한국안전학회지 (Journal of the Korean Society of Safety)

  • 제28권2호
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  • Pages.37-41
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  • 2013
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  • 1738-3803(pISSN)
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  • 2383-9953(eISSN)
한국안전학회 (The Korean Society of Safety)
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Copper phthalocyanine과 Dilithium phthalocyanine 화합물 박막의 휘발성 유기화합물(VOCs) 센서 특성

Volatile Organic Compounds(VOCs) Sensing Properties of Thin Films Based on Copper phthalocyanine and Dilithium phthalocyanine Compounds

  • 김동현 (단국대학교 직업환경의학과) ;
  • 강영구 (호서대학교 안전보건학과) ;
  • 강영진 (호서대학교 대학원 안전공학과)
  • Kim, Dong Hyun (Department of Occupational and Environmental Mediecine, Dankook University) ;
  • Kang, Young Goo (Department of Safety & Health Engineering, Hoseo University) ;
  • Kang, Young Jin (Department of Safety Engineering, Graduate School, Hoseo University)
  • 투고 : 2012.10.17
  • 심사 : 2013.04.10
  • 발행 : 2013.04.30
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초록

In this work, we report the effect on the volatole organic compounds(VOCs) sensing properties of Copper phthalocyanine(CoPc) and Dilithium phthalocyanine(DiLiPc) thin films onto alumina substrates. Use evaporation method and the spin-coated method for sensing device. The materials of metallophthalocyanine macrocyclic compound solutions blended with N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4"-diamine and/or Poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] solutions. The influence of the blended in with metallophthalocyanine macrocyclic compounds on the resistance have been measured and analyzed in five different volatole organic compounds. The following results were obtained: The AFM 3D image of thin films deposited on metallophthalocyanine macrocyclic compound shows that the surfaces roughness were about CuPc 4.1~14.3 nm(7.5~8.1%), DiLiPc 10.3~22.2 nm(7.9~11.5%). The resistances decreases upon increasing the concentration of vapor organic compounds to CuPc and DiLiPc thin films. That thin films blended Copper phthalocyanine(CoPc) and Dilithium phthalocyanine(DiLiPc) with N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4"-diamine and/or Poly[2-methoxy--5-(2'-ethylhexyloxy)-1,4-phenylenevinylene]. The resistances of blended thin films with N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4"-diamine and/or Poly[2-methoxy--5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] decreases upon increasing the concentration of volatole organic compounds(VOCs) on DiLiPc than CuPc compound thin films.

