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Degradation of 3-Chlorophenol by a Ultraviolet-Fenton Process: Parameters and Degradation Pathways

자외선 펜톤산화공정에 의한 수중 3-염화페놀 분해특성 및 분해경로 연구

  • Kim, Il-Kyu (Department of Environmental Engineering, Pukyong National University)
  • Received : 2012.11.21
  • Accepted : 2013.05.10
  • Published : 2013.09.30

Abstract

The degradation of 3-chlorophenol(3-CP) by various AOPs(Advanced Oxidation Processes) including the ultraviolet / hydrogen peroxide, the Fenton and the ultraviolet(UV)-Fenton process has been conducted. The highest removal efficiency for 3-CP in the aqueous phase was obtained by the UV-Fenton process among the AOPs. In the UV-Fenton process, The removal efficiency of 3-CP decreased with increasing pH in the range of 3 to 6, and it decreased with increasing initial concentration. As the intermediates of 3-CP by UV-Fenton reaction, 3-chlorocatechol, 4-chlorocatechol, and chlorohydroquinone were detected thus the degradation pathways were proposed.

Keywords

References

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