DOI QR코드

DOI QR Code

Preparation of Inorganic/Organic Reverse Osmosis Composite Membrane and Its Performance for Desalination of Deep Ocean Water

유·무기계 역삼투 복합막의 제조와 해양심층수의 기능화 특성분석

  • 임경빈 ((주)선진인더스트리 기업부설연구소) ;
  • 홍영기 (건양대학교 패션디자인산업학과)
  • Received : 2013.08.02
  • Accepted : 2013.10.05
  • Published : 2013.10.31

Abstract

In this study, a microfilter medium was prepared using a melt-blown system and used as a pre-filter in a reverse osmosis (RO) separation system. Asymmetric RO composite membranes, which are inorganic/organic-reverse osmosis (IPO-RO) membranes composed of polysulfone and polyamide with tourmaline nanoparticles, have been designed to develop a new desalination membrane showing high selectivity and permeability. The practical separation performance of IPO-RO composite membranes was investigated for the desalination of seawater, especially for deep ocean water. The separation characteristics of IPO-RO composite membranes were discussed by changing some parameters such as applied pressure and temperature. The permeation flux of the IPO-RO composite membranes was investigated using a module composed of RO plate-frame and spiral wound units. The solute rejection and flux for the IPO-RO composite membrane were 99.0-99.4% and 7.4-23.3 $L/m^2{\cdot}h$ in deep ocean water at $20^{\circ}C$, respectively. Further, the separation performance of the IPO-RO composite membrane for deep ocean water was very steady-state for a long time. Remarkably, the solution permeated through the IPO-RO composite membrane matched drinking water standards.

Keywords

References

  1. L. D. Tijing, M. T. G. Ruelo, A. Amarjargal, H. R. Pant, C. H. Park, D. W. Kim, and C. S. Kim, “Antibacterial and Superhydrophilic Electrospun Polyurethane Nano Composite Fibers Containing Tourmaline Nanoparticles”, Chem Eng J, 2012, 197, 41-48. https://doi.org/10.1016/j.cej.2012.05.005
  2. K. D. Hawkins, I. D. R. Mackinnon, and H. Schneeberger, “Influence of Chemistry on the Pyroelectric Effect in Tourmaline”, American Mineralogist, 1995, 80, 491-501. https://doi.org/10.2138/am-1995-5-610
  3. D. H. Kate, D. R. Ian, and S. Helmut, “Influence of Chemistry on the Pyroelectric Effect in Tourmaline”, American Mineralogist, 1995, 80, 491-501. https://doi.org/10.2138/am-1995-5-610
  4. Y. S. Yoon, D. H. Kim, X. F. Qi, S. B. Song, J. H. Jung, K. B. Joo, Y. C. Teng, and K. J. Lee, "The Efficacy Evaluation of Tourmaline-Ionized Water in Animal Study", Korean J Microscopy, 2009, 39(4), 311-317.
  5. A. E. Mohamed, Z. Zhao, and Y. Liqiang, “A Review of Renewable Energy Technologies Integrated with Desalination Systems”, Renewable and Sustainable Energy Reviews, 2009, 13, 2245-2262. https://doi.org/10.1016/j.rser.2009.06.011
  6. E. D. Hisham, A. Imad, and E. Hisham, “Process Synthesis: The Multi-stage Flash Desalination System”, Desalination, 1998, 115, 155-179. https://doi.org/10.1016/S0011-9164(98)00035-6
  7. I. E. Salibya, Y. Okoura, H. K. Shona, J. Kandasamya, and I. S. Kim, "Desalination Plants in Australia, Review and Facts", Desalination, 2009, 247, 1-14. https://doi.org/10.1016/j.desal.2008.12.007
  8. R. W. Baker, "Membrane Technology and Applications", Third Edition, John Wiley & Sons, UK, 2012, pp.207-251.
  9. W. S. Winston and K. Sirkar, "Membrane Handbook", Van, Nostrand Reinhold, NY, 1992, pp.393-398.
  10. J. Altmann and S. Ripperger, “Particle Deposition and Layer Formation at the Crossflow Microfiltration”, J Membr Sci, 1997, 124, 119-128. https://doi.org/10.1016/S0376-7388(96)00235-9
  11. P. Hsieh and Y. Li, “A Cluster Perspective of the Development of the Deep Ocean Water Industry”, Ocean & Coastal Management, 2009, 152, 287-293.
  12. C. W. Armstrong, N. S. Foley, R. Tinch, and S. V. D. Hove, “Services from the Deep: Steps Towards Valuation of Deep Sea Goods and Services”, Ecosystem Services, 2012, 2, 2-13. https://doi.org/10.1016/j.ecoser.2012.07.001
  13. D. S. Joo, "Changes in Quality of Salted and Dried Brown- Croaker Product Prepared with Deep Seawater Salt", J Korean Soc Food Sci Nutr, 2011, 40(2), 235-244. https://doi.org/10.3746/jkfn.2011.40.2.235
  14. Y. T. Lee and N. W. Kim, "Reverse Osmosis Membrane with High Salt Rejection for Seawater Desalination", J Korean Ind Eng Chem, 2004, 15(4), 466-472.
  15. B. H. Jeong, E. M. V. Hoek, Y. Yan, A. Subramani, X Huang, G. Hurwitz, A. K. Ghosh, and A. Jawor, “Interfacial Polymerization of Thin Film Nanocomposites: A New Concept for Reverse Osmosis Membranes”, J Membr Sci, 2007, 294, 1-7. https://doi.org/10.1016/j.memsci.2007.02.025
  16. S. Sourirajan and T. Matsuura, "Reverse Osmosis/Ultrafiltration Process Principles", National Research Council of Canada, Ottawa, Canada, 1985, pp.117-120.
  17. K. Y. Kim and Y. M. Lee, “Separation by Reverse Osmosis”, Polymer(Korea), 1978, 2(5), 228-241.
  18. H. K. Lonsdale, U. Merten, and M. Tagami, “Phenol Transport in Cellulose Acetate Membrane”, J Appl Polym Sci, 1967, 11, 1807-1820. https://doi.org/10.1002/app.1967.070110917
  19. L. F. Greenlee, D. F. Lawler, B. D. Freeman, B. Marrot, and P. Moulin, "Reverse Osmosis Desalination: Water Sources, Technology, and Today's Challenges", Water Res, 2009, 43, 2317-2348. https://doi.org/10.1016/j.watres.2009.03.010
  20. K. Jiang, T. H. Sun, L. N. Sun, and H. B. Li, "Adsorption Characteristics of Copper, Lead, Zinc and Cadmium Ions by Tourmaline", J Environ Sci, 2006, 18(6), 1221-1225. https://doi.org/10.1016/S1001-0742(06)60066-1
  21. Y. K. Hong, K. H. Song, D. S. Moon, and H. J. Kim, “Desalination Performance of Deep Ocean Water Using New Mode Reverse Osmosis Composite Membrane”, Text Sci Eng, 2006, 43(6), 291-297.
  22. E. H. Kim, H. G. Kim, and J. H. Kim, “Preparation and Properties of Chitosan/Poly(vinyl alcohol) Nanofibers Containing Silver Zeolite”, Text Sci Eng, 2013, 50(2), 132-138. https://doi.org/10.12772/TSE.2013.50.132