멤브레인 (Membrane Journal)

  • 제23권2호
  • /
  • Pages.119-128
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  • 2013
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  • 1226-0088(pISSN)
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  • 2288-7253(eISSN)
한국막학회 (The Membrane Society of Korea)
권호 표지

PEI/PEBAX 복합 중공사 막을 이용한 수분 제거에 관한 연구

Study on the Removal of Water Vapor Using PEI/PEBAX Composite Hollow Fiber Membrane

  • 투고 : 2012.11.26
  • 심사 : 2013.02.05
  • 발행 : 2013.04.30
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⟨ 이전 논문 다음 논문 ⟩

초록

본 연구에서는 복합 중공사 막을 이용하여 가스 중 수분(water vapor)의 제거에 관한 연구를 수행하였다. 막 소재로는 PEI (Polyetherimide)를 사용하였고 건/습식 상전이 법을 이용하여 중공사 형태로 제조한 후, 표면에 PEBAX (Polyether block amides) 3533또는 PEBAX1657를 코팅하여 복합 중공사막을 제조하였다. 제조된 중공사 막에 대한 SEM 관찰을 통하여 외부 표면에 치밀한 선택층과 망상구조의 하부로 이루어진 비대칭 구조임을 확인하였다. 막의 수분 투과특성을 확인하기 위하여 수분활성도(Water activity), 온도와 압력 변화에 따른 수분과 $N_2$의 투과도를 측정하였다. PEBAX3533을 코팅한 복합중공사 막의 수분 투과도는 운전 조건에 따라 385.6~727.3 GPU, 수분/$N_2$ 선택도는 61.7~118.5의 값을 나타내었다. PEBAX1657 코팅의 경우, 수분 투과도는 204.1~562.1 GPU, 수분/$N_2$ 선택도는 85.3~175.4의 값을 나타내었다. 막의 수분제거율은 PEBAX3533 코팅한 경우에 90%를 나타내었다.

In this research, PEI/PEBAX composite hollow fiber membrane was used for the removal of water vapor from gases. PEI (Polyetherimide) substrate membrane was spinned by dry-wet phase inversion method and coated with PEBAX (Polyether block amides) 3533 and PEBAX1657. Fabricated fibers typically had an asymmetric structure of a dense top layer supported by a sponge-like substructure through scanning electron microscopy (SEM). $H_2O/N_2$ mixture gas was used to compare the performance of separation according to temperature, pressure and water activity. The results of PEBAX3533 and PEBAX1657 composite membranes respectively showed $H_2O/N_2$ selectivity of 61.7~118.5 and 85.3~175.4 according to operating conditions. PEBAX3533 composite hollow fiber membranes module showed the water vapor removal of 90%.

키워드

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