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Dyeabilities with Various Fabrics and Chemical Composition of Brown Colorants from Pine Bark

적송수피 색소 성분의 화학적 조성과 섬유 염색성

  • Kim, Yong-Sook (Systems and Synthetic Biology Research Center, Korea Research Institute of Bioscience & Biotechnology) ;
  • Bae, Soon Ei (Dept. of Fashion Design, Hanseo University)
  • 김용숙 (한국생명공학연구원 바이오합성연구센터) ;
  • 배순이 (한서대학교 예술학부 의상디자인학과)
  • Received : 2012.03.05
  • Accepted : 2012.12.27
  • Published : 2013.02.28

Abstract

Chemical compositions and biological functions of brown colorants extracted from pine bark(Pinus densiflora) have been studied. Dyeing test using multifiber fabrics with extracted colorants were preliminary carried out. Dyeing conditions and fastness tests of selected fabrics have been also studied. The brown colorants were produced 1.5% concentrations by solvent extraction from milled pine bark using methanol. The colorants were extracted with 80% methanol as best choice by a criteria of solid quantity and dyeability on fabrics. The chemical compositions were identified as mixtures of taxifolin epicatechin and procyanidin by LC/MS analysis. The brown colorants could be dyed not only natural fibers such as cotton, silk and wool but also synthetic fiber as nylon and semi-synthetic fiber as viscose rayon. Maximum K/S values was shown at 400 nm according to different fiber with color appearance of redish brown. Optimum pH and temperature of dyeing conditions was 4 and above $80^{\circ}C$, respectively. The brown colorants had a strong antioxidant activity compared to Butylated hydroxyanisole as standard and weak antimicrobial activity against E. coli. compared to kanamycin. Washing, rubbing, perspiration, dry cleaning and light fastness for cotton, nylon and silk dyed with the brown colorants were carried out by KS K method. Most of color fastness such as washing, rubbing, perspiration, and dry cleaning were represented as 4-5 grade. However, light fastness was reported as 2-3 grade. From this studies, brown colorants produced pine bark have a high potentials for natural dyeing on fabrics with antioxidant activity.

Keywords

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