DOI QR코드

DOI QR Code

Effect of Organoclay and Blends on the Abrasion Resistance and Mechanical Properties of Poly(styrene-block-butadiene-block-styrene)

  • Kim, Ji-Hoo (Division of Energy and Bio Engineering, Dongseo University) ;
  • Kim, Gue-Hyun (Division of Energy and Bio Engineering, Dongseo University)
  • Received : 2013.04.08
  • Accepted : 2013.06.10
  • Published : 2013.06.28

Abstract

To investigate organoclay, high styrene resin masterbatch (HSR), high impact polystyrene (HIPS), and polystyrene (PS) as reinforcing materials for the improvement of the abrasion resistance of poly(styrene-block-butadiene-block-styrene) (SBS), SBS/organoclay nanocomposites, SBS/HSR, SBS/HIPS, and SBS/PS blends were prepared. The effect of organoclay and blends on the abrasion resistance and mechanical properties of SBS was investigated. Even though intercalations of organoclay are observed for SBS/Cloisite 20A nanocomposites and not for SBS/Cloisite 30B composites, the abrasion resistance of SBS/Cloisite 20A nanocomposites is worse than that of SBS/Cloisite 30B composites. When SBS was blended with HSR, HIPS and PS, the abrasion resistance of the blends increases with increasing of HSR, HIPS and PS content from 0 to 20 wt%.

Keywords

References

  1. Ahmadi, S. J., Huang, Y., Li, W., 2005, Fabrication and physical properties of EPDM-organoclay nanocomposites, Compos. Sci. Technol., 65, 1069-1076. https://doi.org/10.1016/j.compscitech.2004.10.028
  2. Alexandre, M., Dubois, P., 2000, Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials, Mater. Sci. Eng., 28, 1-63. https://doi.org/10.1016/S0927-796X(00)00012-7
  3. Ataeefard, M., Moradian, S., 2011, Polypropylene/ Organoclay Nanocomposites: Effects of Clay Content on Properties, Polym-Plast. Technol. Eng., 50, 732-739. https://doi.org/10.1080/03602559.2010.551438
  4. Briscoe, B., 1981, Wear of polymers: an essay on fundamental aspects, Tribol. Int., 14, 231-243. https://doi.org/10.1016/0301-679X(81)90050-5
  5. Chen, Z., Feng, R., 2009, Preparation and characterization of poly (styrene-b-butadiene-bstyrene)/ montmorillonite nanocomposites, Polym. Compos., 30, 281-287. https://doi.org/10.1002/pc.20631
  6. Chu, L. H., Chiu, W. Y., Chen, C. H., Tseng, H. C., 1999, A Modified Rheological Model of Viscosities for BR-SBS Blends, J. Appl. Polym. Sci., 71, 39-46. https://doi.org/10.1002/(SICI)1097-4628(19990103)71:1<39::AID-APP6>3.0.CO;2-3
  7. Giannelis, E. P., 1996, Polymer layered silicate nanocomposites, Adv. Mater, 8, 29-35. https://doi.org/10.1002/adma.19960080104
  8. Han, C. D., Baek, D. M., Kim, J., Kimishima, K., Hashimoto, T., 1992, Viscoelastic behavior, phase equilibria, and microdomain morphology in mixtures of a block copolymer and a homopolymer, Macromolecules, 25, 3052-3067. https://doi.org/10.1021/ma00038a008
  9. Laus, M., Francescangeli, O., Sandrolini, F. J., 1997, New hybrid nanocomposites based on an organophilic clay and poly(styrene-b-butadiene) copolymers, Mater. Res., 12, 3134-3139. https://doi.org/10.1557/JMR.1997.0409
  10. LeBaron, P. C., Wang, Z., Pinnavaia, T. J., 1999, Polymerlayered silicate nanocomposites: an overview, 1999, Appl. Clay Sci., 15, 11-29. https://doi.org/10.1016/S0169-1317(99)00017-4
  11. Liao, M., Zhu, J., Xu, H., Li, Y., Shan, W., 2004, Preparation and Structure and Mechanical Properties of Poly(Styrene-b-butadiene)/Clay Nanocomposites, J. Appl. Polym. Sci., 92, 3430-3434. https://doi.org/10.1002/app.20372
  12. Maniar, K. K., 2004, Polymeric Nanocomposites: A Review, Polym-Plast. Technol. Eng., 43, 427-443. https://doi.org/10.1081/PPT-120029972
  13. Mukhopadhyay, K., Tripathy, D. K., De, S. K., 1991, Wear, tear and tensile failure of silica-filled ethylene vinyl acetate rubber, Wear, 152, 111-125.
  14. Pappa, G., Boukouvalas, N., Giannaris, C., Ntaras, N., Zografos, V., Magoulas, K., Lygeros, A., Tassios, D., 2001, The selective dissolution/precipitation technique for polymer recycling: a pilot unit application, Resources Conserv. Recycling, 34, 33-44. https://doi.org/10.1016/S0921-3449(01)00092-1
  15. Ray, S. S., Okamoto, M., 2003, Polymer/layered silicate nanocomposites: a review from preparation to processing, Prog. Polym. Sci., 28, 1539-1641. https://doi.org/10.1016/j.progpolymsci.2003.08.002
  16. Roe, R. J., Jin, W. C., 1984, Phase equilibria and transition in mixtures of a homopolymer and a block copolymer. 2. Phase diagram, Macromolecules, 17, 189-194. https://doi.org/10.1021/ma00132a012
  17. Shafiee, M., Ramazani, S. A. A., Danaei, M., 2010, Investigation of the Gas Barrier Properties of PP/Clay Nanocomposite Films with EVA as a Compatibiliser Prepared by the Melt Intercalation Method, Polym-Plast. Technol. Eng., 49, 991-995. https://doi.org/10.1080/03602559.2010.482075
  18. Yang, A. C. M., Ayala, J. E., Scott, J. C., 1991, Abrasive wear in filled elastomers, J. Mater. Sci., 26, 5823-5837. https://doi.org/10.1007/BF01130121
  19. Zhang, S. W., 1981, Mechanisms of rubber abrasion in unsteady state, Rubber Chem. Technol., 57, 755-768.