대한토목학회논문집 (KSCE Journal of Civil and Environmental Engineering Research)

  • 제33권2호
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  • Pages.609-617
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  • 2013
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  • 1015-6348(pISSN)
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  • 2799-9629(eISSN)
대한토목학회 (Korean Society of Civil Engeneers)
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과황산나트륨을 이용한 내분비계장애물질 산화제거

Oxidation of Endocrine Disrupting Chemicals Using Sodium Persulfate

  • 임찬수 (경희대학교 대학원 토목공학과) ;
  • 윤여복 (금호건설 기술연구소) ;
  • 김도군 (경희대학교 대학원 토목공학과) ;
  • 고석오 (경희대학교 공과대학 토목공학과)
  • 투고 : 2012.11.02
  • 심사 : 2012.12.31
  • 발행 : 2013.03.30
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초록

본 연구에서는 역삼투 공정 농축수에 존재할 수 있는 내분비계 장애물질의 처리에 있어, 고급산화 공정의 적용가능성을 다양한 조건하에서 평가하였다. 오염물 제거에는 Fe(II)를 촉매로 한 과황산나트륨 산화를 이용하였으며, 초기 pH와 이온강도 등, 영향인자에 따른 산화능을 검토하였다. Fe(II) 촉매 과황산나트륨에 의한 $17{\alpha}$-ethynylestradiol(EE2) 제거효율은 초기 pH와 이온강도가 증가할수록 감소하였다. 반면, 이온강도 물질로 염소이온과 같은 할로겐족 이온을 적용 시 산화반응에 긍정적인 영향을 나타냈는데, 이는 라디칼 전이에 따른 영향으로 판단된다.

The objective of this study was to evaluate the oxidation method to remove endocrine disrupting chemicals in reverse osmosis(RO) retentate for the reuse of wastewater effluent. Oxidation of organic pollutants was induced by the persulfate catalyzed by Fe(II). Affecting factors such as initial pH and ionic strength on the Fe(II) catalyzed persulfate oxidation were evaluated. $17{\alpha}$-ethynylestradiol (EE2) degradation efficiency decreased as pH and ionic strength increased. However, the efficiency increased as chloride ion concentration increased due to the influence of radical transfer.

