Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of CuO/ZnO Nanoparticles and Their Application for Photocatalytic Degradation of Lidocaine HCl by the Trial-and-error and Taguchi Methods

  • Giahi, M. (Department of Chemistry, Lahijan Branch, Islamic Azad University) ;
  • Badalpoor, N. (Department of Chemistry, Shahreray Branch, Islamic Azad University) ;
  • Habibi, S. (Department of Chemistry, Shahreray Branch, Islamic Azad University) ;
  • Taghavi, H. (Department of Chemistry, Lahijan Branch, Islamic Azad University)
  • Received : 2013.01.11
  • Accepted : 2013.04.04
  • Published : 2013.07.20
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Abstract

A novel sol-gel method was implied to prepare CuO-doped ZnO nanoparticles. XRD and SEM techniques were used to characterize the CuO-doped ZnO sample. The photocatalytic degradation of Lidocaine HCl was investigated by two methods. The degradation was studied under different conditions such as the amount of photocatalyst, pH of the system, initial concentration, presence of electron acceptor, and presence of anions. The results showed that they strongly affected the photocatalytic degradation of Lidocaine HCl. The photodegradation efficiency of drug increased with the increase of the irradiation time. After 6 h irradiation with 400-W mercury lamp, about 93% removal of Lidocaine HCl was achieved. The degree of photodegradation obtained by Taguchi method compatible with the trial-and-error method showed reliable results.

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References

  1. Emad, S.; Chaudhuri, M. Journal of Hazardous Materials 2010, 173, 445. https://doi.org/10.1016/j.jhazmat.2009.08.104
  2. Giahi, M.; Habibi, S.; Toutounchi, S.; Khavei, M. Russian Journal of Physical Chemistry A 2012, 86, 689. https://doi.org/10.1134/S0036024412040103
  3. Ahuja, R.; Fast, L.; Eriksson, O.; Wills, J. M.; Johansson, B. J. Appl. Phys. 2005, 83, 1835.
  4. Giahi, M.; Taghavi, H.; Habibi, S. Russian Journal of Physical Chemistry A 2012, 86, 2003. https://doi.org/10.1134/S0036024412130080
  5. Wang, C.; Xu, B. Q.; Wang, X. M.; Zhao, J. C. J. Solid State Chem. 2005, 178, 3500. https://doi.org/10.1016/j.jssc.2005.09.005
  6. Zhang, Z. H.; Yuan, Y.; Fang, Y. J.; Liang, L. H.; Ding, H. C.; Jin, L. T. Talanta 2007, 73, 523. https://doi.org/10.1016/j.talanta.2007.04.011
  7. Wang, C.; Wang, X. M.; Xu, B. Q.; Zhao, J. C.; Mai, B. X.; Peng, P. A.; Sheng, G. Y.; Fu, H. M. J. Photochem. Photobiol. A 2004, 168, 47. https://doi.org/10.1016/j.jphotochem.2004.05.014
  8. Sakthivel, S.; Geissen, S. U.; Bahnemann, D. W.; Murugesan, V.; Vogelpohl, A. J. Photochem. Photobiol. A 2002, 148, 283. https://doi.org/10.1016/S1010-6030(02)00055-2
  9. Li, D.; Haneda, H. J. Photochem. Photobiol. A 2003, 160, 203. https://doi.org/10.1016/S1010-6030(03)00212-0
  10. Spanhel, L.; Weller, H.; Henglein, A. J. Am. Chem. Soc. 1987, 109, 6632. https://doi.org/10.1021/ja00256a012
  11. Rabani, J. J. Phys. Chem. 1989, 93, 7707. https://doi.org/10.1021/j100359a035
  12. Eswaramoorthi, I.; Sundaramurthy, V.; Dalai, A. K. Appl. Catal. A 2006, 313, 22. https://doi.org/10.1016/j.apcata.2006.06.052
  13. Yang, H. C.; Chang, F. W.; Roselin, L. S. J. Mol. Catal. A 2007, 276, 184. https://doi.org/10.1016/j.molcata.2007.07.002
  14. Yoon, D. H.; Yu, J. H.; Choi, G. M. Sens. Actuators B 1998, 46, 15. https://doi.org/10.1016/S0925-4005(97)00317-1
  15. Hu, Y.; Zhou, X. H.; Han, Q.; Cao, Q. X.; Huang, Y. X. Mater. Sci. Eng. B 2003, 99, 41. https://doi.org/10.1016/S0921-5107(02)00446-4
  16. Fierro, G.; Jacono, M. L.; Inversi, M.; Porta, P.; Cioci, F.; Lavecchia, R. Appl. Catal. A 1996, 137, 327. https://doi.org/10.1016/0926-860X(95)00311-8
  17. Behnajadi, M. A.; Modirshahla, N.; Hamzavi, R. J. Hazard. Mater. B 2006, 133, 226. https://doi.org/10.1016/j.jhazmat.2005.10.022
  18. Titus, M. P.; Molina, V. G.; Banos, M. A.; Gimenes, J.; Esplugas, S. Appl. Catal, B Environ. 2004, 47, 219. https://doi.org/10.1016/j.apcatb.2003.09.010
  19. Mijin, D.; Savic, M.; Snezana, P.; Smiljanic, A.; Glavaski, O.; Jovanovic, M.; Petrovic, S. Desalination 2009, 249, 2862.
  20. Daneshvar, N.; Salari, D.; Khataee, A. R. J. Photochem. Photobiol. A: Chem. 2004, 162, 317. https://doi.org/10.1016/S1010-6030(03)00378-2
  21. Wei, L.; Shifu, C.; Wei, Z.; Sujuan, Z. Journal of Hazardous Materials 2009, 164, 154. https://doi.org/10.1016/j.jhazmat.2008.07.140
  22. Devipriya, S.; Yesodharan, S. Sol. Energy Mater. Sol. Cells 2005, 86, 309. https://doi.org/10.1016/j.solmat.2004.07.013
  23. Kown, Y. T.; Song, K. Y.; Lee, W. I.; Choi, G. J.; Do, Y. R. J. Catal. 2000, 191, 192. https://doi.org/10.1006/jcat.1999.2776
  24. Mozia, S.; Tomaszewska, M.; Morawski, A. W. Desalination 2005, 185, 449. https://doi.org/10.1016/j.desal.2005.04.050
  25. Chen, C. C.; Lu, C. S.; Fan, H. J.; Lin, H. D. Desalination 2008, 219, 89. https://doi.org/10.1016/j.desal.2007.05.009
  26. Rajeshwa, K.; Osugi, M. E.; Chanmanee, W.; Chenthamarakshan, C. R.; Zanoni, P.; Kajitvichyanukul, M. V. W.; Krishnan-Ayer, R. J. Photochem. Photobiol. C: Photochem Rev. 2008, 9, 171. https://doi.org/10.1016/j.jphotochemrev.2008.09.001
  27. Roy, R. K. Design of Experiments Using The Taguchi approach: 16 Steps to Product and Process Improvement; John Wiley & Sons Inc.: Canada, step 1, 2001; p 10.
  28. Konstantinou, I. K.; Albanis, T. A. Appl Catal B: Environ. 2004, 49, 1. https://doi.org/10.1016/j.apcatb.2003.11.010

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