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Desorption and Regeneration Characteristics for Nickel Ions Loaded onto Sericite Using HNO3 Solution

  • Jeon, Choong (Department of Biochemical Engineering, Gangneung-Wonju National University)
  • Received : 2013.06.03
  • Accepted : 2013.07.08
  • Published : 2013.09.30

Abstract

Desorption characteristics for ions adsorbed onto sericite was performed by means of $HNO_3$ solution which was selected as the best desorbing agent in the previous work. Elution of nickel ions adsorbed onto sericite using $HNO_3$ solution was confirmed by means of scanning electron microscopy (SEM) & energy dispersive X-ray spectroscopy (EDX) analysis. Desorption efficiency for nickel ions was 100% at the 20 mM of concentration. Also, nickel ions was completely desorbed within 1.0 of S/L (mg/mL) ratio which is defined as the ratio of adding amount of adsorbent and volume of desorbing agent and desorption process was quickly carried out within 60min. Finally, removal efficiency of reused sericite for nickel ions was constantly maintained until the 4th cycle.

견운모에 흡착된 니켈이온의 탈착과 재생특성에 관한 연구가 최적의 탈착제로서 선정된 $HNO_3$를 이용하여 수행되어졌다. 견운모에 흡착된 니켈이온의 탈리는 주사전자현미경과 에너지 분산형 X선 분광기에 의해서 확인 되어졌다. 20 mM의 농도에서 니켈이온의 탈착율은 100%였다. 또한, 투입된 흡착제의 양과 탈착제의 부피로서 정의되는 S/L비가 1.0내에서는 니켈이온은 완전히 탈착 되어졌으며 탈착 공정은 60분내에 빨리 일어났다. 마지막으로 재사용된 견운모를 이용하였을 때 4회까지는 니켈이온의 탈착율이 일정하게 유지되었다.

Keywords

References

  1. Njikam, E., and Schiewer, S., "Optimization and Kinetic Modeling of Cadmium Desorption from Citrus Peels: A Process for Biosorbent Regeneration," J. Hazard. Mater., 213-214(1), 242-248 (2012). https://doi.org/10.1016/j.jhazmat.2012.01.084
  2. Aldor, I., Fourest, E., and Volesky, B., "Desorption of Cadmium from Algal Biosorbent," Can. J. Chem. Eng., 73(4), 516-522 (1995). https://doi.org/10.1002/cjce.5450730412
  3. Bux, F., Naridoo, D., and Kasan, H. C., "Laboratory-scale Biosorption and Desorption of Metal Ions Using Waste Sludges and Selected Acids," S. Afr. J. Sci., 92(11-12), 527-529 (1996).
  4. Beolchini, F., Pagnanelli, F., Toro, L., and Veglio, F., "Biosorption of Copper by Sphaerotilus Natans Immobilized in Polysulfone Matrix: Equilibrium and Kinetic Analysis," Hydrometallurgy., 70(1-3), 101-112 (2003). https://doi.org/10.1016/S0304-386X(03)00049-5
  5. Sekhar, K. C., Kamala, C. T., Chary, N. S., Sastry, A. R. K., Rao, T. N., and Vairamani, M., "Removal of Lead from Aqueous Solutions Using an Immobilized Biomaterial Derived from a Plant Biomass," J. Hazard. Mater., 108(1-2), 111-117 (2004). https://doi.org/10.1016/j.jhazmat.2004.01.013
  6. Mata, Y. N., Blazquez, M. L., Ballester, A., Gonzalez, F., and Munoz, J. A., "Studies on Sorption, Desorption, Regeneration and Reuse of Sugar-Beet Pectin Gels for Heavy Metal Removal," J. Hazard. Mater., 178(1-3), 243-248 (2010). https://doi.org/10.1016/j.jhazmat.2010.01.069
  7. Jeon, C., and Kwon, T. N., "Adsorption Characteristics of Sericite for Nickel Ions from Industrial Waste Water," J. Ind. Eng. Sci., 19(1), 68-72 (2012).
  8. Suresh, G., and Babu, B. V., "Removal of Toxic Metal Cr(VI) from Aqueous Solutions Using Sawdust as Adsorbent: Equilibrium, Kinetics and Regeneration Studies," Chem. Eng. J., 150(2-3), 352-365 (2009). https://doi.org/10.1016/j.cej.2009.01.013
  9. Mustafa, G., Singh, B., and Kookana, R. S., "Cadmium Adsorption and Desorpion Behavior on Goethite at Low Equilibrium Concentration," Chemosphere., 57(10), 1325-1333 (2004). https://doi.org/10.1016/j.chemosphere.2004.08.087
  10. Jeon, C., and Park, K. H., "Adsorption and Desorption Characteristics of Mercury(II) Ions Using Aminated Chitosan Bead," Water Res., 39(16), 3938-3944 (2005). https://doi.org/10.1016/j.watres.2005.07.020
  11. Volesky, B., "Biosorption of Heavy Metals: Environmental Impact of Heavy Metals," CRC Press, Inc., Boca Raton, FL (1990).
  12. Jeon, C., and Kwon, T. N., "Desorption and Regeneration Characteristics for Previously Adsorbed Indium Ions to Phosphorylated Sawdust," Environ. Eng. Res., 17(2), 65-67 (2012). https://doi.org/10.4491/eer.2012.17.2.065

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