Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Novel and Chemoselective Dehydrogenation of 3,4-Dihydropyrimidin-2(1H)-ones with 1,4-Bis(triphenylphosphonium)-2-butene Peroxodisulfate

  • Received : 2013.02.10
  • Accepted : 2013.03.18
  • Published : 2013.06.20
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Abstract

3,4-Dihydropyrimidin-2(1H)-ones were efficiently converted into the corresponding pyrimidin-2(1H)-ones in high yields within a short period of time on treatment with aqueous acetonitrile using 1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate. Chemoselective oxidation of 3,4-dihydropyrimidin in the presence of other oxidizable functional groups was also achieved by this reagent.

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References

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Cited by

  1. ChemInform Abstract: Novel and Chemoselective Dehydrogenation of 3,4-Dihydropyrimidin-2(1H)-ones with 1,4-Bis(triphenylphosphonium)-2-butene Peroxodisulfate. vol.44, pp.41, 2013, https://doi.org/10.1002/chin.201341183