키워드

참고문헌

  1. Agenson, K. O., Oh, J. I., and Urase, T. (2003). "Retention of a wide variety of organic pollutants by different nanofiltration/reverse osmosis membranes: controlling parameters of process." J. Membrane Sci., Vol. 225, No. 1/2, pp. 91-103. https://doi.org/10.1016/j.memsci.2003.08.006
  2. Balazs, G. B., Cooper, J. F., Lewis, P. R., and Adamson, G. M. (2000). Emerging Technologies in Hazardous Waste Management, 8, ed. Tedderand Pohland, Kluwer Academic/Plenum Publishers, New York.
  3. Behrman, E. J. and Edwards, J. O. (1980). "The thermal decomposition of peroxodisulfate ions." Rev. Inorg. Chem., Vol. 2, pp. 179-206.
  4. Block, P. A., Brown, R. A., and Robinson, D. (2004). "Novel activation technologies for sodium persulfate in situ chemical oxidation." Proc. of the Fourth Int. Conference on the Remediation of Chlorinated and Recalcitrant Compounds, Monterey, California, May 24-27.
  5. Buxton, G. V., Greenstock, C. L., Helman, W. P., and Ross, A. B. (1988). "Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals ($OH^{.}/OH^{.-}$ in aqueous solution." J. Phys. Chem. Ref. Data, Vol. 17, No. 2, pp. 513-531. https://doi.org/10.1063/1.555805
  6. Dahmani, M. A., Huang, K., and Hoag, G. E. (2006). "Sodium persulfate oxidation for the remediation of chlorinated solvents (USEPA Superfund Innovative Technology Evaluation Program)." Water, Air, Soil Pollut., Vol. 6, No. 1/2, pp. 127-141. https://doi.org/10.1007/s11267-005-9002-5
  7. Garcia-Figueruelo, C., Bes-Pia, A., and Mendoza-Roca, J. A. (2009). "Reverse osmosis of the retentate from the nanofiltration of secondary effluents." Desalin., Vol. 240, No. 1/3, pp. 274-279. https://doi.org/10.1016/j.desal.2008.01.052
  8. Herrmann, H., Ervens, B., and Nowacki, P. (1999). "A chemical aqueous phase radical mechanism for tropospheric chemistry." Chemosphere, Vol. 38, No. 6, pp. 1223-1232. https://doi.org/10.1016/S0045-6535(98)00520-7
  9. House, D. A. (1962). "Kinetics and mechanism of oxidations by peroxy disulphate." Chem. Rev., Vol. 62, pp. 185-200. https://doi.org/10.1021/cr60217a001
  10. Huang, K. C., Couttenye, R. A., and Hoag, G. E. (2002). "Kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE)." Chemosphere, Vol. 49, No. 4, pp. 413-420. https://doi.org/10.1016/S0045-6535(02)00330-2
  11. Huang, K. C., Zhao, Z., Hoag, G. E., Dahmani, A., and Block, P. A. (2005). "Degradation of volatile organic compounds with thermally activated persulfate oxidation." Chemosphere, Vol. 61, No. 4, pp. 551-560. https://doi.org/10.1016/j.chemosphere.2005.02.032
  12. Huie, R. E., Clifton, C. L., and Neta, P. (1991). "Electron transfer reaction rates and equilibria of the carbonate and sulfate radical anions." Radiat. Phys. Chem., Vol. 38, pp. 477-481.
  13. Kiwi, J., Lopez, A. and Nadtochenko, V. (2000). "Mechanism and kinetics of the OH.radical intervention during fenton oxidation in the presence of a significant amount of radical scavenger ($Cl^{-}$)." Environ. Sci. Technol., Vol. 34, No. 11, pp. 2162-2168. https://doi.org/10.1021/es991406i
  14. Kolpin, D. W., Furlong. E. T., and Meyer. M. T. (2002). "Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999 - 2000: A National Reconnaissance." Environ. Sci. Technol., Vol. 36, No. 6, pp. 1202-1211. https://doi.org/10.1021/es011055j
  15. Liang, C. and Su, H. W. (2009). "Identification of sulfate and hydroxyl radicals in thermally activated persulfate." Ind. Eng. Chem. Res., Vol. 48, No. 11, pp. 5558-5562. https://doi.org/10.1021/ie9002848
  16. Liang, C., Bruell, C. J., Marley, M. C., and Sperry, K. L. (2004). "Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple." Chemosphere, Vol. 55, No. 9, pp. 1213-1223. https://doi.org/10.1016/j.chemosphere.2004.01.029
  17. Liang, C., Huang, C. F., Mohanty, N., and Kurakalva, R. M. (2008). "A rapid spectrophotometric determination of persulfate anion in ISCO." Chemosphere, Vol. 73, No. 9, pp.1540-1543. https://doi.org/10.1016/j.chemosphere.2008.08.043
  18. Neta, P., Huie, R. E., and Ross, A. B. (1988). "Rate constants for reactions for inorganic radicals in aqueous solution." J. Phys. Chem. Ref. Data, Vol. 173, pp. 1027-1247.
  19. Rahman, M. F., Yanful, E. K., and Jasim, S. Y. (2009). "Endocrine disrupting compounds (EDCs) and pharmaceuticals and personal care products (PPCPs) in the aquatic environment: implications for the drinking water industry and global environmental health." J. Water Health, Vol. 7, No. 2, pp. 224-243. https://doi.org/10.2166/wh.2009.021
  20. Westerhoff, P., Moon, H., Minakata, D., and Crittenden, J. (2009). "Oxidation of organics in retentates from reverse osmosis wastewater reuse facilities." Water Res., Vol. 43, Issue 16, pp. 3992-3998. https://doi.org/10.1016/j.watres.2009.04.010
  21. Xu, S. C., Zhou, H. D., Wei, X. Y., and Lu, J. (1989). "The pH dependence and effects of the oxidative products of some aromatic compounds in ozonation under irradiation." Ozone Sci. Eng., Vol. 11, No. 3, pp. 281-296. https://doi.org/10.1080/01919518908552442
  22. Yu, X. Y. and Baker, J. R. (2003). "Hydrogen peroxide photolysis in acidic aqueous solutions containing chloride ions. I. Chemical mechanism." J. Phys. Chem. A, Vol. 107, No. 9, pp. 1313-1324. https://doi.org/10.1021/jp0266648