DOI QR코드

DOI QR Code

A new method for in line electrokinetic characterization of cakes

  • 투고 : 2012.06.12
  • 심사 : 2013.04.13
  • 발행 : 2013.07.25

초록

The present study is devoted to the validation of a new method for in line electrokinetic characterisation of deposits on membrane surfaces. This method is based upon simultaneous measurements of transversal streaming potential and permeates flux at constant pressure before and during the deposit formation. Dead-end filtration experiments were conducted with negative flat membranes forming a narrow slit channel, negative hollow fiber membranes and mono-dispersed suspensions of (negatively charged) polystyrene latex and (positively charged) melamine particles at various concentrations. It was observed that the overall streaming potential coefficient increased in absolute value with the deposited latex quantity, whereas it decreased and changed of sign during the filtration of melamine suspensions. By considering a resistance-in-series model, the streaming potential coefficient of the single deposit ($SP_d$) was deduced from the electrokinetic and hydraulic measurements. The independence of $SP_d$ with respect to growth kinetics validates the measurement method and the reliability of the proposed procedure for calculating $SP_d$. It was found that $SP_d$ levelled off much more quickly when filtration was performed through the slit channel. This different behaviour could result from a non-uniform distribution of the deposit thickness along the membrane given that the position of measuring electrodes is different between the two cells.

키워드

참고문헌

  1. Chun, M.S. and Park, W.C. (2004), "Time evolution of electrokinetic flow-induced streaming potential and flux in dead-end and cross-flow filtration of colloids through nanopores", J. Membr. Sci., 243(1-2), 417-424. https://doi.org/10.1016/j.memsci.2004.07.009
  2. Chun, M.S., Cho, H.I. and Song, I.K. (2002), "Electrokinetic behavior of membrane zeta potential during the filtration of colloidal suspensions", Desalination, 148(1-3), 363-368. https://doi.org/10.1016/S0011-9164(02)00731-2
  3. Chloe, T.B., Masse, P., Verdier, A. and Clifton, M.J. (1986), "Flux decline in batch ultrafiltration: Concentration, polarization and cake formation", J. Membr. Sci., 26(1), 1-15. https://doi.org/10.1016/S0376-7388(00)80109-X
  4. Gourgues, C., Aimar, P. and Sanchez, V. (1992), "Ultrafiltration of bentonite suspensions with hollow fiber membranes", J. Membr. Sci., 74(1-2), 51-69. https://doi.org/10.1016/0376-7388(92)87072-6
  5. Hamachi, M. and Mietton-Peuchot, M. (1999), "Experimental investigation of cake characteristics in crossflow microfiltration", Chem. Eng. Sci., 54(18), 4023-4030. https://doi.org/10.1016/S0009-2509(99)00101-3
  6. Hunter, R.J. (1981), Zeta potential in Colloid Science, Principles and Applications, Academic Press, San Diego, CA, USA.
  7. Hwang, K.J., Wu, Y.S. and Lu, W.M. (1996), "The surface structure of cake formed by uniform sized rigid spheroids in cake filtration", Powder Tech., 87(2), 161-168. https://doi.org/10.1016/0032-5910(95)03084-0
  8. Jons, S., Ries, P. and McDonald, C.J. (1999), "Porous latex composite membranes: Fabrication and properties", J. Membr. Sci., 155(1), 79-99. https://doi.org/10.1016/S0376-7388(98)00304-4
  9. Karode, S.K. (2001), "Unsteady state flux response: A method to determine the nature of the solute and gel layer in membrane filtration", J. Membr. Sci., 188(1), 9-20. https://doi.org/10.1016/S0376-7388(00)00644-X
  10. Le Bolay, N. and Ricard, A. (1995), "Streaming potential in membrane processes: microfiltration of egg proteins", J. Colloid Interface Sci., 170(1), 154-160. https://doi.org/10.1006/jcis.1995.1083
  11. Mendret, J., Guigui, C., Cabassud, C. and Schmitz, P. (2010), "Numerical investigations of the effect of non-uniform membrane permeability on deposit formation and filtration process", Desalination, 263(1-3), 122-132. https://doi.org/10.1016/j.desal.2010.06.048
  12. Mendret, J., Guigui, C., Schmitz, P. and Cabassud, C. (2009), "In situ dynamic characterisation of fouling under different pressure conditions during dead-end filtration: Compressibility properties of particle cakes", J. Membr. Sci., 333(1-2), 20-29. https://doi.org/10.1016/j.memsci.2009.01.035
  13. Murase, T., Ohn, T. and Kimata, K. (1995), "Filtration flux in cross flow microfiltration of dilute suspension forming a highly compressible fouling cake-layer", J. Membr. Sci., 108(1-2), 121-128. https://doi.org/10.1016/0376-7388(95)00154-2
  14. Nystrom, M., Kaipia, L. and Luque, S. (1995), "Fouling and retention of nanofiltration membranes", J. Membr. Sci., 98(3), 249-262. https://doi.org/10.1016/0376-7388(94)00196-6
  15. Nystrom, M., Pihlajamaki, A. and Ehsani, N. (1994), "Characterization of ultrafiltration membranes by simultaneous streaming potential and flux measurements", J. Membr. Sci., 87(3), 245-256. https://doi.org/10.1016/0376-7388(94)87031-4
  16. Park, P.K., Lee, C.H. and Lee, S. (2007), "Determination of cake porosity using image analysis in a coagulation-microfiltration system", J. Membr. Sci., 293(1-2), 66-72. https://doi.org/10.1016/j.memsci.2007.01.035
  17. Sung, J.H., Chun, M.S. and Choi, H.J. (2003), "On the behavior of electrokinetic streaming potential during protein filtration with fully and partially retentive nanopores", J. Colloid Interf. Sci., 264(1), 195-202. https://doi.org/10.1016/S0021-9797(03)00352-7
  18. Szymczyk, A., Fievet, P., Reggiani, J.C. and Pagetti, J. (1998), "Determination of the filtering layer electrokinetic properties of a multi-layer ceramic membrane", Desalination, 116(1), 81-88. https://doi.org/10.1016/S0011-9164(98)00059-9
  19. Szymczyk, A., Fievet, P. and Foissy, A. (2002), "Electrokinetic characterization of porous plugs from streaming potential coupled with electrical resistance measurements", J. Colloid Interf. Sci., 255(2), 323-331. https://doi.org/10.1006/jcis.2002.8591
  20. Teychene, B., Loulergue, P., Guigui, C. and Cabassud, C. (2011), "Development and use of a novel method for in line characterisation of fouling layers electrokinetic properties and for fouling monitoring", J. Membr. Sci., 370(1-2), 45-47. https://doi.org/10.1016/j.memsci.2010.12.014