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참고문헌

  1. J. P. Cheong and S. J. You, "Characteristics and Identification of Ambient VOCs Sources in Busan Industrial Area", Journal of Korean Society of Environmental Engineers, Vol. 33, No. 9, pp. 644-655, 2011. https://doi.org/10.4491/KSEE.2011.33.9.644
  2. H. J. Byun, K. N. Ryu, C. S. Yoon and J. I. Park, "Quantitative Assessment Strategy for Determining the Exposures to Volatile Organic Chemicals in Chemistry Laboratories", Journal of Korean Society of Occupational and Environmental Hygiene, Vol. 21, No. 1, pp. 11-24, 2011.
  3. H. D. Jo, J. H. Roh, C. N. Kim, S. H. Sim and J. U. Won, "A Study on the Air Quality of Indoor Screen Golf in Seoul", Journal of Korean Society of Occupational and Environmental Hygiene, Vol. 20, No. 3, pp. 192-202, 2010.
  4. Linda Rosenstock, Mark R Cullen, Carl Andrew Brodkin and Carrie A Redlich, "Textbook of Clinical Occupational and Environmental Medicine", Second Edition, pp. 991-1008, 2005.
  5. H. Y. Kim, S. B. Lee, J. H. Han, T. G. Kim, J. S. Lee and M. G. Kang, C. K. Lee, "A Study on thinner's Physicochemical Property and its Effect on Genital Organ of Rat", Journal of Korean Society of Occupational and Environmental Hygiene, Vol. 18, No. 3, pp. 224-238, 2008.
  6. Y. M. Kim and H. W. Kim, "The Assessment of Health Risk and Subjective Symptoms of Printing Workers Exposed to Mixed Organic Solvents", Journal of Korean Society of Occupational and Environmental Hygiene, Vol. 19, No. 3, pp. 270-279, 2009.
  7. J. S. Byun and J. Y. Kim, Y. C. Cho, D. H. Kim, "A Study on the Mixed Organic Solvent Dose and Subjective Symptoms of Direct and Indirect Bonding workers in Shoes Manufacturing Industrial", Journal of Korean Society of Occupational and Environmental Hygiene, Vol. 5, No. 1, pp. 48-58, 1995.
  8. Y. G. Kang, H. Kim and L.R. Subramanian, "Michael Hanack Synthesis and Properties of Aromatic Amine-bridgedphthalocyaninato Ruthenium(II) Coordination Compounds", Synthetic Metals, Vol. 78, pp. 11-18, 1996. https://doi.org/10.1016/0379-6779(95)03494-3
  9. M. I. Newton, T. K. H. Starke, M. R. Willis and G. McHale "$NO_{2}$ Detection at Room Temperature with Copper Phthalocyanine Thin Film Devices", Sensors and Actuators B: Chemical, Vol. 67, pp. 307-311, 2000. https://doi.org/10.1016/S0925-4005(00)00542-6
  10. G. G. Fedoruk, D. I. Sagaidak, A. V. Misevich and A. E. Pochtenny, "Electrical and Gas Sensing Properties of Copper Phthalocyanine- polymer Composites", Sensors and Actuators B: Chemical, Vol. 48, pp. 351-355, 1998. https://doi.org/10.1016/S0925-4005(98)00070-7
  11. R. Rella, A. Serra, A. Siciliano, A. Tepore, L. Valli and A. Zocco, "Applications in Gas-Sensing Devices of a New Macrocyclic Copper Complex", Sensors and Actuators B: Chemical, Vol. 42, pp. 53-58, 1997. https://doi.org/10.1016/S0925-4005(97)80312-7
  12. C. Park, D. H. Yun, S. T. Kim and Y. W. Park, "Enhancement of the $NO_{2}$-Sensing Capability of Copper Phthalocyanine by Measuring the Relative Resistance Change", Sensors and Actuators B: Chemical, Vol. 30, pp . 23-27, 1996. https://doi.org/10.1016/0925-4005(95)01727-D
  13. Q. Zhou and R. D. Gould, "A Study of the Response Rate to Nitrogen Dioxide Exposure in Metal Phthalocyanine thin Film Sensors", Thin Solid Films, Vol. 317, No. 1, pp. 432-435, 1998. https://doi.org/10.1016/S0040-6090(97)00577-4
  14. A. K. Hassan, A. V. Nabok, A. K. Ray, A. Lucke, K. Smith, C. J. M. Stirling and F. Davis, "Thin Films of Calix-4-Resorcinarene Deposited by Spin Coating and Langmuir-Blodgett Techniques: Determination of Film Parameters by Surface Plasmon Resonance", Materials Science and Engineering: C, Vol. 8, pp. 251-255, 1999.
  15. B. Leyer, H. Knozinger, H. Schmelz, H. Göbel, H. Meixner and T. Scherg, "Preparation of AlVO4-Films for Sensor Application via a sol-gel/spin-coating Technique", Thin Solid Films, Vol. 310, pp. 228-233, 1997. https://doi.org/10.1016/S0040-6090(97)00412-4
  16. B. W. Koo, C. K. Song and C. K. Kim, "CO Gas Sensor Based on a Conducting Dendrimer", Sensors and Actuators B: Chemical, Vol. 77, pp. 432-436, 2001. https://doi.org/10.1016/S0925-4005(01)00750-X
  17. V. Uwira, A. Schütze and D. Kohl "Detection of Low Hydrogen Concentrations by a Cu-Pc Sensor", Sensors and Actuators B: Chemical, Vol. 26, pp. 153-157, 1995. https://doi.org/10.1016/0925-4005(94)01577-5
  18. E. van Faassen and H. Kerp, "Explanation of the Low Oxygen Sensitivity of Thin Film Phthalocyanine Gas Sensors", Sensors and Actuators B: Chemical, Vol. 88, No. 3, pp. 329-333, 2003. https://doi.org/10.1016/S0925-4005(02)00379-9
  19. I Zhivkov, E Spassova, G Danev, Tz Ivanov and S Andreev "Vacuum Deposited Copper Phthalocyanine thin Films-Structure and Surface Morphologyfn2", Vacuum, Vol. 51, No. 2, pp. 189-192, 1998. https://doi.org/10.1016/S0042-207X(98)00157-2

피인용 문헌

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