Studies on the Applications of PSL, TL and ESR Methods for the Detection of Dried Fruits and Mushrooms

PSL, TL 및 ESR 분석에 의한 건조과일류 및 버섯류에 대한 검지 특성 연구

  • Kim, Kyu-Heon (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety) ;
  • Son, Jin-Hyok (Hazardous Substances Analysis Division, Seoul Regional Food and Drug Administration) ;
  • Kang, Yoon-Jung (Hazardous Substances Analysis Team, Busan Regional Food and Drug Administration) ;
  • Park, Hye-Young (Imported Food Analysis Team, Gyeongin Regional Food and Drug Administration) ;
  • Hwang, Cho-Rong (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety) ;
  • Kim, Jae-I (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety) ;
  • Lee, Kang-Bong (Hazardous Substances Analysis Division, Seoul Regional Food and Drug Administration) ;
  • Jo, Tae-Yong (Hazardous Substances Analysis Team, Busan Regional Food and Drug Administration) ;
  • Eom, Mi-Ok (Imported Food Analysis Team, Gyeongin Regional Food and Drug Administration) ;
  • Park, Sue-Nie (Hazardous Substances Analysis Division, Seoul Regional Food and Drug Administration) ;
  • Seong, Rack Seon (Hazardous Substances Analysis Team, Busan Regional Food and Drug Administration) ;
  • Jang, Young-Mi (Imported Food Analysis Team, Gyeongin Regional Food and Drug Administration) ;
  • Lee, Jae-Hwang (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety) ;
  • Park, Yong-Chjun (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety) ;
  • Lee, Hwa-Jung (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety) ;
  • Lee, Sang-Jae (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety) ;
  • Han, Sang-Bae (New Hazardous Substances Team, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety)
  • 김규헌 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀) ;
  • 손진혁 (서울지방식품의약품안전청 유해물질분석과) ;
  • 강윤정 (부산지방식품의약품안전청 유해물질분석팀) ;
  • 박혜영 (경인지방식품의약품안전청 수입식품분석팀) ;
  • 황초롱 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀) ;
  • 김재이 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀) ;
  • 이강봉 (서울지방식품의약품안전청 유해물질분석과) ;
  • 조태용 (부산지방식품의약품안전청 유해물질분석팀) ;
  • 엄미옥 (경인지방식품의약품안전청 수입식품분석팀) ;
  • 박순희 (서울지방식품의약품안전청 유해물질분석과) ;
  • 성락선 (부산지방식품의약품안전청 유해물질분석팀) ;
  • 장영미 (경인지방식품의약품안전청 수입식품분석팀) ;
  • 이재황 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀) ;
  • 박용춘 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀) ;
  • 이화정 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀) ;
  • 이상재 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀) ;
  • 한상배 (식품의약품안전처 식품의약품안전평가원 식품위해평가부 신종유해물질팀)
  • Received : 2013.02.15
  • Accepted : 2013.04.11
  • Published : 2013.03.31

Abstract

In this study, we investigated the applicability of the photostimulated luminescence (PSL), thermoluminescence (TL) and electron spin resonance (ESR) methods for various foods. The analysed samples consist of 11 items including dried fruits (6 items) and mushrooms (5 items). To compare between non-irradiated and irradiated food, all samples were irradiated with $^{60}Co$ gamma-ray source. In PSL study, the photon counts of all the unirradiated sample were identified negative (lower than 700). The photon counts irradiated (1, 5, 10 kGy) dried date-palm, dried jujube and mushrooms (Auricularia auricula, Phellinus linteus and Sarcodon aspratus) showed positive (higher than 5,000) and the results for the other samples were negative or intermediate (>700 and >5,000). In TL analysis most of items can be applicable to detect irradiated foods because of showing TL ratio above 0.1. The glow curves by TL method were estimated in the range of $150{\sim}250^{\circ}C$ in irradiated samples. In ESR measurements, the intensity of ESR signal (single-line) increased as the dose of irradiation increased. In particular, the specific ESR signals of irradiation-induced radical were detected in dried papaya, dried date-palm, dried banana, dried pineapple and S. aspratus. According to the results, PSL, TL and ESR methods were successfully applied to detect the irradiated foods. It is concluded that PSL, TL and ESR methods are suitable for detection of irradiated samples and a combined method is recommendable for enhancing the reliability of detection results.

Keywords

Acknowledgement

Supported by : 식품의약품안전평가원