
  16. Hu, Y., Liu, X., Bai, J., Shih, K., Zeng, E.Y. and Cheng, H. (2013), "Assessing heavy metal pollution in the surface soils of a region that had undergone three decades of intense industrialization and urbanization", Environ. Sci. Pollut. Res., 20(9), 6150-6159. https://doi.org/10.1007/s11356-013-1668-z
  17. Huang, J., Huang, R., Jiao, J.J. and Chen, K. (2007), "Speciation and mobility of heavy metals in mud in coastal reclamation areas in Shenzhen, China", Environ. Geol., 53(1), 221-228. https://doi.org/10.1007/s00254-007-0636-7
  18. Jaradat, Q.M., Massadeh, A.M., Zaitoun, M.A. and Maitah, B. (2006), "Fractionation and sequential extraction of heavy metals in the soil of scrap yard of discarded vehicles", Environ. Monit. Assess., 112(1-3), 197-210. https://doi.org/10.1007/s10661-006-0356-6
  19. Kaminski, M.D. and Landsberger, S. (2000), "Heavy metals in urban soils of East St. Louis, IL Part 2: Leaching characteristics and modeling", J. Air Waste Manag. Assoc., 50(9), 1680-1687. https://doi.org/10.1080/10473289.2000.10464190
  20. Krishna, A.K. and Govil, P.K. (2005), "Heavy metal distribution and contamination in soils of Thane-Belapur industrial development area, western India", Environ. Geol., 47(8), 1054-1061. https://doi.org/10.1007/s00254-005-1238-x
  21. Lagrega, M.D., Buckingham, P.L. and Evans, J.C. (1994), Hazardous Waste Management, McGraw-Hill Inc., Singapore, pp. 50-51.
  22. Linde, M., Bengtsson, H. and Oborn, I. (2001), "Concentrations and pools of heavy metals in urban soils in Stockholm, Sweden", Water, Air and Soil Pollution: Focus, 1(3-4), 83-101. https://doi.org/10.1023/A:1017599920280
  23. Lu, Y., Zhu, F., Chen, J., Gan, H. and Guo, Y. (2007), "Chemical fractionation of heavy metals in urban soils of Guangzhou, China", Environ. Monit. Assess., 134(1-3), 429-439. https://doi.org/10.1007/s10661-007-9634-1
  24. Masood, Md. (1982), "Structural history of the Precambrian rocks around Guwahati, Assam", Quart. J. Geol. Min. Meteorol. Soc. India, 54(1-2), 33-38.
  25. Moustafa El Nemr, A., El Sikaily, A. and Khaled, A. (2007), "Total and leachable heavy metals in muddy and sandy sediments of Egyptian Coast along Mediterranean Sea", Environ. Monit. Assess., 129(1-3), 151-168. https://doi.org/10.1007/s10661-006-9349-8
  26. Moller, A., Muller, H.W., Abdullah, A., Abdelgawad, G. and Utermann, J. (2005), "Urban soil pollution in Damascus, Syria: Contamination and patterns of heavy metals in this soils of the Damacus Ghouta", Geoderma, 124, 63-71. https://doi.org/10.1016/j.geoderma.2004.04.003
  27. Pan, Shih-C., Lin, Chin-C. and Tseng, Dyi-H. (2003), "Reusing sewage sludge ash as adsorbent for copper removal from wastewater", Resour. Conserv. Recy., 39(1), 79-90. https://doi.org/10.1016/S0921-3449(02)00122-2
  28. Prez-de-Mora, A., Burgos, P., Cabrera, F. and Madejon, E. (2007), ""In situ" amendments and revegetation reduce trace element leaching in a contaminated soil", Water Air Soil Pollut., 185(1-4), 209-222 https://doi.org/10.1007/s11270-007-9443-8
  29. Rakib, M.A., Ali, M., Akter, M.S. and Bhuiyan, M.A.H. (2014), "Assessment of heavy metal (Pb, Zn, Cr and Cu) content in roadside dust of Dhaka metropolitan city, Bangladesh", Int. Res. J. Environ. Sci., 3(1), 1-5.
  30. Rauret, G. (1998), "Extraction procedure for the determination of heavy metals in contaminated soil and sediment", Talanta, 46(3), 449-455. https://doi.org/10.1016/S0039-9140(97)00406-2
  31. Ross, S.M. (1994), "Sources and forms of potentially toxic metal in soil-plant system", Toxic Metals in Soil- Plant Systems, (S.M. Ross Eds.), John Wiley & Sons, New York, NY, USA, pp. 3-25.
