DOI QR코드

DOI QR Code

NaOH처리시 Poly(ethylene terephthalate)필름의 표면특성에 영향을 주는 Diamine의 첨가효과

Effect of Diamine Addition in NaOH Treatment Solution on Surface Characteristics of Poly (Ethylene Terephthalate) Film

  • Kang, In-Sook (Dept. of Clothing & Textiles, Changwon National University) ;
  • Bae, Hyun-Sook (Dept. of Clothing & Textiles, Changwon National University)
  • 투고 : 2012.11.28
  • 심사 : 2013.03.15
  • 발행 : 2013.04.30

초록

This study is a preliminary investigation of the influence of surface characteristics of substrates on detergency of particulate soil. The surface of PET film was modified with NaOH and NaOH+ethylene diamine on different times. The surface morphology of the film was scanned by AFM and surface energies were calculated from measured contact angles between several solutions and film based on the geometric mean and a Lewis acid base method. The surface morphology of PET film treated with NaOH and NaOH+ethylene diamine became more etched, and the surface area, surface roughness and the coefficient of friction of film increased with treatment of NaOH and NaOH+ethylene diamine. The contact angle of film treated with NaOH and NaOH+ethylene diamine decreased in water and surfactant solution; in addition, the surface energy increased was largely attributed to the increased portion on the polar surface energy of film. However, the effect of the diamine addition to the NaOH treatment solution on surface characteristics of PET film was insignificant.

키워드

참고문헌

  1. Brendan, C. (1996). The direct study of soil removal from solid substrates in detergency. Colloid and Surfaces A:Physicochemical and Engineering Aspects, 114, 161-164. https://doi.org/10.1016/0927-7757(96)03525-X
  2. Haghighatkish, M., & Yousefi, M. (1992). Alkaline hydrolysis of polyester fibers -structural effects. Iranian Journal of Polymer Science & Technology, 1(2), 56-61.
  3. Hauthal, H. G. (2002). Structured surfaces-detergency angled at new materials. Seifen Oele Fette Waches Journal, 128(10), 4-13.
  4. Kang, I. S., & Kim, B. J. (2001). Effect of electrolyte on the adhesion of particulate soil to fabric in the surfactant solution. Journal of the Korean Society of Clothing and Textiles, 25(8), 1465-1474.
  5. Kang, I. S., & Jung, S. Y. (2005). Effect of steric stability by adsorption of surfactant on the detergency of particulate soil in anionic/nonionic surfactant mixed solution(I). Textile Science and Engineering, 42(3), 166-173.
  6. Lee, J. S., & Ryu, H. S. (1992). An addition effect of amine and cethyl trimethyl ammonium bromide on alkali-treatment of polyester. Journal of the Korean Society of Clothing and Textiles, 16(3), 335-344.
  7. Mun, M. H., & Kang, I. S. (2009). Interfacial electrical effect of particle radius on detergency of particulate soil- particle sizes and dispersion stability of particle-. Textile Science and Engineering, 46(6), 334-341.
  8. Rha, J. J., Kwon, S. C., & Jeong, Y. S. (2006). The effects of surface energy and roughness on adhesion force. The Korean Society of Mechanical Engineers, 30(11), 1335-1347. https://doi.org/10.3795/KSME-A.2006.30.11.1335
  9. Tagawa, Y., & Gotoh, K. (2007). Effect of surface free energies on the detergency phenomena of particulate soils. Journal of the Japan Research Association for Textile End-Uses, 48(6), 29-36.
  10. Zimoch, J., Hreczuch, W., Trathnigg, B., Meissner, J., Bialowas, E., & Szymanowski, J. (2002). Detergency and dynamic surface tension reduction of oxyethylated fatty acid methyl esters. Tenside Surface Detergents, 39(2), 8-16.