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Surface Modification of Poly(p-phenylene benzobisoxazole) Fibers by UV-Absorbers for Enhancement of UV Resistance

Poly(p-phenylene benzobisoxazole) 고성능 섬유의 자외선 저항성 향상을 위한 표면처리 기술 연구

  • Park, Seong Woo (Korean Textile Development Institute) ;
  • Kang, Yoon Hwa (Korean Textile Development Institute) ;
  • Jeon, Gil Woo (Korean Textile Development Institute) ;
  • Min, Byung Gil (Department of Materials Design Engineering, Kumoh National Institute of Technology) ;
  • Baik, Doo Hyun (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
  • 박성우 (한국섬유개발연구원) ;
  • 강윤화 (한국섬유개발연구원) ;
  • 전길우 (한국섬유개발연구원) ;
  • 민병길 (금오공과대학교 소재디자인공학과) ;
  • 백두현 (충남대학교 유기소재섬유시스템공학과)
  • Received : 2013.04.30
  • Accepted : 2013.06.10
  • Published : 2013.06.30

Abstract

A UV testing chamber was designed and prepared for testing the UV-resistance of poly(p-phenylene benzobisoxazole) (PBO) fibers. The optimum conditions for the test were established by measuring UV irradiation at a chamber position using various kinds of UV sources and different irradiation times. Expectedly, PBO fibers (Zylon$^{(R)}$) showed significant degradation under UV irradiation by exhibiting a decrease in the tensile strength and elongation of up to 37% and 18%, respectively. Selected UV-absorbing and -stabilizing agents were successfully coated onto the fibers using water-borne polyurethane. It was found that triazine-type UV absorbing agents were more effective than benzophenone- or benzotriazole-type agents in reducing the degradation of PBO fibers under UV irradiation.

Keywords

References

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Cited by

  1. Enhancement in compressive strength and UV ageing-resistance of poly(p-phenylene benzobisoxazole) nanocomposite fiber containing modified polyhedral oligomeric silsesquioxane vol.18, pp.3, 2017, https://doi.org/10.1007/s12221-017-1080-2
  2. Surface Modification of Poly(p-phenylene benzobisoxazole) Fiber Using UV-absorbing Agents for Improving the UV Resistance. II. Process Optimization and Performance Assessment vol.52, pp.6, 2015, https://doi.org/10.12772/TSE.2015.52.416