Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Different Dimensional and Structural Variations in Coordination Compounds of Cadmium, Manganese and Nickel Constructed from the Ligand 2,2'-Bipyidine-3,3',6,6'-tetracarboxylic Acid (H4bptc)

  • Xiang, Jing (College of Chemistry and Environmental Engineering, Yangtze University) ;
  • Yang, Tian-Tian (College of Chemistry and Environmental Engineering, Yangtze University) ;
  • Fu, Lu-Lu (College of Chemistry and Environmental Engineering, Yangtze University) ;
  • Luo, Ya (College of Chemistry and Environmental Engineering, Yangtze University) ;
  • Wu, Jia-Shou (School of Pharmaceutical and Chemical Engineering, TaiZhou University)
  • Received : 2013.04.15
  • Accepted : 2013.06.05
  • Published : 2013.09.20
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Abstract

The reactions of hydrated $CdCl_2$, $MnCl_2$, and $NiCl_2$ with 2,2'-bipyidine-3,3',6,6'-tetracarboxylic acid ($H_4bptc$) afforded the mononuclear [$Cd^{II}(H_2bptc)(H_2O)_3]{\cdot}H_2O$ (1), linear $\{[Cd(H_2bptc)(H_2O)]{\cdot}3H_2O\}_n$ (2), 3-D heterobimetallic $[NaCd(Hbptc)(H_2O)]$ (3), layer $[Mn(H_2bptc)(H_2O)]_n$ (4) and a dinuclear compound $[Ni_2(H_2bptc)-(H_2O)_2]{\cdot}6H_2O$ (5). These compounds have been characterized by elemental analysis, IR, and their structures have been determined by X-ray crystallography. The thermal stabilities of 1-3 were measured by thermogravimetric analysis (TGA) and their solid state luminescence properties together with the free ligand $H_4bptc$ were investigated at room temperature.

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