한국염색가공학회지 (Textile Coloration and Finishing)

  • 제25권3호
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  • Pages.159-164
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  • 2013
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  • 1229-0033(pISSN)
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  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
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Electrochemical Study on Energy Potential Levels with Pyrene Molecule

  • Kim, Hyungjoo (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Li, Xiaochuan (College of Chemistry and Chemical Engineering, Henan Normal University) ;
  • Son, Young-A (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
  • 투고 : 2013.08.16
  • 심사 : 2013.09.23
  • 발행 : 2013.09.27
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초록

Pyrene based molecule has been synthesized through the reaction of pyrene-1-carboxaldehyde and 4- phenylthiosemicarbazide in this research. The pyrene based molecule showed specific optical properties such as absorption and emission changes after mixing with fluoride in DMSO. The phenomenon is induced by the interaction of the molecule and fluoride. This interaction may affect to electron distributions and potential energy levels. In this regard, synthesized pyrene based molecule has been investigated for its electron distributions and HOMO/LUMO energy levels depending on interaction with fluoride. The absorption measurement, cyclicvoltammograms and computational method were investigated to calculate and compare energy potential levels.

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참고문헌

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