Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Efficient Ring Opening Reaction of Epoxides with Oxygen Nucleophiles Catalyzed by Quaternary Onium Salt

  • Kim, Jin Won (Department of Chemistry, Yeungnam University) ;
  • Cho, Dae Won (Department of Chemistry, Yeungnam University) ;
  • Park, Gyoosoon (Department of Chemistry, Kookmin University) ;
  • Kim, Sung Hong (Analysis Research Division, Daegu Center, Korea Basic Science Institute) ;
  • Ra, Choon Sup (Department of Chemistry, Yeungnam University)
  • Received : 2013.04.05
  • Accepted : 2013.05.05
  • Published : 2013.08.20
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Abstract

Ring opening reactions of epoxides with oxygen nucleophiles catalyzed by a variety of quaternary onium salt, such as ammonium or phosphonium salt were explored. The results showed that tetrabutylphosphonium bromide (TBPB) among salts serves as the most efficient catalyst for this process and that expoxide ring opening reactions with a variety of oxygen nucleophiles including carboxyic acid and phenol, promoted using this salt, lead to generate readily purifiable products in excellent yields.

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References

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