  32. Rowbotham, A.L., Levy, L.S. and Shuker, L.K. (2000), "Chromium in the environment: An evaluation of exposure of the UK general population and possible adverse health effects", J. Toxicol. Environ. Health B, 3(3), 145-178. https://doi.org/10.1080/10937400050045255
  33. Ruiz-Cortes, E., Reinoso, R., Diaz-barrientos, E. and Madrid, L. (2005), "Concentrations of potentially toxic metals in urban soils of Seville: Relationship with different land uses", Environ. Geochem. Health, 27(5-6), 465-474. https://doi.org/10.1007/s10653-005-4222-1
  34. Saeedi, M., Hosseinzadeh, M., Jamshidi, A. and Pajooheshfar, S.P. (2009), "Assessment of heavy metals contamination and leaching characteristics in highway side soils, Iran", Environ. Monit. Assess., 151(1-4), 231-241. https://doi.org/10.1007/s10661-008-0264-z
  35. Sahuquillo, A., Rigol, A. and Rauret, G. (2002), "Comparison of leaching tests for the study of trace metals remobilization in soils and sediments", J. Environ. Monit., 4(3), 1003-1009. https://doi.org/10.1039/b206284b
  36. Stephen, L., David, S., Claus, S. and Edward, T. (2004), "Deriving soil critical limits for Cu, Zn, Cd, and Pb: A method based on free ion concentrations", Environ. Sci. Tech., 38(13), 3623-3631. https://doi.org/10.1021/es030155h
  37. Stohs, S.J., Bagchi, D., Hassoun, E. and Bagchi, M. (2001), "Oxidative mechanisms in the toxicity of chromium and cadmium ions", J. Environ. Pathol. Tox. Oncol., 20(2), 77-88.
  38. Sutherland, R.A. (2000), "Comparison between non-residual Al, Co, Cu, Fe, Mn, Ni, Pb and Zn released by a three-step sequential extraction procedure and a dilute hydrochloric acid leach for soil and road deposited sediment", Appl. Geochem., 17(4), 353-365.
  39. Temminghoff, E.J.M., Van der Zee, S.E.A.T.M. and de Haan, F.A.M. (1997), "Copper mobility in a copper-contaminated sandy soil as affected by pH and solid and dissolved organic matter", Environ. Sci. Tech., 31(4), 1109-1115. https://doi.org/10.1021/es9606236
  40. Thornton, I. (1991), "Metal contamination of soils in urban areas", Soils in the Urban Environment, (P. Bullock and P.J. Gregory Eds.), Blackwell Scientific Publications, Oxford, UK, pp. 47-75.
  41. Tiller, K.G. (1992), "Urban soil contamination in Australia", Australian J. Soil Res., 30(6), 937-957. https://doi.org/10.1071/SR9920937
  42. Tipping, E., Rieuwerts, J., Pan, G., Ashmore, M.R., Lofts, S., Hill, M.T.R., Farago, M.E. and Thornton, I. (2003), "The solid-solution partitioning of heavy metals (Cu, Zn, Cd, Pb) in upland soils of England and Wales", Environ. Pollut., 125(2), 213-225. https://doi.org/10.1016/S0269-7491(03)00058-7
  43. Townsend, T.G. and Brantley, A. (1998), "Leaching characteristics of asphalt road waste", Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL, USA.
  44. Udovic, M. and Lestan, D. (2007), "EDTA leaching of Cu contaminated soils using Ozone/UV for treatment and reuse of washing solution in a closed loop", Water Air Soil Pollut., 181(1-4), 319-327. https://doi.org/10.1007/s11270-006-9304-x
  45. Vijay, R. and Sihorwala, T.A. (2003), "Identification and leaching characteristics of sludge generated from metal pickling and electroplating industries by toxicity characteristics leaching procedure (TCLP)", Environ. Monit. Assess., 84(3), 193-202. https://doi.org/10.1023/A:1023363423345
  46. Voegelin, A., Barmettler, K. and Kretzschmar, R. (2003), "Heavy metal release from contaminated soils: Comparison of column leaching and batch extraction results", J. Environ. Quality, 32(3), 865-875. https://doi.org/10.2134/jeq2003.8650
  47. Wang, X.S. and Yong, Q. (2007), "Leaching characteristics of heavy metals and as from two urban roadside soils", Environ. Monit. Assess., 132(1-3), 83-92. https://doi.org/10.1007/s10661-006-9504-2
  48. Wang, X.S., Qin, Y. and Sun, S.X. (2005), "Accumulation and sources of heavy metals in urban top soils: A case study from the city of Xuzhou, China", Environ. Geol., 48(1), 101-107. https://doi.org/10.1007/s00254-005-1270-x

Cited by

  1. Impact of urbanization and industrialization on irrigation water quality of a canal - a case study of Tongi canal, Bangladesh vol.5, pp.2, 2016, https://doi.org/10.12989/aer.2016.5.2.109