폴리머 (Polymer(Korea))

  • 제37권2호
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  • Pages.232-239
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  • 2013
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  • 0379-153X(pISSN)
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  • 2234-8077(eISSN)
한국고분자학회 (The Polymer Society of Korea)
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말단 수산화기를 가진 폴리락타이드와 이미다졸로 블록된 이소시아네이트를 이용한 폴리우레탄 바이오접착제의 합성 및 물성 평가

Preparation and Characterization of Polyurethane Bioadhesive from Hydroxyl-terminated Polylactide and Imidazole-blocked Isocyanate

  • Shen, Tengfei (Department of Environmental Engineering, North China Institute of Science and Technology) ;
  • Sun, Yingjuan (Department of Environmental Engineering, North China Institute of Science and Technology) ;
  • Sun, Chunfeng (Department of Environmental Engineering, North China Institute of Science and Technology) ;
  • Lu, Mangeng (Guangzhou Institute of Chemistry, Graduate University of Chinese Academy of Sciences)
  • 투고 : 2012.11.28
  • 심사 : 2013.01.04
  • 발행 : 2013.03.25
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초록

A series of novel imidazole-blocked diisocyanate bioadhesives (IBAs) were synthesized from reaction of toluene 2, 4-diisocyanate (TDI), isophorone diisocyanate (IPDI), hydroxyl-terminated polylactide (HO-PLA-OH), 1,1,1-trimethylolpropane (TMP), and imidazole. Synthesis of IBAs was confirmed by Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC). Differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) revealed that the TDI-based IBA had lower thermal dissociation temperature and a faster deblocking rate than IBA based on IPDI. Hydroxyl-terminated polyurethane (HPU) was introduced to study the adhesive effect of the synthesized IBAs. Improvement on elastic modulus, tensile strength and water resistance of IBA-modified HPU in comparison with neat HPU suggested the good adhesive effect of IBA due to the strong chemical reaction between released NCO groups from IBA and hydroxyl groups from HPU.

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과제정보

연구 과제 주관 기관 : Central Universities

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피인용 문헌

  1. Study on synthesis, characterizations, and properties of pyridinol-blocked isocyanates and waterborne polyurethane vol.21, pp.8, 2016, https://doi.org/10.1080/1023666x.2016.1207129
  2. Blocking and Deblocking of Diisocyanate to Synthesize Polyurethanes vol.13, pp.17, 2021, https://doi.org/10.3390/polym13172875
  3. Polyvinyl alcohol-waterborne blocked-based polyurethane composite surface sizing agents for enhancing mechanical performance of specialty paper vol.160, pp.None, 2013, https://doi.org/10.1016/j.eurpolymj.2021.110736